Microchemistry and magnesium isotope composition of the Purang ophiolitic chromitites (SW Tibet): New genetic inferences
Abstract
New petrographic and microanalytical studies of mineral inclusions in the Purang ophiolitic chromitites (SW Tibet) are used to scrutinize the evolution of the associated Cretaceous sub-oceanic lithospheric mantle section. Silicate inclusions in the chromite grains include composite and single-phase orthopyroxene, clinopyroxene, amphibole, and uvarovite. Most inclusions are sub-rounded or globular, whereas a few inclusions exhibit cubic/octahedral crystal morphologies. The latter are randomly distributed in the large chromite grains, though discrete aggregates are consistently confined to the grain centers. Abundant micrometer-scale, clinopyroxene inclusions are topotaxially aligned along crystallographic planes. Less-abundant sulfide, wüstite, apatite, and uvarovite inclusions are observed in some samples.
The trace element geochemistry of the Purang chromitite evoke parental MORB- and boninitelike melts, consistent with the supra-subduction zone setting. The δ26Mg values of the high-Cr and high-Al chromitites range from –0.25 to –0.29‰ and –0.05 to –0.32‰, respectively. The associated harzburgite has nearly overlapping δ26Mg values of –0.13 to –0.37‰, but pyroxenite sills show distinct δ26Mg values (–0.61 to –0.67‰). The variable Mg isotope signatures, combined with abundant exotic, ultrahigh-pressure and super reduced (UHP-SuR) mineral inclusions in the chromite grains, suggest that recycling and recrystallization under different mantle conditions played an important role in the genesis and evolution of these rocks. Furthermore, discrete silicate, sulfide, and metal alloy inclusions in the Purang chromitites are comparable to those reported in other Tethyan ophiolites, and collectively suggest a common geodynamic evolution.
Funding statement: This research was co-supported by the National Natural Science Foundation of China (NNSFC; Project No. 92062215, 42172069, 41720104009), the Second Tibetan Plateau Scientific Expedition and Research Program (No. 2019QZKK0801), Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (No. GML2019ZD0201), the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources Fund (No. J1901-28), the China Geological Survey (CGS; Project No. DD20230340, DD20221817, DD20221630).
Acknowledgments
We are indebted to Paul Tomascak (AE) and two anonymous reviewers for their constructive and detailed comments on the early version of this manuscript. Basem Zoheir acknowledges the Alexander von Humboldt Foundation for making his contribution to this work possible during his research stay at Kiel University.
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Articles in the same Issue
- A shallow salt pond analog for aqueous alteration on ancient Mars: Spectroscopy, mineralogy, and geochemistry of sediments from Antarctica’s Dry Valleys
- Incorporation of chlorine in nuclear waste glasses using high-pressure vitrification: Solubility, speciation, and local environment of chlorine
- Experimental constraints on miscibility gap between apatite and britholite and REE partitioning in an alkaline melt
- Thermal expansion of minerals in the tourmaline supergroup
- Viscosity of Earth’s inner core constrained by Fe–Ni interdiffusion in Fe–Si alloy in an internal-resistive-heated diamond anvil cell
- The distribution of carbonate in apatite: The environment model
- Low-temperature crystallography and vibrational properties of rozenite (FeSO4·4H2O), a candidate mineral component of the polyhydrated sulfate deposits on Mars
- Hydrothermal fluid signatures of the Yulong porphyry Cu-Mo deposit: Clues from the composition and U-Pb dating of W-bearing rutile
- Magnetic contributions to corundum-eskolaite and corundum-hematite phase equilibria: A DFT cluster expansion study
- Microchemistry and magnesium isotope composition of the Purang ophiolitic chromitites (SW Tibet): New genetic inferences
- Pyrite geochemistry in a porphyry-skarn Cu (Au) system and implications for ore formation and prospecting: Perspective from Xinqiao deposit, Eastern China
- UV/Vis single-crystal spectroscopic investigation of almandine-pyrope and almandinespessartine solid solutions: Part I. Spin-forbidden Fe2+,3+ and Mn2+ electronic-transition energies, crystal chemistry, and bonding behavior
- Single-crystal UV/Vis optical absorption spectra of almandine-bearing and spessartine garnet: Part II. An analysis of the spin-forbidden bands of Fe2+, Mn2+, and Fe3+
- Single-crystal UV/Vis absorption spectroscopy of aluminosilicate garnet: Part III. {Fe2+} + [Fe3+] → {Fe3+} + [Fe2+] intervalence charge transfer
- A novel method for experiments in a one-atmosphere box furnace
Articles in the same Issue
- A shallow salt pond analog for aqueous alteration on ancient Mars: Spectroscopy, mineralogy, and geochemistry of sediments from Antarctica’s Dry Valleys
- Incorporation of chlorine in nuclear waste glasses using high-pressure vitrification: Solubility, speciation, and local environment of chlorine
- Experimental constraints on miscibility gap between apatite and britholite and REE partitioning in an alkaline melt
- Thermal expansion of minerals in the tourmaline supergroup
- Viscosity of Earth’s inner core constrained by Fe–Ni interdiffusion in Fe–Si alloy in an internal-resistive-heated diamond anvil cell
- The distribution of carbonate in apatite: The environment model
- Low-temperature crystallography and vibrational properties of rozenite (FeSO4·4H2O), a candidate mineral component of the polyhydrated sulfate deposits on Mars
- Hydrothermal fluid signatures of the Yulong porphyry Cu-Mo deposit: Clues from the composition and U-Pb dating of W-bearing rutile
- Magnetic contributions to corundum-eskolaite and corundum-hematite phase equilibria: A DFT cluster expansion study
- Microchemistry and magnesium isotope composition of the Purang ophiolitic chromitites (SW Tibet): New genetic inferences
- Pyrite geochemistry in a porphyry-skarn Cu (Au) system and implications for ore formation and prospecting: Perspective from Xinqiao deposit, Eastern China
- UV/Vis single-crystal spectroscopic investigation of almandine-pyrope and almandinespessartine solid solutions: Part I. Spin-forbidden Fe2+,3+ and Mn2+ electronic-transition energies, crystal chemistry, and bonding behavior
- Single-crystal UV/Vis optical absorption spectra of almandine-bearing and spessartine garnet: Part II. An analysis of the spin-forbidden bands of Fe2+, Mn2+, and Fe3+
- Single-crystal UV/Vis absorption spectroscopy of aluminosilicate garnet: Part III. {Fe2+} + [Fe3+] → {Fe3+} + [Fe2+] intervalence charge transfer
- A novel method for experiments in a one-atmosphere box furnace