New Mineral Names

Acmonidesite*

F. Demartin, C. Castellano, and I. Campostrini (2019) Acmonidesite, a new ammonium sulfate chloride from La Fossa crater, Vulcano, Aeolian Islands, Italy. Mineralogical Magazine 83(1), 137–142.

Acmonidesite (IMA 2013-068), (NH₄,K,Pb²⁺,Na)₉Fe⁴₂⁺(SO₄)₅Cl₈, orthorhombic, is a new mineral discovered in an active fumarole FA (T ~250 °C) at La Fossa crater, Vulcano, Aeolian Islands, Sicily, Italy. It occurs on a pyroclastic breccia with salammoniac, alunite and adranosite as brown prismatic crystals up to 0.1 mm with main forms: {100}, {120}, {011}, {010}, {102}, and no apparent twinning. The mineral has light brown streak, vitreous luster, and no cleavage. No fluorescence under UV radiation was observed. No data on hardness provided; D_meas = 2.56(1), D_calc = 2.551 g/cm³. In plane-polarized transmitted light acmonidesite has intense brown color (pleochroism not mentioned). It is optically biaxial (+), α = 1.580(2), β = 1.590(2), γ = 1.635(2) (white light), 2V_meas = 53(3)° and 2V_calc = 51.6°; X = c, Y = b, Z = a. FTIR spectrum shows strong bands related to the presence of ammonium at 3214 (broad), 2921, 2851, and 1395 cm^–1; typical sulfate absorptions at 740, 1005, 1083, 1137, and 1218 cm^–1. Weak bands at 1620 and 1730 cm^–1 may be due to partial replacement of Cl^– by OH^–. The average of eight electron probe EDS analyses (performed under 20 kV excitation voltage, 10 pA beam current, and 2 μm beam diameter to minimize the damage and deammonation under the beam) on unpolished surface [wt% (range)] is: (NH₄)₂O (by structure) 11.05, K₂O 4.91 (4.28–6.14), Na₂O 2.82 (2.28–3.54), FeO 20.93 (19.51–21.88), MnO 0.42 (0.15–1.24), PbO 10.25 (7.03–12.23), SO₃ 29.67 (27.46–32.51), Cl 20.80 (18.42–23.46), Br 0.45 (0.36–0.51), O=Cl₂ 4.75, total 96.55. The empirical formula based on 28 anions pfu is (NH4)5.77K1.42Pb0.62Na1.24Fe3.962+Mn0.08S5.04O20.16Cl7.97Br0.08.The strongest reflections in the powder X‑ray diffraction pattern are: [d Å (I%; hkl)] 8.766 (100; 110), 1.805 (88; 390), 5.178 (45; 131), 4.250 (42; 221), 2.926 (42; 330), 2.684 (32; 261). The unit-cell parameters refined from the powder data are a = 9.840(1), b = 19.455(2), c = 17.847(2) Å, V = 3416.6 ų. Single-crystal XRD data shows acmonidesite is orthorhombic, space group C2221, a = 9.841(1), b = 19.448(3), c = 17.847(3) Å, V = 3415.7 ų, Z = 4. The crystal structure was refined to final R = 0.0363 for 4614 observed independent I>2σ(I) reflections. The structure contains two different distorted octahedral sites, Fe1 (coordinated by 2 Cl atoms and 4 O atoms of the SO42−groups) and Fe2 (coordinated by 3 Cl atoms and 3 O atoms of the SO42−groups). Chains of four Fe²⁺ distorted octahedra sharing Cl vertexes with other vertexes bridged by three independent SO42−tetrahedra make finite clusters, interacting each other only through the sulfate anions forming a three-dimensional framework with the voids occupied by 4 independent NH₄⁺ ions (2 of them partially replaced by K⁺), one Na⁺/Pb²⁺ site and one Cl^– ion. The name is from Acmonides (from the Greek Ακμωνιδης), one of Ovidius’ Cyclops, helpers of Hephaistos, the mythological god of fire whose forge was alleged to be located at Vulcano. Holotype material is deposited in the Reference Collection of the Dipartimento di Chimica, Università degli Studi di Milano, Italy. D.B.

Ammoniolasalite*

A.R. Kampf, B.P. Nash, P.M. Adams, J. Marthy, and J.M. Hughes (2018) Ammoniolasalite, [(NH₄)₂Mg₂(H₂O)₂₀][V₁₀O₂₈], a new decavanadate species from the Burro Mine, Slick Rock District, Colorado. Canadian Mineralogist, 56(6), 859–869.

Ammoniolasalite (IMA 2017-094), ideally [(NH₄)₂Mg₂(H₂O)₂₀] [V₁₀O₂₈], monoclinic, is a new decavanadate species discovered in the underground Burro mine, Slick Rock district, San Miguel County, Colorado, U.S.A. (38°2ʹ42ʺN 108°53ʹ23ʺW). The mine belongs to a 120 km long arcuate ‘‘Uravan Mineral Belt’’ of bedded or roll-front deposits in sandstone of the Salt Wash member of the Jurassic Morrison Formation. The U and V primary ore mineralization was deposited in strongly reducing environment around accumulations of carbonaceous plant material. Ammoniolasalite along with other decavanadates [V₁₀O₂₈]^6–, protonated decavanadates, [H_xV₁₀O28]^(6x), mixed-valence decavanadates [(Vx4+V10x5+)O28](6+x)and uranium minerals resulted from the postmining oxidation of primary montroseite-corvusite assemblages at ambient temperatures. The ammonium derives from organic matter. The mineral forms crusts generally up to 2 mm thick on montroseite- and corvusite-rich sandstone with ammoniozippeite, and NH₄-bearing decavanadates schindlerite and wernerbaurite. Bright orange to orange yellow ammoniolasalite crystals in the crusts exhibit parallel orientation. They are short prismatic by [101] to equant, often with stepped or skeletal faces. The crystal forms are {001}, {110}, {101}, {111}, {111}, {201}, {311}. The mineral has a light orange streak and a vitreous luster. It mineral does not exhibit any fluorescence in UV radiation. Ammoniolasalite is brittle with conchoidal fracture and no cleavage. Mohs hardness is ~1; D_meas = 2.28(2) and D_calc = 2.278 g/cm³ (2.271 for an ideal formula). At room temperature it is slowly soluble in water (minutes) and rapidly soluble in dilute HCl (seconds). Ammoniolasalite is pleochroic X (yellow) < Y (yellow orange) < Z (orange). It is optically biaxial (–), α = 1.740(3), β = 1.769(3), γ = 1.771(3) (white light), 2V = 31(1)°; Y = b, Z^a = 38° in β obtuse. Dispersion of an optical axes is very strong, r > v. FTIR spectrum is similar to that of lasalite with a broad strong multicomponent feature at ~ 3700–300 cm^–1 (O–H and N–H stretching), and strong peaks around 1700 cm^–1 (H–O–H bending), around 1450 cm^–1 (NH₄ deformation) and around 1000 cm^–1 (VO stretching). The average of four points electron probe WDS analyses on three crystals [wt% (range)] is K₂O 0.95 (0.53–1.16), MgO 6.53 (6.36–6.79), V₂O₅ 76.02 (75.12–76.84), (NH₄)₂O 1.64 (1.34–1.75). Ammoniolasalite is very sensitive to dehydration and deammoniation in air and particularly during separating the crystals from matrix and under vacuum. The data obtained by CHN analysis shows (NH₄)₂O 2.65, H₂O 19.76 wt%. The calculations based on structural study (considering the full occupancy of the NH₄/K site; V = 10 and O = 48 apfu) gave (NH₄)₂O 3.26, and H₂O 25.70 wt%. The empirical formula based on 48 O, 10 V apfu, calculated values for (NH₄)₂O and H₂O, and other elements normalized to provide a total of 100% (i.e. K₂O 0.81, MgO 5.56, V₂O₅ 64.68) is [(NH₄)_1.76K_0.24]_Ʃ2.00Mg_1.94[V₅¹⁰₊ O₂₈]·20H₂O. The strongest lines in the diffraction pattern are [d Å (I%; hkl)]: 10.64 (24; 200), 8.57 (21; 202), 9.43(100; 110,111), 7.62 (26; 002,111), 6.80 (32; 112,311), 2.725 (23; 040,621). Unit-cell parameters refined from the powder data with whole pattern fitting are a = 24.471(9), b = 10.935(9), c = 17.456(9) Å, β = 119.051(14)°, and V = 4083 ų. The single-crystal XRD data shows ammoniolasalite is monoclinic, space group C2/c, a = 24.478(3), b = 10.9413(4), c = 17.5508(12) Å, β = 119.257(7)°, V = 4100.9 ų, Z =4. The structure was solved by direct methods and refined to R₁ = 0.0357 for 3628 I >2σ(I) independent reflections. Ammoniolasalite is isostructural with lasalite, [Na₂Mg₂(H₂O)₂₀][V₁₀O₂₈]. Its atomic arrangement consists of structural unit [V₁₀O₂₈]^6– decavanadate group and interstitial complex [(NH₄,K)₂Mg₂(H₂O)₂₀]⁶⁺. The Mg atoms bond to interstitial-unit H₂O groups and do not share any bonds with the decavanadate group or other polyhedra of the interstitial unit. The (NH₄,K) site links to four H₂O groups and three oxygen atoms of the decavanadate structural group. The occupancy of that site refined from the structure is [(NH₄)_1.30K_0.70]_Ʃ2.00. The difference is assigned to a real variation in the relative amounts of NH₄ and K. The name reflects the chemical composition as NH₄-dominant (over Na) analogue of lasalite. Five cotype specimens are deposited in the Natural History Museum of Los Angeles County, Los Angeles, California, U.S.A. D.B.

