Hematite (U-Th)/He thermochronometry unveils unique exhumation history: An example from the Dexing porphyry copper deposit, Southern China
Abstract
Hematite, commonly found in endogenetic deposits, plays a crucial role in monitoring temperature variations during cooling history and can be used for (U-Th)/He dating. Hematite thermochronometry, when combined with apatite and zircon (U-Th)/He dating, also provides the clearest guide to the timing of the latest thermal evolution path. In this study, we established a new method of hematite (U-Th)/He thermochronometry based on an optimized analytical protocol to reveal the evolution of the latest uplift and cooling history of the Dexing porphyry copper deposit (DPCD) in South China. Two hematite samples from the Tongchang and Fujiawu mines in the DPCD yielded age distributions of 92–11.2 and 112–24 Ma, respectively, and gave closure temperatures between 180 and 215 °C based on their relations to hematite particle sizes (88–199 μm). Combined with the published (U-Th)/He thermochronological data on zircon and apatite, we propose that the DPCD may have experienced a prolonged thermal history characterized by a temperature decrease. The initial exhumation and uplift happened at 112 Ma, and then a rapid uplift occurred from 11.2 to 8.0 Ma. This study demonstrates that hematite (U-Th)/He dating can be effectively applied to reveal the uplift and preservation history of porphyry copper deposits.
Acknowledgments and Funding
We thank the reviewers and the editor for constructively engaging with our work to improve the presentation of our work. We also thank Peng Peng and Lin Wu from the Institute of Geology and Geophysics, Chinese Academy of Science, for earlier manuscript suggestions. This study was supported by the National Science Fund for Distinguished Young Scholars (42025301) and Natural Science Foundation of China (Grant 42130102).
References Cited
Ault, A.K. (2020) Hematite fault rock thermochronometry and textures inform fault zone processes. Journal of Structural Geology, 133, 104002, https://doi.org/10.1016/j.jsg.2020.104002.Suche in Google Scholar
Ault, A.K., Reiners, P.W., Evans, J.P., and Thomson, S.N. (2015) Linking hematite (U-Th)/He dating with the microtextural record of seismicity in the Wasatch fault damage zone, Utah, USA. Geology, 43, 771–774, https://doi.org/10.1130/G36897.1.Suche in Google Scholar
Bähr, R., Lippolt, H.J., and Wernicke, R.S. (1994) Temperature-induced 4He degassing of specularite and botryoidal hematite: A 4He retentivity study. Journal of Geophysical Research: Solid Earth, 99, 17695–17707, https://doi.org/10.1029/94JB01055.Suche in Google Scholar
Calzolari, G., Ault, A.K., Hirth, G., and McDermott, R.G. (2020) Hematite (U-Th)/He thermochronometry detects asperity flash heating during laboratory earthquakes. Geology, 48, 514–518, https://doi.org/10.1130/G46965.1.Suche in Google Scholar
Cooper, F.J., Adams, B.A., Blundy, J.D., Farley, K.A., McKeon, R.E., and Ruggiero, A. (2016) Aridity-induced Miocene canyon incision in the Central Andes. Geology, 44, 675–678, https://doi.org/10.1130/G38254.1.Suche in Google Scholar
Danišík, M., Evans, N.J., Ramanaidou, E.R., McDonald, B.J., Mayers, C., and McInnes, B.I.A. (2013) (U-Th)/He chronology of the Robe River channel iron deposits, Hamersley Province, Western Australia. Chemical Geology, 354, 150–162, https://doi.org/10.1016/j.chemgeo.2013.06.012.Suche in Google Scholar
Deng, X.D., Li, J.W., and Shuster, D.L. (2017) Late Mio-Pliocene chemical weathering of the Yulong porphyry Cu deposit in the eastern Tibetan Plateau constrained by goethite (U-Th)/He dating: Implication for Asian summer monsoon. Earth and Planetary Science Letters, 472, 289–298, https://doi.org/10.1016/j.epsl.2017.04.043.Suche in Google Scholar
