Startseite Single-crystal elasticity of phase Egg AlSiO3OH and δ-AlOOH by Brillouin spectroscopy
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Single-crystal elasticity of phase Egg AlSiO3OH and δ-AlOOH by Brillouin spectroscopy

  • Baoyun Wang , Yanyao Zhang , Suyu Fu , Wei Yan , Eiichi Takahashi , Li Li , Jung-Fu Lin und Maoshuang Song
Veröffentlicht/Copyright: 28. Dezember 2021
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American Mineralogist
Aus der Zeitschrift American Mineralogist Band 107 Heft 1

Abstract

Phase Egg and δ-AlOOH are two typical hydrous phases that might exist in the wet sedimentary layer of subducted slabs under mantle conditions. They are thus regarded as potential water carriers to Earth’s deep mantle. In this report, we report the full elastic constants of both phases determined by Brillouin scattering and X-ray diffraction measurements under ambient conditions. Our results indicate that the hydrogen-bond configurations in the crystal structures of the two phases have a profound effect on their principal elastic constants. The adiabatic bulk modulus (KS) and shear modulus (G) calculated from the obtained elastic constants using the Voigt-Reuss-Hill averaging scheme are 158.3(201) GPa and 123.0(60) GPa for phase Egg and 162.9(31) GPa and 145.2(13) GPa for δ-AlOOH, respectively. These results allow us to evaluate elastic moduli and sound velocities of hydrous minerals in the Al2O3-H2O-SiO2 ternary system (simplified composition of subducted wet sedimentary layer) at ambient conditions, including the contrast of the acoustic velocities VP and VS for the reaction AlSi3OH = δ-AlOOH + SiO2 (stishovite) and the evolution in the elastic moduli and sound velocities of hydrous minerals as a function of density.

Keywords: Phase Egg; δ-AlOOH; elasticity; anisotropy; Brillouin spectroscopy

Funding statement: This research at Guangzhou Institute of Geochemistry is financially supported by the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (Grant No. XDB18000000) and the National Natural Science Foundation of China (Grant No. 41874107 and 41574079). J.F.L. acknowledges support from the Geophysics Program of the National Science Foundation, U.S. (EAR-1916941 and EAR-2001381). The single-crystal X-ray diffraction measurements of δ-AlOOH were performed at GSECARS, Advanced Photon Source, Argonne National Laboratory. GSECARS is supported by the National Science Foundation-Earth Sciences (EAR-1634415) and Department of Energy-GeoSciences (DEFG02-94ER14466). This is Contribution No. IS-3099 from GIGCAS.

Acknowledgments

We thank Vincent Lynch at University of Texas X-ray Diffraction Lab for measuring the crystallographic orientations of the phase Egg.

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Received: 2021-03-13
Accepted: 2021-06-25
Published Online: 2021-12-28
Published in Print: 2022-01-27

© 2021 Mineralogical Society of America

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https://doi.org/10.2138/am-2022-8056
Schlagwörter für diesen Artikel
Phase Egg; δ-AlOOH; elasticity; anisotropy; Brillouin spectroscopy

Artikel in diesem Heft

  1. MSA Presidential Address
  2. MSA at 100 and why optical mineralogy still matters: The optical properties of talc
  3. Boron isotope compositions establish the origin of marble from metamorphic complexes: Québec, New York, and Sri Lanka
  4. Celleriite, □(Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), , a new mineral species of the tourmaline supergroup
  5. Jingsuiite, TiB2, a new mineral from the Cr-11 podiform chromitite orebody, Luobusa ophiolite, Tibet, China: Implications for recycling of boron
  6. Incorporation of incompatible trace elements into molybdenite: Layered PbS precipitates within molybdenite
  7. Experimental melt inclusion homogenization in a hydrothermal diamond-anvil cell: Comparison with homogenization at one atmosphere
  8. Thermoelastic properties of zircon: Implications for geothermobarometry
  9. A Rayleigh model of cesium fractionation in granite-pegmatite systems
  10. The atomic arrangement and electronic interactions in vonsenite at 295, 100, and 90 K
  11. Oxalate formation by Aspergillus niger on minerals of manganese ores
  12. High-pressure experimental study of tetragonal CaSiO3-perovskite to 200 GPa
  13. Mesoproterozoic seafloor authigenic glauconite-berthierine: Indicator of enhanced reverse weathering on early Earth
  14. Chemical variability in vyacheslavite, U(PO4)(OH): Crystal-chemical implications for hydrous and hydroxylated U4+, Ca, and REE phosphates
  15. Bennesherite, Ba2Fe2+Si2O7: A new melilite group mineral from the Hatrurim Basin, Negev Desert, Israel
  16. Single-crystal elasticity of phase Egg AlSiO3OH and δ-AlOOH by Brillouin spectroscopy
  17. Letter
  18. On the formation of Martian blueberries
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