Beckettite*, Burnettite*, Paqueite*

C. Ma, J. Paque, and O. Tschauner (2016) Discovery of beckettite, Ca₂V₆Al₆O₂₀, a new alteration mineral in a V-rich Ca-Al-rich inclusion from Allende. 47^th Lunar and Planetary Science Conference, session T335, 1704.

C. Ma and J.R. Beckett (2016) Burnettite, CaVAlSiO₆, and paqueite, Ca₃TiSi₂(Al₂Ti)O₁₄, two new minerals from Allende: clues to the evolution of a V-rich Ca-Al-rich inclusion. 47^th Lunar and Planetary Science Conference, session T335, 1595.

Three new minerals: beckettite (IMA 2015-001), ideally Ca₂V₆Al₆O₂₀, triclinic, a member of aenigmatite group of the sapphirine supergroup; burnettite (IMA 2013-054), ideally CaVAlSiO₆, monoclinic, a member of pyroxene group; paqueite (IMA 2013-053), Ca₃TiSi₂(Al₂,Ti)₃O₁₄, trigonal, were discovered in a V-rich, fluffy Type A Ca-Al-rich inclusion (CAI) A-WP1 (0.6 × 1 mm) in Allende carbonaceous chondrite CV3. Phases of similar compositions were previously mentioned (Paque 1985, 1989) during the study of on the specimen USNM 7617 of the National Museum of Natural History, Smithsonian Institution, Washington, D.C., U.S.A. After completing the chemical and structural (EBSD) studies this specimen is considered as a holotype for all three new mineral species). Ti-rich phase similar to paqueite was characterized in CAIs from the CM2 Essebi chondrite (El Goresy et al. 1984). Burnettite and paqueite form micrometer-sized euhedral crystals within aluminous

melilite (Ak₉ and Ak₁₁, respectively) in A-WP1. Other primary phases in the CAI are spinel, perovskite, grossmanite-davisite, hibonite, and refractory metal grains. Beckettite occurs within highly altered areas of A-WP1 and forms aggregates of grains 48 μm in the central portions of alteration regions composed of fine-grained secondary corundum and grossular with anorthite, coulsonite, hercynite. Burnettite is supposed to be formed in reducing conditions from an ultra-refractory parent. Paqueite could be produced during late-stage dynamic crystallization or could be resulted of exsolution. Beckettite, probably formed in the parent body by the late-stage metasomatic reactions in which grossular, corundum, coulsonite, and hercynite, replace primary phases such as melilite, hibonite, spinel, perovskite, and burnettite. The mineral along with coulsonite might be a product of the destruction of what was a V-rich inclusion in melilite in that same spot. Alternatively, it could be resulted along with corundum from the breakdown of the primary hibonite in a hot V-rich fluid. Physical properties of new minerals were not determined due to a small size. The averages of five electron probe (mode is not specified) analyses for each of species [wt%, (standard deviation)] are: for beckettite, Na₂O 0.04 (0.01), CaO 13.58 (0.15), MgO 1.22 (0.03), FeO 0.35 (0.14), MnO 0.05 (0.06), Al₂O₃ 44.14 (0.29), Sc₂O₃ 0.7 (0.03), V₂O₃ 31.6 (0.1), SiO₂ 2.02 (0.03), TiO₂ 5.54 (0.07), total 99.24, with corresponding empirical formula (Ca_1.99Na_0.01)_Ʃ1.00(V3.473+Al1.40Ti0.574+Mg0.25Sc0.08Fe0.042+Mn0.01)Σ5.82(Al5.72Si0.28)Σ6.00O20based on 20 O pfu; for burnettite /paqueite (deviations or ranges not given): Na₂O– /0.62, CaO 24.83 /29.58, MgO 1.51 /0.18, Al₂O₃ 23.36 /15.21, V₂O₃ 9.35 /1.56, Sc₂O₃ 6.89 /0.84, SiO₂ 25.69 /24.43, TiO₂ 8.49 /27.51, total 100.12 /99.93 with empirical formulae Ca1.04[(V0.293+Sc0.24Ti0.133+Al0.09)Ti0.134+Mg0.08]Σ0.96(Si1.01Al0.99)Σ2.00O6based on 4 cations (with Ti⁴⁺ = Ti³⁺) apfu /(Ca2.91 Na0.11)Σ3.02Ti4+Si2(Al1.64Ti0.904+Si0.24V0.123+Sc0.07Mg0.03)Σ3.00O14based on 14 O pfu. The EBSD patterns of beckettite indexed with best fits obtained using the structure of rhönite. Beckettite is triclinic, space Group: P1, a = 10.367, b = 10.756, c = 8.895 Å, α = 106.0°, β = 96.0°, γ = 124.7°, V = 739.7 ų, Z = 2. The main lines of the calculated powder XRD pattern [(d Å (I%; hkl)] are: 2.684 (60; 241), 2.683 (68; 203), 2.544 (100; 420), 2.541 (81; 242), 2.540 (75; 2 13), 2.104 (84; 251), 2.103 (84; 204), 2.089 (89; 411) (Ma et al. 2015). Burnettite EBSD patterns can only be indexed by a C2/c pyroxene structure. It is monoclinic, space group C2/c, a = 9.80, b = 8.85, c = 5.36 Å, β = 105.62°, Z = 4. The main lines of the calculated powder XRD pattern [(d Å (I%; hkl)] are: 2.996 (100; 221), 2.964 (33; 310), 2.909 (20), 2.581 (41; 002), 2.560 (29; 131), 2.535 (47; 221), 2.131 (19; 331), 1.650 (17; 223) (Ma 2013). For paqueite the EBSD patterns were indexed and gave best fits using the P321 structure of synthetic high-pressure phase Ca₃TiSi₂(Al,Ti,Si)₃O₁₄. Paqueite is trigonal, space group P321, a = 7.943, c = 4.930 Å, Z = 1. The main lines of the calculated powder XRD pattern [(d Å (I%; hkl)] are: 6.879 (20; 010), 3.093 (100; 111), 2.821 (68; 021), 2.600 (21; 120), 2.300 (43; 121), 1.908 (17; 130), 1.789 (28; 122) (Ma 2013). The names of the new minerals honors John R. Beckett, Donald S. Burnett, and Julie M. Paque, cosmochemists at the California Institute of Technology. D.B.