Dodson, M.H. (1973) Closure temperature in cooling geochronological and petrological systems. Contributions to Mineralogy and Petrology, 40, 259–274, https://doi.org/10.1007/BF00373790.Suche in Google Scholar
Evenson, N.S., Reiners, P.W., Spencer, J.E., and Shuster, D.L. (2014) Hematite and Mn oxide (U-Th)/He dates from the Buckskin – Rawhide detachment system, Western Arizona: Gaining insights into hematite (U-Th)/He systematics. American Journal of Science, 314, 1373–1435, https://doi.org/10.2475/10.2014.01.Suche in Google Scholar
Farley, K.A. (2000) Helium diffusion from apatite: General behavior as illustrated by Durango fluorapatite. Journal of Geophysical Research: Solid Earth, 105 (B2), 2903–2914, https://doi.org/10.1029/1999JB900348.Suche in Google Scholar
Farley, K.A. (2018) Helium diffusion parameters of hematite from a single-diffusion-domain crystal. Geochimica et Cosmochimica Acta, 231, 117–129, https://doi.org/10.1016/j.gca.2018.04.005.Suche in Google Scholar
Farley, K.A. and Flowers, R.M. (2012) (U-Th)/Ne and multidomain (U-Th)/He systematics of a hydrothermal hematite from eastern Grand Canyon. Earth and Planetary Science Letters, 359-360, 131–140, https://doi.org/10.1016/j.epsl.2012.10.010.Suche in Google Scholar
Farley, K.A. and Stockli, D.F. (2002) (U-Th)/He dating of phosphates: Apatite, monazite, and xenotime. Phosphates. Geochemical, Geobiological, and Materials Importance, 48, 559–578, https://doi.org/10.1515/9781501509636-018.Suche in Google Scholar
Flowers, R.M., Ketcham, R.A., Enkelmann, E., Gautheron, C., Reiners, P.W., Met-calf, J.R., Danisík, M., Stockli, D.F., and Brown, R.W. (2022a) (U-Th)/He chronology: Part 2. Considerations for evaluating, integrating, and interpreting conventional individual aliquot data. Geological Society of America Bulletin, 135, 137–161.Suche in Google Scholar
Flowers, R.M., Zeitler, P.K., Danisík, M., Reiners, P.W., Gautheron, C., Ketcham, R.A., Metcalf, J.R., Stockli, D.F., Enkelmann, E., and Brown, R.W. (2022b) (U-Th)/He chronology: Part 1. Data, uncertainty, and reporting. Geological Society of America Bulletin, 135, 104–136.Suche in Google Scholar
Gallagher, K. (2012) Transdimensional inverse thermal history modeling for quantitative thermochronology. Journal of Geophysical Research: Solid Earth, 117, B02408.Suche in Google Scholar
Gernon, T.M., Hincks, T.K., Brune, S., Braun, J., Jones, S.M., Keir, D., Cunningham, A., and Glerum, A. (2024) Coevolution of craton margins and interiors during continental break-up. Nature 632, 327–335.Suche in Google Scholar
Hamilton, P.J., Kelley, S.P., and Fallick, A.E. (1989) K-Ar dating of illite in hydrocarbon reservoirs. Clay Minerals, 24, 215–231, https://doi.org/10.1180/claymin.1989.024.2.08.Suche in Google Scholar
Hou, Z.Q., Pan, X.F., Li, Q.Y., Yang, Z.M., and Song, Y.C. (2013) The giant Dexing porphyry Cu-Mo-Au deposit in east China: Product of melting of juvenile lower crust in an intracontinental setting. Mineralium Deposita, 48, 1019–1045, https://doi.org/10.1007/s00126-013-0472-5.Suche in Google Scholar
Kesler, S.E. and Wilkinson, B.H. (2006) The role of exhumation in the temporal distribution of ore deposits. Economic Geology and the Bulletin of the Society of Economic Geologists, 101, 919–922, https://doi.org/10.2113/gsecongeo.101.5.919.Suche in Google Scholar
Li, X.F., Watanabe, Y., and Yi, X.K. (2013) Ages and sources of ore-related porphyries at Yongping Cu-Mo deposit in Jiangxi Province, Southeast China. Resource Geology, 63, 288–312, https://doi.org/10.1111/rge.12009.Suche in Google Scholar
