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Synthesis and characterization of françoisite-(Nd): Nd[(UO2)3O(OH)(PO4)2]·6H2O

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Published/Copyright: April 2, 2015
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American Mineralogist
From the journal American Mineralogist Volume 96 Issue 2-3

Abstract

In this report, synthesis and characterization data for françoisite-(Nd), Nd[(UO2)3O(OH) (PO4)2]·6H2O are presented. Experimental studies including chemical digestion, thermogravimetric analysis (TG), attenuated total reflection infrared spectroscopy (ATR-IR), Raman spectroscopy, and X-ray powder diffraction (XRD) were conducted. The local bonding environments of uranyl and water were investigated with ATR-IR and Raman spectroscopy. The average axial uranium-oxygen bond lengths [R(U=O)] and the oxygen-oxygen hydrogen bond distances [R(O···O)] in water were calculated from the vibrational frequencies of the stretching modes of uranyl and water, respectively. The IR spectra of protiated and deuterated françoisite-(Nd) appear to confirm a coordinated hydroxyl group bridging vicinal uranyl groups in the structural unit. These studies provide the basis for further thermodynamic (e.g., calorimetry, solubility, and sorption) and geochemical modeling investigations of hydrated uranyl phosphate compounds

Keywords: Françoisite-(Nd); uranyl phosphates; mixed actinide solid phases; spent nuclear fuel corrosion; uranium remediation
Received: 2010-5-21
Accepted: 2010-10-6
Published Online: 2015-4-2
Published in Print: 2011-2-1

© 2015 by Walter de Gruyter Berlin/Boston

Articles in the same Issue

  1. Paulscherrerite from the Number 2 Workings, Mount Painter Inlier, Northern Flinders Ranges, South Australia: “Dehydrated schoepite” is a mineral after all
  2. Atomistic investigation of the pyrophyllitic substitution and implications on clay stability
  3. Application of the two-feldspar geothermometer to ultrahigh-temperature (UHT) rocks in the Khondalite belt, North China craton and its implications
  4. Wüstite in a hydrothermal silver-lead-zinc vein, Lucky Friday mine, Coeur d’Alene mining district, U.S.A.
  5. Gelosaite, BiMo6+(2–5x)Mo5+6xO7(OH)·H2O (0 ≤ x ≤ 0.4), a new mineral from Su Senargiu (CA), Sardinia, Italy, and a second occurrence from Kingsgate, New England, Australia
  6. Improved electron probe microanalysis of trace elements in quartz
  7. Ultra-high residual compressive stress (>2 GPa) in a very small volume (<1 μm3) of indented quartz
  8. Transmission electron microscopy investigation of Ag-free lillianite and heyrovskýite from Vulcano, Aeolian Islands, Italy
  9. Combined inelastic neutron scattering and solid-state density functional theory study of dynamics of hydrogen atoms in muscovite 2M1
  10. Contact metamorphism of a Cretaceous accretionary prism by the 14 Ma Okueyama granite, a single post-kinematic pluton in Central Kyushu, Japan: SVD analysis of metamorphic reactions and thermal release
  11. Origin of crosscutting dissolution surfaces in magmatic plagioclase
  12. Néel transition in (Mg,Fe)O: A possible change of magnetic structure
  13. Extreme channelization of fluid and the problem of element mobility during Barrovian metamorphism
  14. The high-temperature P21/m → C2/m phase transitions in synthetic amphiboles along the richterite–(BMg)–richterite join
  15. The crystal structure of barite, BaSO4, at high pressure
  16. Thermal decomposition of brushite, CaHPO4·2H2O to monetite CaHPO4 and the formation of an amorphous phase
  17. Rhombic-shaped nanodomains in columbite driven by contrasting cation order
  18. High-pressure structural evolution and equation of state of analbite
  19. In-situ dehydration studies of fully K-, Rb-, and Cs-exchanged natrolites
  20. The crystal structures and Raman spectra of aravaipaite and calcioaravaipaite
  21. Temperature dependence of the Fe2+ Mössbauer parameters in triphylite (LiFePO4)
  22. Synthesis and characterization of françoisite-(Nd): Nd[(UO2)3O(OH)(PO4)2]·6H2O
  23. Fluorphosphohedyphane, Ca2Pb3(PO4)3F, the first apatite supergroup mineral with essential Pb and F
  24. A new mineral with an olivine structure and pyroxene composition in the shock-induced melt veins of Tenham L6 chondrite
  25. The WURM project—a freely available web-based repository of computed physical data for minerals
  26. Acid production by FeSO4·nH2O dissolution: Comment
  27. Letter. Crystal chemistry of sodium in the Earth’s interior: The structure of Na2MgSi5O12 synthesized at 17.5 GPa and 1700 °C
  28. Letter. In-situ infrared spectra of OH in olivine to 1100°C
https://doi.org/10.2138/am.2011.3609
Keywords for this article
Françoisite-(Nd); uranyl phosphates; mixed actinide solid phases; spent nuclear fuel corrosion; uranium remediation