References cited

El Goresy, A., Palme, H., Yabuki, H., Nagel, K., Herrwerth, I., and Ramdohr, P. (1984) A calcium-aluminum-rich inclusion from the Essebi (CM2) chondrite: Evidence for captured spinel-hibonite spherules and for an ultra-refractory rimming sequence. Geochimica et Cosmochimica Acta, 48(11), 2283–2298.El Goresy A., Palme H., Yabuki H., Nagel K., Herrwerth I., Ramdohr P. , 1984"A calcium-aluminum-rich inclusion from the Essebi (CM2) chondrite: Evidence for captured spinel-hibonite spherules and for an ultra-refractory rimming sequence" Geochimica et Cosmochimica Acta, vol. 48, no. 11, p. 2283–2298–.

Ma, C. (2013) Paqueite, IMA 2013-053. Burnettite, IMA 2013-054, CNMNC Newsletter No. 17, October 2013, page 3002; Mineralogical Magazine, 77, 29973005.Ma C. , 2013"Paqueite, IMA 2013-053" Burnettite, IMA 2013-054, CNMNC Newsletter No. 17, October 2013, page 3002; Mineralogical Magazine, vol. 77, p. 29973005–.

Ma, C., Paque, J. and Tschauner, O. (2015) Beckettite, IMA 2015-001. CNMNC Newsletter No. 25, June 2015, page 531; Mineralogical Magazine, 79, 529535.Ma C., Paque J. and Tschauner O. , 2015"Beckettite, IMA 2015-001" CNMNC Newsletter No. 25, June 2015, page 531; Mineralogical Magazine, vol. 79, p. 529535–.

Paque, J.M. (1985) A vanadium-rich fluffy type a Ca-A1-rich inclusion in Allende. Abstracts of papers submitted to the 16^th Lunar and Planetary Science Conference March 11–15, 1985, 651.Paque J.M. , 1985"A vanadium-rich fluffy type a Ca-A1-rich inclusion in Allende" Abstracts of papers submitted to the 16^th Lunar and Planetary Science Conference March, vol. 11–15, no. 1985, p. 651–.

——— (1989) Vanadium-rich refractory platinum metal nuggets from a fluffy Type A inclusion in Allende. Abstracts of papers submitted to the 20^th Lunar and Planetary Science Conference March 13–17, 1989, 822.———, 1989"Vanadium-rich refractory platinum metal nuggets from a fluffy Type A inclusion in Allende" Abstracts of papers submitted to the 20^th Lunar and Planetary Science Conference March, vol. 13–17, p. 822–.

Elasmochloite*

I.V. Pekov, S.N. Britvin, A.A. Agakhanov, M.F. Vigasina, and E.G. Sidorov (2019) Elasmochloite, Na₃Cu₆BiO₄(SO₄)₅, a new fumarolic mineral from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 31(5-6), 1025–1032.

Elasmochloite (IMA 2018-015), ideally Na₃Cu₆BiO₄(SO₄)₅, monoclinic, was discovered in a single specimen collected in July 2013 at a depth of ~1 m in the central part of Arsenatnaya fumarole, the Second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Kamchatka. It is a new representative of a hydrogen-free alkali-copper oxysulfates family deposited directly from hot gas at temperatures not lower that 350–400 °C. The new mineral is associating with tenorite, hematite, langbeinite, aphthitalite, krasheninnikovite, and johillerite. Elasmochloite forms lamellar quadratic or rectangular with cut vertices crystals up to 0.005 × 0.07 × 0.1 mm flattened on [001], either separate or combined into open-work clusters up to 0.3 mm or interrupted crusts up to 1 × 1 mm on a surface of basalt scoria altered by fumarolic gas. Elasmochloite is green, transparent with a strong vitreous luster and a pale greenish streak. It is brittle with uneven fracture and no cleavage or parting observed. The Mohs hardness and density were not measured due to small crystal size and the open-work nature of aggregates; D_calc = 3.844 g/cm³. Elasmochloite is strongly pleochroic O (grass-green) > E (turquoise-blue), optically pseudo-uniaxial (–), α = 1.611(2), β = γ = 1.698(2), 2V ≈ 0° (589 nm). The bands in the Raman spectrum (cm^–1; s – strong) are: 1283s, 1208, 1098 [F₂(ν₄) bending of [SO42−]1039, 1010s, 996s [A₁(ν₁) symmetric stretching of SO42−].668, 627, 584 [F₂(ν₄) bending of SO42−],503, 445 [E(ν₂) bending of SO42−],268, 190s, and 124 (lattice modes). The features at 550–250 cm^–1 can also be assigned to Bi³⁺–O and Cu²⁺–O stretching vibrations. The absence of bands with frequencies higher than 1300 cm^–1 indicates the absence of groups with O–H, C–H, C–O, N–H, and N–O bonds. The averaged 7 point WDS electron probe analyses is [wt%, (range)]: Na₂O 6.67 (6.50–6.87), K₂O 0.82 (0.70–0.90), CuO 38.77 (38.37–39.34), ZnO 0.25 (0.00–1.06), PbO 3.17 (2.75–3.64), Bi₂O₃ 17.66 (17.17–18.84), SO₃ 32.81 (32.42–33.04), total 100.15. The empirical formula based on 24 O atoms pfu is Na_2.63K_0.21Cu_5.96Zn_0.04Bi_0.93 S_5.01O₂₄. The strongest lines of the powder X‑ray diffraction pattern are [d Å (I%; hkl)]: 10.33 (100; 002), 7.04 (18; 110,111), 6.33 (14; 111,112), 3.576 (24; 221), 2.920 (14; 225), 2.529 (14; 402,040), 2.460 (14; 227). The single-crystal XRD data shows elasmochloite is monoclinic (pseudo-tetragonal), P21/n, a = 10.1273(9), b = 10.1193(8), c = 21.1120(16) Å, β = 102.272(8)°, V = 2114.1 ų, Z = 4. The crystal structure solved by dual space method and refined to R₁ = 20.6% is considered only as a model. Despite high R₁ value, the reliable values of thermal displacement parameters and interatomic distances, good values of bond-valence sums, good agreement between measured and calculated powder XRD patterns, zero charge balance in the structural formula and its agreement with electron microprobe data, confirm that the crystal structure model is correct. It is a novel structure, and contains two types of alternating polyhedral layers: (1) “copper-bismuth slabs” composed by [BiO₄O₂] polyhedra, [CuO₅] square pyramids and [CuO₄] squares and (2) “sodium slabs” consisting of [NaO₅] and [NaO₆] polyhedra. All cationic polyhedral and linked by corner-sharing [SO₄] tetrahedra. Elasmochloite has some common structural features with nabokoite KCu₇Te⁴⁺O₄(SO₄)₅Cl and favreauite PbCu₆BiO₄(Se⁴⁺O₃)₄(OH)·H₂O. The name is based on the Greek words ελασμα, meaning lamella, and χλοη, meaning the green shoot or green grass, thus alluding to elasmochloite’s green color and lamellar crystal habit. The type specimen is deposited in the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia. Yu.U.

Grammatikopoulosite* and Tsikourasite*

L. Bindi, F. Zaccarini, E. Ifandi, B. Tsikouras, C. Stanley, G. Garuti, and D. Mauro (2020) Grammatikopoulosite, NiVP, a new phosphide from the chromitite of the Othrys ophiolite, Greece. Minerals, 10(2), 131.

