A shallow salt pond analog for aqueous alteration on ancient Mars: Spectroscopy, mineralogy, and geochemistry of sediments from Antarctica’s Dry Valleys
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Zachary F.M. Burton
, Janice L. Bishop
Abstract
Understanding past and present aqueous activity on Mars is critical to constraining martian aqueous geochemistry and habitability, and to searching for life on Mars. Assemblages of minerals observed at or near the martian surface include phyllosilicates, sulfates, iron oxides/hydroxides, and chlorides, all of which are indicative of a complex history of aqueous activity and alteration in the martian past. Furthermore, features observed on parts of the martian surface suggest present-day activity of subsurface brines and at least transient liquid water. Terrestrial analogs for younger and colder (Hesperian–Amazonian) martian geologic and climatic conditions are available in the McMurdo Dry Valleys (MDV) of Antarctica and provide opportunities for improved understanding of more recent aqueous activity on Mars. Here, we study the VXE-6 intermittent brine pond site from Wright Valley in the MDV region and use coordinated spectroscopy, X-ray diffraction, and elemental analyses to characterize the mineralogy and chemistry of surface sediments that have evolved in response to aqueous activity at this site. We find that brine pond activity results in mineral assemblages akin to aqueous alteration products associated with younger sites on Mars. In particular, surficial chlorides, a transition layer of poorly crystalline aluminosilicates and iron oxides/hydroxides, and a deeper gypsum-rich interval within the upper 10 cm of sediment are closely related at this Antarctic brine pond site. Activity of the Antarctic brine pond and associated mineral formation presents a process analog for chemical alteration on the martian surface during episodes of transient liquid water activity during the late Hesperian and/or more recently. Our results provide a relevant example of how aqueous activity in a cold and dry Mars-like climate may explain the co-occurrence of chlorides, clays, iron oxides/hydroxides, and sulfates observed on Mars.
Acknowledgments and Funding
Z.F.M.B. thanks the Clay Minerals Society (CMS Travel Award and CMS Research Grant) and the Geological Society of America (GSA Graduate Student Research Grant) for funding. Z.F.M.B. and J.L.B. thank the NASA Astrobiology Institute (NAI NNX15BB01) for support. We thank Takahiro Hiroi at Brown University for assistance with RELAB spectral measurements, Shital Patel for assistance with spectral data processing, Dieter Mader for help with INAA data collection, and Henry Harris for insightful discussions of the VXE-6 site and surrounding region. This manuscript benefited from the comments and suggestions of two anonymous reviewers.
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Articles in the same Issue
- A shallow salt pond analog for aqueous alteration on ancient Mars: Spectroscopy, mineralogy, and geochemistry of sediments from Antarctica’s Dry Valleys
- Incorporation of chlorine in nuclear waste glasses using high-pressure vitrification: Solubility, speciation, and local environment of chlorine
- Experimental constraints on miscibility gap between apatite and britholite and REE partitioning in an alkaline melt
- Thermal expansion of minerals in the tourmaline supergroup
- Viscosity of Earth’s inner core constrained by Fe–Ni interdiffusion in Fe–Si alloy in an internal-resistive-heated diamond anvil cell
- The distribution of carbonate in apatite: The environment model
- Low-temperature crystallography and vibrational properties of rozenite (FeSO4·4H2O), a candidate mineral component of the polyhydrated sulfate deposits on Mars
- Hydrothermal fluid signatures of the Yulong porphyry Cu-Mo deposit: Clues from the composition and U-Pb dating of W-bearing rutile
- Magnetic contributions to corundum-eskolaite and corundum-hematite phase equilibria: A DFT cluster expansion study
- Microchemistry and magnesium isotope composition of the Purang ophiolitic chromitites (SW Tibet): New genetic inferences
- Pyrite geochemistry in a porphyry-skarn Cu (Au) system and implications for ore formation and prospecting: Perspective from Xinqiao deposit, Eastern China
- UV/Vis single-crystal spectroscopic investigation of almandine-pyrope and almandinespessartine solid solutions: Part I. Spin-forbidden Fe2+,3+ and Mn2+ electronic-transition energies, crystal chemistry, and bonding behavior
- Single-crystal UV/Vis optical absorption spectra of almandine-bearing and spessartine garnet: Part II. An analysis of the spin-forbidden bands of Fe2+, Mn2+, and Fe3+
- Single-crystal UV/Vis absorption spectroscopy of aluminosilicate garnet: Part III. {Fe2+} + [Fe3+] → {Fe3+} + [Fe2+] intervalence charge transfer
- A novel method for experiments in a one-atmosphere box furnace
Articles in the same Issue
- A shallow salt pond analog for aqueous alteration on ancient Mars: Spectroscopy, mineralogy, and geochemistry of sediments from Antarctica’s Dry Valleys
- Incorporation of chlorine in nuclear waste glasses using high-pressure vitrification: Solubility, speciation, and local environment of chlorine
- Experimental constraints on miscibility gap between apatite and britholite and REE partitioning in an alkaline melt
- Thermal expansion of minerals in the tourmaline supergroup
- Viscosity of Earth’s inner core constrained by Fe–Ni interdiffusion in Fe–Si alloy in an internal-resistive-heated diamond anvil cell
- The distribution of carbonate in apatite: The environment model
- Low-temperature crystallography and vibrational properties of rozenite (FeSO4·4H2O), a candidate mineral component of the polyhydrated sulfate deposits on Mars
- Hydrothermal fluid signatures of the Yulong porphyry Cu-Mo deposit: Clues from the composition and U-Pb dating of W-bearing rutile
- Magnetic contributions to corundum-eskolaite and corundum-hematite phase equilibria: A DFT cluster expansion study
- Microchemistry and magnesium isotope composition of the Purang ophiolitic chromitites (SW Tibet): New genetic inferences
- Pyrite geochemistry in a porphyry-skarn Cu (Au) system and implications for ore formation and prospecting: Perspective from Xinqiao deposit, Eastern China
- UV/Vis single-crystal spectroscopic investigation of almandine-pyrope and almandinespessartine solid solutions: Part I. Spin-forbidden Fe2+,3+ and Mn2+ electronic-transition energies, crystal chemistry, and bonding behavior
- Single-crystal UV/Vis optical absorption spectra of almandine-bearing and spessartine garnet: Part II. An analysis of the spin-forbidden bands of Fe2+, Mn2+, and Fe3+
- Single-crystal UV/Vis absorption spectroscopy of aluminosilicate garnet: Part III. {Fe2+} + [Fe3+] → {Fe3+} + [Fe2+] intervalence charge transfer
- A novel method for experiments in a one-atmosphere box furnace