Lipar, M., Barham, M., Danišík, M., Šmuc, A., Webb, J.A., McNamara, K.J., Šoster, A., and Ferk, M. (2024) Ironing out complexities in karst chronology: (U-Th)/He ferricrete ages reveal wet MIS 5c. Science Advances, 10, eadp0414, https://doi.org/10.1126/sciadv.adp0414.Suche in Google Scholar
Liu, W. and McPhail, D.C. (2005) Thermodynamic properties of copper chloride complexes and copper transport in magmatic-hydrothermal solutions. Chemical Geology, 221, 21–39, https://doi.org/10.1016/j.chemgeo.2005.04.009.Suche in Google Scholar
Liu, X., Fan, H.R., Santosh, M., Hu, F.F., Yang, K.F., Li, Q.L., Yang, Y.H., and Liu, Y.S. (2012) Remelting of Neoproterozoic relict volcanic arcs in the Middle Jurassic: Implication for the formation of the Dexing porphyry copper deposit, Southeastern China. Lithos, 150, 85–100, https://doi.org/10.1016/j.lithos.2012.05.018.Suche in Google Scholar
Liu, X., Fan, H.R., Evans, N.J., Batt, G.E., McInnes, B.I.A., Yang, K.F., and Qin, K.Z. (2014) Cooling and exhumation of the mid-Jurassic porphyry copper systems in Dexing City, SE China: Insights from geo- and thermochronology. Mineralium Deposita, 49, 809–819, https://doi.org/10.1007/s00126-014-0536-1.Suche in Google Scholar
Mao, J.W., Xie, G.Q., Duan, C., Pirajno, F., Ishiyama, D., and Chen, Y.C. (2011) A tectono-genetic model for porphyry-skarn-stratabound Cu-Au-Mo-Fe and magnetite-apatite deposits along the Middle-Lower Yangtze River Valley, Eastern China. Ore Geology Reviews, 43, 294–314, https://doi.org/10.1016/j.oregeorev.2011.07.010.Suche in Google Scholar
McDermott, R.G., Ault, A.K., Evans, J.P., and Reiners, P.W. (2017) Thermochronometric and textural evidence for seismicity via asperity flash heating on exhumed hematite fault mirrors, Wasatch fault zone, UT, USA. Earth and Planetary Science Letters, 471, 85–93, https://doi.org/10.1016/j.epsl.2017.04.020.Suche in Google Scholar
McInnes, B.I.A. and Evans, N.J. (2005) Application of thermochronology to hydrothermal ore deposits. Low-Temperature Thermochronology. Techniques, Interpretations, and Applications, 58, 467–498.Suche in Google Scholar
Min, K. and Gao, J.F. (2022) Application of low-temperature thermochronology on ore deposits preservation framework in South China: A review. Acta Geochimica, 41, 165–184, https://doi.org/10.1007/s11631-021-00506-x.Suche in Google Scholar
Reiners, P.W. (2005) Zircon (U-Th)/He thermochronometry. Low-Temperature Thermochronology. Techniques, Interpretations, and Applications, 58, 151–179.Suche in Google Scholar
Reiners, P.W. and Farley, K.A. (1999) Helium diffusion and (U–Th)/He thermochronometry of titanite. Geochimica et Cosmochimica Acta, 63, 3845–3859, https://doi.org/10.1016/S0016-7037(99)00170-2.Suche in Google Scholar
Reiners, P.W., Farley, K.A., and Hickes, H.J. (2002) He diffusion and (U-Th)/He thermochronometry of zircon: Initial results from Fish Canyon Tuff and Gold Butte. Tectonophysics, 349, 297–308, https://doi.org/10.1016/S0040-1951(02)00058-6.Suche in Google Scholar
Seedorff, E., Dilles, J.H., Proffett, J.M., Einaudi, M.T., and Barton, M. (2005) Porphyry deposits characteristics and origin of hypogene features. In J.W. Hedenquist, J.F.H. Thompson, R.J. Goldfarb, and J.P. Richards, Eds., One Hundredth Anniversary Volume, p. 251–298. Society of Economic Geologists.Suche in Google Scholar
Shuster, D.L., Vasconcelos, P.M., Heim, J.A., and Farley, K.A. (2005) Weathering geochronology by (U-Th)/He dating of goethite. Geochimica et Cosmochimica Acta, 69, 659–673, https://doi.org/10.1016/j.gca.2004.07.028.Suche in Google Scholar
Sun, W.D., Ling, M.X., Chung, S.L., Ding, X., Yang, X.Y., Liang, H.Y., Fan, W.M., Goldfarb, R., and Yin, Q.Z. (2012) Geochemical constraints on adakites of different origins and copper mineralization. The Journal of Geology, 120, 105–120, https://doi.org/10.1086/662736.Suche in Google Scholar