F. Zaccarini, L. Bindi, E. Ifandi, T. Grammatikopoulos, C. Stanley, G. Garuti, and D. Mauro (2019) Tsikourasite, Mo₃Ni₂P_1+x (x < 0.25), a new phosphide from the chromitite of the Othrys ophiolite, Greece. Minerals, 9(4), 248.

Two new phosphides: grammatikopoulosite (IMA 2019-090), NiVP, orthorhombic, and tsikourasite (IMA 2018-156), Mo₃Ni₂P_1+x (x < 0.25), cubic, were discovered in a heavy mineral concentrate separated from podiform chromitite hosted in strongly serpentinized dunite from a mantle tectonite composed of harzburgite and minor intercalations of plagioclase-bearing lherzolite. The main chromitite constituent is magnesiochromite. The interstitial assemblage is pervasively replaced by chlorite and hydrogrossular and minor talc and serpentine. Locally, hydrogarnet fills veins up to 50 μm thick crosscutting magnesiochromite. These veins are presumably associated with the rodingitized gabbro cross-cutting chromitites. Rare titanite, kammererite, pentlandite, and millerite also occur in the hydrogarnet veins. The genetic models of phosphide precipitation are discussed. The concentrate obtained by processing (crushing, treating with heavy liquid, panning, etc.) of ~10 kg of massive chromitite collected in the abandoned mine of Agios Stefanos ~10 km south of Domokos village, Mesozoic Othrys ophiolite complex, central Greece. The heavy minerals were prepared in epoxy blocks. No source of contamination is likely during sampling and subsequent treatments. In the polished sections grammatikopoulosite and tsikourasite occur as generally isolated grains less than 10 μm rarely up to ~80 μm. In poly-phase grains they associated with each other and nickelphosphide, awaruite and potential new minerals (under study) such as Ni-allabogdanite or Ni-barringerite and V-sulfide. Other minerals in polished sections include PGM:Ru-Os-Ir-Ni alloys, laurite, erlichmanite, Pd-Sb-Cu alloys, Pd-Cu-Pt alloys, irarsite, platarsite, hollingworthite, merenskyite, and cooperite-braggite. Both new minerals have metallic luster, are opaque and brittle. Density and hardness were not measured due to small size. Other properties and characteristics are as follows:

Grammatikopoulosite in reflected light is creamy-yellow, weakly bireflectant, with measurable but not discernible pleochroism and slight anisotropy with indeterminate rotation tints. Internal reflections were not observed. Reflectance values in air (R₁/R₂% λ nm) are (COM wavelengths are bolded): 47.6/48.8 400, 47.9/49.1 420, 48.3/49.4 440, 48.6/49.9 460, 48.8/50.3 470, 49.0/50.7 480, 49.4/51.5 500, 49.9/52.4 520, 50.3/53.3 540, 50.5/53.5 546, 50.9/54.1 560, 51.4/54.9 580, 51.7/55.2 589, 51.9/55.5 600, 52.4/56.2 620, 53.0/56.8 640, 53.2/57.1 650, 53.8/58.0 680, 54.2/58.6 700. The average of five spot electron probe WDS analyses [wt% (range)] is: Ni 21.81 (21.69–21.98), Co 16.46 (16.33–16.66), Fe 3.83 (3.78–3.86), V 20.85 (20.48–21.05), Mo 16.39 (16.20–16.72), Si 0.14 (0.13–0.16), P 19.90 (19.65–20.38), S 0.41 (0.39–0.42), total 99.79. The empirical formula based on ΣMetals = 2 apfu, and considering structural results is M¹(Ni_0.57Co_0.32Fe_0.11)_Σ1.00M²(V_0.63Mo_0.26Co_0.11)_Σ1.00(P_0.98S_0.02)_Σ1.00. The strongest X‑ray powder diffraction lines are [d Å (I%; hkl)]: 4.43 (10; 101), 2.950 (20; 102), 2.785 (25; 111), 2.273 (60; 112), 2.157 (100; 211), 2.118 (25; 103), 1.784 (20; 020). The unit-cell parameters refined from the powder data are a = 5.8088(2), b = 3.5993(2), c = 6.8221(3) Å, V = 142.63 ų. The single-crystal XRD data shows grammatikopoulosite is orthorhombic, space group Pnma, a = 5.8893(8), b = 3.5723(4), c = 6.8146(9) Å, V = 143.37 ų, Z = 4; D_calc = 7.085 g/cm³. The structure was refined (starting from the atomic coordinates of allabogdanite FeNiP) to R₁ = 0.0276 for 465 F_o>4σ(F_o) reflections. Grammatikopoulosite belongs to the group of natural phosphides (florenskyite FeTiP, allabogdanite (Fe,Ni)₂P, and andreyivanovite FeCrP) with the Co₂Si structure. In the structure M 1 links four P atoms and eight M2, whereas M2 links five P, six M 1, and two M2. The M–P distances are much shorter in the M 1 coordination sphere than in that of M 2. If only the M–P distances are considered in the coordination polyhedra of the M atoms, M 1P₄ tetrahedra forming corner-sharing chains along the b-axis or M2P₅ square pyramids forming zigzag chains along the a-axis can be observed. The mineral name honors Tassos Grammatikopoulos (b. 1966), geoscientist at the SGS Canada Inc., for his contribution to the economic mineralogy and mineral deposits of Greece. Holotype material is deposited in the Museo di Storia Naturale, Università di Pisa, Italy.

Tsikourasite in reflected light is white yellow with no bireflectance, anisotropism or pleochroism. Internal reflections were not observed, Reflectance values in air (R% λ nm) are (COM wavelengths are bolded): 54.6 400, 54.9 420, 55.2 440, 55.5 460, 55.7 470, 55.8 480, 56.1 500, 56.4 520, 56.7 540, 56.8 546, 57.0 560, 57.3 580, 57.5 589, 57.6 600, 58.0 620, 58,3 640, 58.5 650, 58.6 660, 58.9 680, 59.2 700. The average of five spot electron probe WDS analyses [wt% (range)] is: Ni 23.9 (23.77–24.16), Co 7.59 (7.53–7.72), Fe 1.18 (1.14–1.20), V 14.13 (13.98–14.19), Mo 44.16 (43.56–44.65), P 7.97 (7.59–8.20), S 0.67 (0.64–0.71), total 99.60. The empirical formula based on ƩMetals = 5 apfu and considering the structural data is (Mo_1.78V_1.07Fe_0.08Co_0.07)_Ʃ3.00(Ni_1.57Co_0.43)_Ʃ2.00(P_0.98S_0.08)_Ʃ1.06. The powder XRD data was not obtained. The strongest lines of the calculated X‑ray powder diffraction pattern are [d_calc Å (I_calc%; hkl)]: 2.705 (13; 400), 2.483 (12; 331), 2.209 (42; 422), 2.083 (65; 422), 2.083 (35; 511), 1.913 (21; 440), 1.275 (14; 660), 1.275 (17; 822). The single-crystal study shows tsikourasite is cubic, space group F43m, a = 10.8215(5) Å, Z = 16; D_calc = 9.182 g/cm³. The crystal structure was refined (starting from the atom coordinates of the Mo₃Ni₂P_1.16 compound synthesized at 1350 °C) to R₁ = 0.0188 for 216 I >2σ(I) reflections. The tsikourasite structure shows numerous metal–metal bonds (Ni–Ni, Mo–Ni, and Mo–Mo) in contrast to Mo–P and Ni–P bonds. The metal atoms are connected to only two or three P atoms, whereas 12 or 6 metal atoms surround the P1 and P2 sites, respectively. In the structure Mo atoms are arranged as [PMo₆]-octahedra in a diamond-like network. Half of the octahedra, which are built by Mo2 atoms, are empty, while the second half formed by Mo1 atoms are occupied by P2, which shows partial occupancy (20%). These occupied octahedra are displayed in an fcc array. Unlike tsikourasite, similar in composition, monipite MoNiP, polekhovskyite MoNiP₂, and synthetic MoNiP₂ are hexagonal. Tsikourasite could represent the Mo equivalent of the grains of composition (Ni,Fe)₅P recently found in chromitites of the Alapaevsk (Russia) and Gerakini-Ormylia (Greece) ophiolites (Sideridis et al. 2018). The mineral honors Basilios Tsikouras (b. 1965) of the Universiti Brunei Darussalam for his contributions to the ore mineralogy and mineral deposits related to ophiolites. The type material is deposited in the Museo di Storia Naturale, Università di Firenze, Italy. D.B.