Articles in the same Issue

  1. Paulscherrerite from the Number 2 Workings, Mount Painter Inlier, Northern Flinders Ranges, South Australia: “Dehydrated schoepite” is a mineral after all
  2. Atomistic investigation of the pyrophyllitic substitution and implications on clay stability
  3. Application of the two-feldspar geothermometer to ultrahigh-temperature (UHT) rocks in the Khondalite belt, North China craton and its implications
  4. Wüstite in a hydrothermal silver-lead-zinc vein, Lucky Friday mine, Coeur d’Alene mining district, U.S.A.
  5. Gelosaite, BiMo6+(2–5x)Mo5+6xO7(OH)·H2O (0 ≤ x ≤ 0.4), a new mineral from Su Senargiu (CA), Sardinia, Italy, and a second occurrence from Kingsgate, New England, Australia
  6. Improved electron probe microanalysis of trace elements in quartz
  7. Ultra-high residual compressive stress (>2 GPa) in a very small volume (<1 μm3) of indented quartz
  8. Transmission electron microscopy investigation of Ag-free lillianite and heyrovskýite from Vulcano, Aeolian Islands, Italy
  9. Combined inelastic neutron scattering and solid-state density functional theory study of dynamics of hydrogen atoms in muscovite 2M1
  10. Contact metamorphism of a Cretaceous accretionary prism by the 14 Ma Okueyama granite, a single post-kinematic pluton in Central Kyushu, Japan: SVD analysis of metamorphic reactions and thermal release
  11. Origin of crosscutting dissolution surfaces in magmatic plagioclase
  12. Néel transition in (Mg,Fe)O: A possible change of magnetic structure
  13. Extreme channelization of fluid and the problem of element mobility during Barrovian metamorphism
  14. The high-temperature P21/m → C2/m phase transitions in synthetic amphiboles along the richterite–(BMg)–richterite join
  15. The crystal structure of barite, BaSO4, at high pressure
  16. Thermal decomposition of brushite, CaHPO4·2H2O to monetite CaHPO4 and the formation of an amorphous phase
  17. Rhombic-shaped nanodomains in columbite driven by contrasting cation order
  18. High-pressure structural evolution and equation of state of analbite
  19. In-situ dehydration studies of fully K-, Rb-, and Cs-exchanged natrolites
  20. The crystal structures and Raman spectra of aravaipaite and calcioaravaipaite
  21. Temperature dependence of the Fe2+ Mössbauer parameters in triphylite (LiFePO4)
  22. Synthesis and characterization of françoisite-(Nd): Nd[(UO2)3O(OH)(PO4)2]·6H2O
  23. Fluorphosphohedyphane, Ca2Pb3(PO4)3F, the first apatite supergroup mineral with essential Pb and F
  24. A new mineral with an olivine structure and pyroxene composition in the shock-induced melt veins of Tenham L6 chondrite
  25. The WURM project—a freely available web-based repository of computed physical data for minerals
  26. Acid production by FeSO4·nH2O dissolution: Comment
  27. Letter. Crystal chemistry of sodium in the Earth’s interior: The structure of Na2MgSi5O12 synthesized at 17.5 GPa and 1700 °C
  28. Letter. In-situ infrared spectra of OH in olivine to 1100°C
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