Suzuki, K., Masuda, A., and Shimizu, H. (1996) Re-Os dating of molybdenites from ore deposits in Japan: Implication for the closure temperature of the Re-Os system for molybdenite and the cooling history of molybdenum in ore deposits. Geochimica et Cosmochimica Acta. Journal of the Geochemical Society and the Meteoritical Society, 60, 3151–3159.Suche in Google Scholar
Vasconcelos, P.M., Heim, J.A., Farley, K.A., Monteiro, H., and Waltenberg, K. (2013) 40Ar/39Ar and (U-Th)/He - 4He/3He geochronology of landscape evolution and channel iron deposit genesis at Lynn Peak, Western Australia. Geochimica et Cosmochimica Acta, 117, 283–312, https://doi.org/10.1016/j.gca.2013.03.037.Suche in Google Scholar
Wang, Q., Zhao, Z.H., Jian, P., Xu, J.F., Bao, Z.W., and Ma, J.L. (2004) SHRIMP zircon geochronology and Nd-Sr isotopic geochemistry of the Dexing granodiorite porphyries. Yanshi Xuebao, 20, 315–324.Suche in Google Scholar
Wang, Y., Yang, X., and Kang, X. (2022) Geochemical and mineralogical studies of zircon, apatite, and chlorite in the giant Dexing porphyry Cu-Mo-Au deposit, South China: Implications for mineralization and hydrothermal processes. Journal of Geochemical Exploration, 240, 107042.Suche in Google Scholar
Wolf, R.A., Farley, K.A., and Silver, L.T. (1996) Helium diffusion and low-temperature thermochronometry of apatite. Geochimica et Cosmochimica Acta, 60, 4231–4240, https://doi.org/10.1016/S0016-7037(96)00192-5.Suche in Google Scholar
Wu, L.Y., Stuart, F.M., Di Nicola, L., Heizler, M., Benvenuti, M., and Hu, R.Z. (2019) Multi-aliquot method for determining (U plus Th)/He ages of hydrothermal hematite: Returning to Elba. Chemical Geology, 504, 151–157, https://doi.org/10.1016/j.chemgeo.2018.11.005.Suche in Google Scholar
Yang, Z.M. and Cooke, D.R. (2019) Porphyry copper deposits in China. Society of Economic Geologists Special Publication, 22, 133–187.Suche in Google Scholar
Zhang, H., Ling, M.X., Liu, Y.L., Tu, X.L., Wang, F.Y., Li, C.Y., Liang, H.Y., Yang, X.Y., Arndt, N.T., and Sun, W.D. (2013) High oxygen fugacity and slab melting linked to Cu mineralization: Evidence from Dexing porphyry copper deposits, Southeastern China. The Journal of Geology, 121, 289–305, https://doi.org/10.1086/669975.Suche in Google Scholar
Zhang, C.C., Sun, W.D., Wang, J.T., Zhang, L.P., Sun, S.J., and Wu, K. (2017) Oxygen fugacity and porphyry mineralization: A zircon perspective of Dexing porphyry Cu deposit, China. Geochimica et Cosmochimica Acta, 206, 343–363, https://doi.org/10.1016/j.gca.2017.03.013.Suche in Google Scholar
Zhang, H., An, F., Ling, M.X., Feng, X.L., and Sun, W.D. (2022) Metallogenesis of porphyry copper deposit indicated by in situ zircon U-Pb-Hf-O and apatite Sr isotopes. Minerals, 12, 1464–1482, https://doi.org/10.3390/min12111464.Suche in Google Scholar
Zhou, Q., Jiang, Y.H., Zhao, P., Liao, S.Y., and Jin, G.D. (2012a) Origin of the Dexing Cu-bearing porphyries, SE China: Elemental and Sr-Nd-Pb-Hf isotopic constraints. International Geology Review, 54, 572–592, https://doi.org/10.1080/00206814.2010.548119.Suche in Google Scholar
Zhou, Q., Jiang, Y.H., Zhao, P., Liao, S.Y., Jin, G.D., Liu, Z., and Jia, R.Y. (2012b) SHRIMP U-Pb dating on hydrothermal zircons: Evidence for an Early Cretaceous epithermal event in the Middle Jurassic Dexing porphyry copper deposit, SE China. Economic Geology and the Bulletin of the Society of Economic Geologists, 107, 1507–1514, https://doi.org/10.2113/econgeo.107.7.1507.Suche in Google Scholar
Zhu, X., Huang, C., Rui, Z., Zhou, Y., Zhu, X., Hu, C., and Mei, Z. (1983) Geology of the Dexing Porphyry Copper Orefield, p. 1–336. Geological Publishing House, Beijing (in Chinese).Suche in Google Scholar