References cited

Sideridis, A., Zaccarini, F., Grammatikopoulos, T., Tsitsanis, P., Tsikouras, B., Pushkarev, E., Garuti, G., and Hatzipanagiotou, K. (2018) First occurrences of Ni-phosphides in chromitites from the ophiolite complexes of Alapaevsk, Russia and GerakiniOrmylia, Greece. Ofioliti, 43, 75–84.Sideridis A., Zaccarini F., Grammatikopoulos T., Tsitsanis P., Tsikouras B., Pushkarev E., Garuti G., Hatzipanagiotou K. , 2018"First occurrences of Ni-phosphides in chromitites from the ophiolite complexes of Alapaevsk, Russia and GerakiniOrmylia, Greece" Ofioliti, vol. 43, p. 75–84–.

Halamishite*, Murashkoite*, Negevite*, Transjordanite*, Zuktamrurite*

S.N. Britvin, M. Murashko, Y. Vapnik, Y.S. Polekhovsky, S.V. Krivovichev, O.S. Vereshchagin, V.V. Shilovskikh, N.S. Vlasenko, and M.G. Krzhizhanovskaya (2020) Halamishite, Ni₅P₄, a new terrestrial phosphide in the Ni–P system. Physics and Chemistry of Minerals, 47, 3.

S.N. Britvin, Y. Vapnik, Y.S. Polekhovsky, S.V. Krivovichev, M.G. Krzhizhanovskaya, L.A. Gorelova, O.S. Vereshchagin, V.V. Shilovskikh, and A.N. Zaitsev (2019) Murashkoite, FeP, a new terrestrial phosphide from pyrometamorphic rocks of the Hatrurim Formation, South Levant. Mineralogy and Petrology, 113(2), 237–248.

S.N. Britvin, M.N. Murashko, Ye. Vapnik, Y.S. Polekhovsky, S.V Krivovichev, O.S. Vereshchagin, V.V. Shilovskikh, and M.O. Krzhizhanovskaya (2020) Negevite, the pyrite-type NiP₂, a new terrestrial phosphide. American Mineralogist, 105(3), 422–427.

S.N. Britvin, M.N. Murashko, Ye. Vapnik, Y.S. Polekhovsky, S.V. Krivovichev, M.O. Krzhizhanovskaya, O.S. Vereshchagin, V.V. Shilovskikh, and N.S. Vlasenko (2020) Transjordanite, Ni₂P, a new terrestrial and meteoritic phosphide, and natural solid solutions barringerite-transjordanite (hexagonal Fe₂P–Ni₂P). American Mineralogist, 105(3), 428–436.

S.N. Britvin, M. Murashko, Y. Vapnik, Y.S. Polekhovsky, S.V. Krivovichev, O.S. Vereshchagin, N.S. Vlasenko, V.V. Shilovskikh, and A.N. Zaitsev (2019) Zuktamrurite, FeP₂, a new mineral, the phosphide analogue of löllingite, FeAs₂. Physics and Chemistry of Minerals, 46, 361–369.

Five new natural, terrestrial phosphides: halamishite (IMA 2013-105), Ni₅P₄, hexagonal; murashkoite (IMA 2012-071), FeP, orthorhombic; negevite (IMA 2013-104) NiP₂, cubic; transjordanite (IMA 2013-106), Ni₂P, hexagonal; and zuktamrurite (IMA 2013-107), orthorhombic were discovered in pyrometamorphic assemblages of the Hatrurim Formation (“Mottled Zone”). This is the world’s largest, geologically juvenile suite of pyrometamorphic rocks exposed across 150 × 200 km territory in the surroundings of the Dead Sea, in Israel, Palestinian Authority, and Jordan. The chalky-marly sediments of the Hatrurim formation underwent extensive and repetitive high-temperature (500–1350 °C) and low-pressure (~1 bar) metamorphism ~2.3–4 Ma. Two most popular hypothesis are explaining high temperature and (in a number of cases) strongly reducing environment as a result of burning bituminous rich sedimentary units or a result of a firing of hydrocarbons (mostly methane) from mud volcano explosions initiated by tectonic activity at the Dead Sea transform fault. Phosphides were usually considered as having meteoritic origin. Finding a bunch of new terrestrial phosphides along with previously found in the rocks of Hatrurim formation schreibersite, Fe₃P, and barringerite, Fe₂P, shows a wide variability of the M/P ratios making it substantially distinct from meteoritic minerals. Phosphide associations of the “Mottled Zone” are Earth’s richest example of the parageneses bearing siderophile rather than lithophile phosphorus. Two phosphide-bearing locations were found on both sides of the Dead Sea (Levantine) Transform Fault at Nahal Halamish (Halamish wadi), southern part of the Hatrurim Basin, Negev Desert, Israel (31° 09′ 47″ N; 35° 17′ 57″ E) and in phosphorite quarry at the Daba-Siwaqa complex, Transjordan Plateau, Al-Rasas Sub-District, 80 km SSE of Amman, Jordan (31°21′ 52″; N, 36° 10′ 55″ E). The distance between location ~100 km. At the Halamish wadi phosphides are disseminated in fine-grained in hydrothermally altered micro-breccia consisting on colorless almost pure diopside (~50–60 vol%). Other associated minerals are merrillite, Cu-trevorite, hematite, magnetite, pyrrhotite, troilite, hydrous X‑ray amorphous silicates and hydroxides of Ca, Mg, Fe, Ni, Ca-carbonates and sulfates. The interstices are filled with secondary calcite, fluorapatite, smectites and unidentified hydrous Ca–Fe–Ni–Mg phosphates. Halamishite (grains up to 20 μm) and negevite (grains up to 15 μm) are closely associated with zuktamrurite (grains ~10 μm, rarely up to 50 μm, sometimes hosting lamellae of molybdenite), transjordanite (irregular grains up to 0.2 mm), murashkoite (grains 10–200 μm, rarely up to 2 mm often intergrown with barringerite), and unnamed nickel phosphide–sulfide. Murashkoite also forms dendritic aggregates in the matrix of hydrous silicates. In Daba-Siwaqa complex same phosphide association (besides halamishite) found disseminated in centimeter-sized veins of medium-grained clinopyroxene (diopside-hedenbergite)-anorthite paralavas of gabbro-dolerite compositions cross-cutting heterogeneous calcined marble conglomerates. Subordinate minerals of paralavas are gehlenite, tridymite, cristobalite with accessory magnetite, troilite, pyrrhotite, hematite, merrillite, and fluorapatite. This primary association partially substituted by a late, low-temperature carbonates, silicates, and sulfates. Transjordanite was also found in iron ungrouped meteorite Cambria found in 1818 nearby Lockport, Niagara County, New York, U.S.A., where recrystallized microgranular (10–20 μm) troilite stuffed with fragments of finely brecciated schreibersite frequently encrusted with 5–10 μm thick, onion-like rims composed of sub-microcrystalline transjordanite-barringerite aggregate with the grain size less than 0.5 μm.

Halamishite is dark gray, transjordanite is grayish-white or gray and murashkoite is yellowish-gray. In reflected light they are white with a beige tint. Macroscopical colors are not given for zuktamrurite and negevite due to its small size but in reflected light both are white with bluish tint more distinctive for transjordanite. All five new phosphides have metallic luster, are non-pleochroic, brittle (its grains are usually fractured) with no evidence of cleavage. The density values were not measured. Micro-indentation hardness data were obtained for murashkoite (VHN₂₀ = 468 kg/mm², corresponding to ~5 of Mohs scale) and for transjordanite (658 kg/mm²). Other characteristics are as follows:

Halamishite, is moderately anisotropic and bireflectant (ΔR589 = 7.2%). The reflectance values [R_max/R_min% λ nm] COM wavelengths are bolded: 40.3/34.5 400; 41.5/35.2 420; 42.5/36.3 440; 43.7/37.3 460; 44.3/36.6 470; 44.8/35.8 480; 46.2/39.6 500; 47.7/40.7 520; 48.9/41.9 540; 49.2/42.1 546; 50.0/42.7 560; 50.9/43.7 580; 51.3/44.1 589; 51.7/44.5 600; 52.4/45.3 620; 53.0/45.8 640; 53.3/46.1, 650; 53.6/46.5 660; 54.2/46.9 680; 55.0/47.5 700. The average of three electron probe EDS analyses of the holotype (wt%): Ni 69.23, Fe 1.80, P 29.59, total 100.62 (ranges or deviations are not given). The empirical formula based on 9 atoms pfu is (Ni_4.90Fe_0.13)_5.03P_3.97. D_calc = 6.249 g/cm³. Powder XRD data was not obtained. The strongest lines in the calculated XRD powder pattern [d_calc Å (I_calc%; hkl)] are: 3.121 (45; 103), 2.953 (56; 200), 2.498 (57; 104), 2.069 (57; 212), 2.015 (88; 204), 1.938 (69; 301), 1.908 (77; 213), 1.735 (100; 214), 1.705 (58; 220). The single-crystal XRD data obtained on a grain of 0.01 × 0.01 × 0.01 mm shows halamishite is hexagonal, space group P63mc, a = 6.8184(4), c = 11.0288(8) Å, V = 444.04 ų, Z = 4. The crystal structure was solved and refined to R₁ = 0.031 based on 425 unique observed [I≥2σ(I)] reflections. It contains eight unique Ni and P sites. A distinguished feature of halamishite structure is a short P–P bond (2.196 Å) “P–P dumbbell” similar to S–S dumbbells in sulfide structures. The synthetic Ni₅P₄, analogue of halamishite is widely used in electro- and photocatalytic applications. Due to chemical proximity to the Ni₅P₄, end-member, halamishite can be used as a geothermometer indicating that formation of phosphide assemblages had occurred at a temperature below 870 °C. The mineral was named for its type locality, the Halamish wadi. The holotype is deposited at the Mineralogical Museum of the Department of Mineralogy, St. Petersburg State University, St. Petersburg, Russia.

Murashkoite is weakly bireflectant ΔR(589 nm) = 1.2% and distinctly anisotropic with rotation tints from yellow-gray to grayish blue. The reflectance values [R_max/R_min% λ nm] interpolated COM wavelengths are bolded: 42.7/40.8 400; 41.9/40.0 420; 41.5/39.8 440; 41.6/39.9 460; 41.65/40.0 470; 41.7/40.1 480; 42.0/40.6 500; 42.2/40.7 520; 42.7/41.5 540; 42.9/41.7 546; 43.3/42.1 560; 43.9/42.7 580; 44.2/43.0 589; 44.5/43.4 600; 45.2/44.3 620; 45.9/45.2 640; 46.3/45.6, 650; 46.6/46.0 660; 47.2/46.9 680; 48.0/47.7 700. The ranges for representative chemical compositions (electron probe, EDS) selected from over 100 analysis (wt%) are: Fe 51.63–64.34, Ni 0–13.25, P 34.84–36.49 (Co below 0.05%). The average of unspecified number of holotype analyses is (wt%) Fe 63.82, Ni 0.88, P 35.56, total 100.26; with corresponding empirical formula based on 2 apfu: (Fe_0.99Ni_0.01)_1.00P_1.00. D_calc = 6.108 g/cm³. The strongest lines of the powder XRD pattern [d Å (I%; hkl)] are: 2.831 (75; 011,002), 2.548 (22; 200), 2.477 (46; 102,111), 1.975 (47; 112), 1.895 (100; 202,211), 1.779 (19; 103), 1.632 (45; 013,301,020). The unit-cell parameters refined from the powder data are a = 5.098(5), b = 3.251(1), c = 5.699(3) Å, V = 94.5 ų. The single-crystal XRD data obtained on a crystal of 0.05 × 0.06 × 0.12 mm shows murashkoite is orthorhombic, space group Pnma, a = 5.099(2), b = 3.251(2), c = 5.695(2) Å, V = 94.41 ų, Z = 4. The crystal structure was solved and refined to R₁ = 0.0305 for 131 unique I>2σ(I) reflections. Murashkoite crystallizes in the MnP structure type, which is an orthorhombically distorted homeotype of the hexagonal aristotype structure of nickeline, NiAs. The crystal structure of murashkoite is based upon layers of Fe and P atoms alternating along the a axis. The layer of Fe atoms is a distorted planar 3⁶ net consisting of chains of Fe-Fe atoms extended along the b axis. The layer of P atoms is a non-planar 3⁶ net with no P-P contacts shorter than 3 Å. The coordination of Fe is a distorted FeP₆ octahedron complemented by four additional Fe-Fe bonds. The P site is in distorted trigonal prismatic coordination by six Fe atoms complemented by two P-P. Murashkoite is the phosphide analogue of westerveldite, FeAs, and belongs to the modderite group being an only phosphide there. Murashkoite is a natural counterpart of synthetic FeP, the compound widely used in heterogeneous catalysis and electrocatalysis. The mineral name honors Mikhail Nikolaevich Murashko (b. 1952), for his contributions to the mineralogy of the Hatrurim Formation. The holotype specimen of is deposited in the Museum of the Mining Institute (Technical University), St. Petersburg, Russia.

Negevite is isotropic with no internal reflections. The reflectance values with bolded COM wavelengths [R%, λ nm] are: 53.6 400, 53.9 420, 54.3 440, 54.5 460, 54.6 470, 54.6 480, 54.8 500, 54.9 520, 55.0 540, 55.0 546, 55.1 560, 55.2 580, 55.3 589, 55.3 600, 55.4 620, 55.5 640, 55.6 650, 55.7 660, 55.6 680, 55.8 700. The ranges for selected representative chemical compositions (electron probe, WDS) (wt%) are: Fe 2.876.41, Ni 37.77–42.57, Co 2.92–3.40, Ag 0–1.01, P 39.51–42.93, S 8.33–12.78, Se 0–0.24. The average of unspecified number of holotype analyses is (wt%) Fe 2.87, Ni 42.57, Co 3.40, P 42.93, S 8.33, total 100.10; with corresponding empirical formula based on 3 apfu: (Ni_0.88Co_0.07Fe_0.06)_Ʃ1.01 (P_1.68S_0.31)_Ʃ1.99. D_calc = 4.881 g/cm³. Negevite is insoluble in cool 10% HCl. Powder XRD data was not obtained. The strongest lines in the calculated XRD powder pattern [d_calc Å (I_calc%; hkl)] are: 3.165 (54; 111), 2.741 (95; 002), 2.451 (42; 012), 2.238 (35; 112), 1.938 (54; 022), 1.653 (100; 113), 1.582 (17; 222), 1.465 (17; 123). Single-crystal XRD data obtained on a grain ~10 μm shows negevite is cubic, space group Pa3, a = 5.4816(5) Å, V = 164.71(3) ų, Z = 4. The crystal structure was solved by direct methods and refined to R₁ = 1.73% for 52 observed independent I>2σ(I) reflections. Negevite is the first natural phosphide of the pyrite structure type. It is a structural analog of vaesite (NiS₂), krutovite (NiAs₂), and penroseite (NiSe₂). The synthetic counterpart of negevite has well-explored catalytic and photocatalytic properties. Negevite is named for its type locality in the Negev Desert, Israel The holotype is deposited in the Mineralogical Museum of the St. Petersburg State University, Russia.