© 2025 Mineralogical Society of America
Artikel in diesem Heft
- Hematite (U-Th)/He thermochronometry unveils unique exhumation history: An example from the Dexing porphyry copper deposit, Southern China
- Viscosity measurements of selected lunar regolith simulants
- Formation of nano-CdS solid solution: A mechanism for Cd enrichment in sphalerite
- Identification of the nature of recycled carbonates in the mantle: Insights from the Mo-Mg isotopic pair
- Discriminating ionic mobility between diffusivity and electrical conductivity experiments on Earth’s silicate materials
- Morphological approach to understanding mineral alteration and nanoparticle formation under alkaline conditions using granitic rock thin sections
- Identification of hydroandradite in CM carbonaceous chondrites: Aproduct of calc-silicate alteration on C-complex asteroids
- Growth and crystallographic features of interpenetrant twins in natural diamonds
- Determination of the oxidation state of iron in calcic pyroxene using the electron microprobe flank method
- Formation mechanism of boehmite and diaspore in karstic bauxites: Trace element geochemistry in source materials using a large sample geochemical dataset and a random forest model
- High-temperature Raman spectroscopy of K2Ca(CO3)2 bütschliite and Na2Ca2(CO3)3 shortite
- Effects of high-temperature annealing and low-temperature metamictization on Archean zircon: Constraints from U-Pb isotopes, trace elements, and Raman dating
- Nanoscale insights into weathering of Ti-bearing minerals and heterogeneous crystal growth mechanisms of nano Ti oxides in altered volcanic ash
- High-pressure single-crystal X-ray diffraction and Raman spectroscopy of boltwoodite, K0.63Na0.37[(UO2)(SiO3OH)](H2O)1.5
- Nanoscale characterization of chrysocolla, black chrysocolla, and pseudomalachite from supergene copper deposits of Atacama Desert in northern Chile
Artikel in diesem Heft
- Hematite (U-Th)/He thermochronometry unveils unique exhumation history: An example from the Dexing porphyry copper deposit, Southern China
- Viscosity measurements of selected lunar regolith simulants
- Formation of nano-CdS solid solution: A mechanism for Cd enrichment in sphalerite
- Identification of the nature of recycled carbonates in the mantle: Insights from the Mo-Mg isotopic pair
- Discriminating ionic mobility between diffusivity and electrical conductivity experiments on Earth’s silicate materials
- Morphological approach to understanding mineral alteration and nanoparticle formation under alkaline conditions using granitic rock thin sections
- Identification of hydroandradite in CM carbonaceous chondrites: Aproduct of calc-silicate alteration on C-complex asteroids
- Growth and crystallographic features of interpenetrant twins in natural diamonds
- Determination of the oxidation state of iron in calcic pyroxene using the electron microprobe flank method
- Formation mechanism of boehmite and diaspore in karstic bauxites: Trace element geochemistry in source materials using a large sample geochemical dataset and a random forest model
- High-temperature Raman spectroscopy of K2Ca(CO3)2 bütschliite and Na2Ca2(CO3)3 shortite
- Effects of high-temperature annealing and low-temperature metamictization on Archean zircon: Constraints from U-Pb isotopes, trace elements, and Raman dating
- Nanoscale insights into weathering of Ti-bearing minerals and heterogeneous crystal growth mechanisms of nano Ti oxides in altered volcanic ash
- High-pressure single-crystal X-ray diffraction and Raman spectroscopy of boltwoodite, K0.63Na0.37[(UO2)(SiO3OH)](H2O)1.5
- Nanoscale characterization of chrysocolla, black chrysocolla, and pseudomalachite from supergene copper deposits of Atacama Desert in northern Chile