Transjordanite is weakly bireflectant ΔR(589 nm) = 1.8% and weakly anisotropic. The reflectance values [R_max/R_min% λ nm], COM wavelengths are bolded: 41.0/40.2 400; 42.2/41.1 420; 43.2/42.4 440; 44.5/43.5 460; 45.1/44.2 470; 45.7/44.8 480; 47.1/46.1 500; 48.3/47.3 520; 49.6/48.3 540; 49.9/48.5 546; 50.7/49.1 560; 51.6/49.9 580; 52.1/50.3 589; 52.6/50.8 600; 53.4/51.4 620; 54.0/51.9 640; 54.3/52.1 650; 54.5/52.3 660; 55.0/52.6 680; 55.5/53.0 700. A complete series of natural solid solutions exists between transjordanite (Ni₂P) and barringerite (Fe₂P) end-members. Variations of other elements (wt%) are: P 20.39–21.72, Co 0–3.09, Mo 0–3.09, and S up to 0.27 (in Cambria meteorite). The averages of unspecified numbers of electron probe WDS analysis of transjordanite from holotype /Cambria meteorite (wt%) are: Ni 67.80 /60.55, Fe 10.20 /18.16, Co 0 /0.26, P 21.50 /20.53, S 0 /0.27, total 99.50 /99.77. Corresponding empirical formulae based on 3 apfu are (Ni_1.72Fe_0.27)_Ʃ1.99P_1.02 /(Ni1.52Fe0.48Co0.01)Ʃ2.01(P0.98S0.01)Ʃ0.99. D_calc = 7.297(5) g/cm³. The strongest lines of the powder XRD pattern [(d Å (I%; hkl)] are: 2.211 (100; 111), 2.028 (42; 201), 1.926 (37; 210), 1.697 (21; 300), 1.676 (18; 002), 1.672 (18; 211), 1.264 (15; 212), 1.192 (15; 302), 1.104 (20; 321). Single-crystal study on a grain 0.08 × 0.06 × 0.05 mm shows transjordanite is hexagonal, space group P62m; unit-cell parameters for the holotype are: a = 5.8897(3), c = 3.3547(2) Å, V = 100.78 ų, Z = 3. The crystal structure was solved and refined to R₁ = 0.013 for 190 observed independent I>2σ(I) reflections. It consists of two types of infinite rods propagated along the c axis. The first rod is composed of corner-sharing M (1)P₄ tetrahedra alternating with the empty square pyramids ◻P5. The next rod is built up of edge-sharing M (2)P₅ square pyramids alternating with the empty tetrahedra ◻P4. The rods are arranged into a framework via common P–P edges of adjacent metal-phosphorus polyhedra. The mineral was named for the type locality on the Transjordan Plateau in West Jordan. The holotype is deposited at the Mineralogical Museum of the St. Petersburg State University, Russia.

Zuktamrurite is weakly bireflectant ΔR(589 nm) = 2.8% and distinctly anisotropic with bluish rotation tints. The reflectance values (R_max/R_min% λ nm), interpolated COM wavelengths are bolded: 52.5/49.8 400; 51.8/48.9 420; 51.2/48.2 440; 50.6/47.5 460; 50.4/47.2 470; 50.2/46.9 480; 49.8/46.7 500; 49.5/46.4 520; 49.2/46.3 540; 49.16/46.23 546; 49.0/46.2 560; 49.0/46.2 580; 48.97/46.16 589; 49.0/46.2 600; 49.1/46.2 620; 49.3/46.3 640; 49.40/46.40 650; 49.5/46.5 660; 49.8/46.7 680; 50.0/47.0 700. The ranges for 20 selected representative electron probe EDS analyses (wt%) are: Fe 37.37–46.76, Ni 1.37–9.84, Co 00.69, P 47.50–53.74). S 0–4.52. The average of five-point analyses of holotype is (wt%) Fe 40.23, Ni 7.97, P 51.70, total 99.90; with corresponding empirical formulae based on 3 apfu: (Fe_0.86Ni_0.16)_1.02P_1.98. D_calc = 5.003 g/cm³. The strongest lines of the powder XRD pattern [(d Å (I%; hkl)] are: 3.714 (54; 110), 2.820 (31; 020), 2.451 (100; 120,101), 2.259 (25; 210), 2.242 (55; 111); 1.760 (37; 211), 1.579 (23; 310), 1.564 (26; 031). The unit-cell parameters refined from the powder data are a = 4.927(5), b = 5.645(1), c = 2.815(3) Å, V = 78.3 ų. The single-crystal XRD data obtained on a crystal of 0.01 × 0.01 × 0.01 mm shows zuktamrurite is orthorhombic, space group Pnnm, a = 4.9276(6), b = 5.6460(7), c = 2.8174(4) Å, V = 78.38 ų, Z = 2. The crystal structure was solved by direct methods and refined to R₁ = 0.0121 based on 109 unique I>2σ(I) reflections. Zuktamrurite is the phosphide analogue of löllingite FeAs₂. Distorted octahedra MP₆ (M = Fe,Ni) are arranged sharing common edges into infinite chains propagated along the c axis. The length of the c axis corresponds to the shortest M–M distance. Octahedra belonging to adjacent chains are connected via shared corners forming a three-dimensional framework. The characteristic feature of zuktamrurite structure is the occurrence of P–P bonds like the S–S in the marcasite. The P–P dumbbell in zuktamrurite plays the role of the anion and its structural formula can be written as Fe²⁺[P₂]²⁻. Zuktamrurite is the most phosphorus-rich phosphide found in nature so far. The mineral is named for the Zuk-Tamrur cliff (Dead Sea) located nearby the type locality (Halamish Wadi). The holotype specimen is deposited in the Mineralogical Museum of Saint-Petersburg State University, St. Petersburg, Russia. D.B.

Kamenevite*

I.V. Pekov, N.V. Zubkova, V.O. Yapaskurt, D.I. Belakovskiy, I.S. Lykova, S.N. Britvin, A.G. Turchkova, and D.Y. Pushcharovky (2019) Kamenevite, K₂TiSi₃O₉⋅H₂O, a new mineral with microporous titanosilicate framework from the Khibiny alkaline complex, Kola peninsula, Russia. European Journal of Mineralogy, 31(3), 557–564.

Kamenevite (IMA 2017-021), ideally K₂TiSi₃O₉⋅H₂O, orthorhombic, was discovered in K-rich peralkaline pegmatites related to rischorrites associated with apatite-nepheline rocks at two deposits: Oleniy Ruchey (Reindeer Stream) underground mine, Mt. Suoluaiv and Rasvumchorr mine, Mt. Rasvumchorr, Khibiny complex, Kola Peninsula, Russia. The holotype specimen originates from the pegmatite which was found in several lumps in the dump of Oleniy Ruchey apatite deposit. The pegmatite is mainly composed of potassic feldspar, nepheline, sodalite, aegirine, arfvedsonite series amphibole, lamprophyllite, lomonosovite, eudialyte with and the accessory shcherbakovite, sphalerite, galena, and molybdenite. Pockets with hydrothermal minerals (pectolite, villiaumite, ershovite, shafranovskite) found in some part of the pegmatite enriched in green acicular aegirine. Minor minerals are umbite, sidorenkite, djerfisherite, rasvumite, and Na-bearing neotocite. Kamenevite replaces lomonosovite and fills cracks in crystals of slightly etched lomonosovite. It forms coarse lamellar crystals up to 0.02 × 0.1 × 0.3 mm. Crystals are combined in aggregates up to 0.7 mm. Individual crystals are rectangular or irregular and flattened on [010]. Pinacoid {010} is the major crystal form, lateral faces are probably pinacoids {100} and {001}. Kamenevite from a dump material mined at the level +470 m of Rasvumchorr underground apatite mine was found later in a similar assemblage in a pegmatite mainly consisting of potassic feldspar, nepheline, sodalite, Na–Mg–Fe³⁺-enriched hedenbergite, aegirine, potassic-arfvedsonite, lamprophyllite, eudialyte, and lomonosovite; with subordinate and accessory annite, fluorapatite, shcherbakovite, lobanovite, sphalerite, galena, and molybdenite. Sporadically the pegmatite contains abundant and unusually diverse (especially in part of potassium-rich silicates and sulfides) hydrothermal mineralization forming lenticular or irregular nests up to 20 cm. These nests are formed of pectolite, natrolite, villiaumite, lovozerite-group minerals, shafranovskite, zakharovite, ershovite (and highly hydrated products of its alteration), paraershovite, tinaksite, phosinaite-(Ce), umbite, tiettaite, lithosite, barytolamprophyllite, chkalovite, loparite, nacaphite, natrophosphate, K-rich vishnevite, cryptophyllite, shlykovite, mountainite, fluorapophyllite-(K), neotocite, cobaltite, jerfisherite, chlorbartonite, and rasvumite. At the Rasvumchorr mine, kamenevite occurs as equant or flattened grains up to 0.15 mm across, or as cavernous and granular accumulations up to 0.1 × 0.4 mm embedded in aggregates of different hydrous silicates. Kamenevite is closely associated with shafranovskite, altered ershovite and lovozerite. The new mineral is transparent, colorless in individual grains and white in aggregates. It has a white streak and vitreous lustre. Kamenevite is brittle with stepped fracture and good cleavage on {010}. The Mohs hardness is ca. 4; D_meas = 2.69(2) and D_calc = 2.698 g/cm³ (both for the holotype). In plane-polarized transmitted light kamenevite is colorless, non-pleochroic. It is optically biaxial (–), α = 1.650(4), β = 1.678(5), γ = 1.685(5) (589 nm), 2V_meas = 60(10)°, 2V_calc = 52°; Y = b. Dispersion of optical axes was not observed. The average of 4 WDS analyses on the holotype [wt% (range)] is: Na₂O 0.48 (0.21–0.69), K₂O 24.37 (24.11–24.53), CaO 0.13 (0.10–0.16), Fe₂O₃ 0.35 (0.13–0.52), SiO₂ 48.78 (47.19–50.29), TiO₂ 20.30 (19.75–20.66), ZrO₂ 0.89 (0.41–1.83), Nb₂O₅ 0.35 (00.63), H₂O 4.85 (by structure refinement based on 1 H₂O pfu), total 100.50. The empirical formula based on 10 O atoms pfu is (K_1.92Na_0.06Ca_0.01)_Σ1.99(Ti_0.94Zr_0.03Fe_0.02Nb_0.01)_Σ1.00S_3.01O₉·H₂O. The strongest lines in the powder X‑ray diffraction pattern are [d Å (I%; hkl)]: 7.92 (70; 110), 6.51 (47; 020), 5.823 (95; 101), 2.988 (84; 301,122), 2.954 (100; 041,320), 2.906 (68; 311,202), 2.834 (69, 141,212). The crystal structure of kamenevite was solved by direct methods and refined to R₁ = 3.84%. The new mineral is orthorhombic, P212121, a = 9.9166(4), b = 12.9561(5), c = 7.1374(3) Å, V = 917.02(6) ų, Z = 4. The crystal structure of kamenevite is based on a microporous heteropolyhedral framework built by [Si₃O₉]^∞ wollastonite-type chains linked by isolated Ti-centred octahedra. The K⁺ cations and H₂O groups are located in wide and narrower [001] channels. Kamenevite is isostructural with umbite, K₂ZrSi₃O₉·H₂O. The synthetic analogue of kamenevite known as titanosilicate AM-2, K₂TiSi₃O₉·H₂O, which displays strong zeolitic properties. The mineral is named after the outstanding Russian geologist Evgeniy Arsenievich Kamenev (1934–2017) for his great contribution to the geological study and exploration of the Khibiny complex apatite deposits. The type specimen is deposited in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia. Yu.U.

Russoite*

I. Campostrini, F. Demartin, and M. Scavini (2019) Russoite, NH₄ClAs₂³⁺O₃(H₂O)_0.5, a new phylloarsenite mineral from Solfatara Di Pozzuoli, Napoli, Italy. Mineralogical Magazine, 83(1), 89–94.

Russoite (IMA 2015-105), NH₄ClAs₂³⁺O₃(H₂O)_0.5, hexagonal, is a new mineral found in the volcanic fumarole “Bocca Grande” at Solfatara di Pozzuoli, near the town of Pozzuoli, Campi Flegrei area, Napoli, Italy. The fumarole has temperature ~160 °C. Russoite is closely associated with alacránite, dimorphite, realgar, mascagnite, salammoniac, and an amorphous arsenic sulfide. Other minerals found in the same fumarole are adranosite, adranosite-(Fe), efremovite, huizingite-(Al), and godovikovite. Russoite forms rosette-like intergrowths or subparallel aggregates of hexagonal plates flattened on {001} and bounded by {100} up to ~300 × 15 μm. The aggregates are sometimes yellowish due to admixed amorphous arsenic sulfide. Crystals are colorless to white, transparent to translucent, with vitreous luster, white streak and no apparent twinning. No fluorescence in UV radiation was observed. Russoite is brittle with perfect cleavage on {001}and irregular fracture. Mohs hardness was not determined; D_meas = 2.89(1), D_calc = 2.911 g/cm³. The mineral is optically uniaxial (–), ω = 1.810(6) and ε = 1.650(5) (white light). FTIR spectrum shows bands at (cm^–1): 3254, 3145, 1403 (ammonium); 3454, 3398, 1625 (H₂O); 670, 604 (arsenite bands); ~2400 weak (atmospheric CO₂); 1110 (minor OH^–, partially replacing the chloride ion). The average of six electron probe EDS analyses (performed under 20 kV excitation voltage, 10 pA beam current and 2 μm beam diameter to minimize the damage and deammonation under the beam) on a crystals flat surfaces [wt% (range)] is: K₂O 1.05 (0.65–1.22), As₂O₃ 74.16 (73.25–75.80), Cl 11.96 (11.73–12.94), Br 0.44 (0.25–0.80), [(NH₄)₂O 9.04 and H₂O 3.35 – by stoichiometry]; sum 100.00, –O=Cl, Br 2.75, total 97.25. No amounts of other elements above 0.1 wt% were detected. The empirical formula based on 4.5 anions pfu and K + NH₄ = 1 atom pfu is [(NH₄)_0.94,K_0.06]_Σ1.00 (Cl_0.91,Br_0.01)_Σ0.92As_2.02O₃(H₂O)_0.5. The strongest X‑ray powder diffraction lines are [d Å (I%; hkl)]: 12.63 (19; 001), 6.32 (100; 002), 4.547 (75; 100), 4.218(47; 003), 3.094 (45; 103), 2.627 (46; 110), 2.428 (31; 112), 1.820 (28; 115). The unit-cell parameters refined from powder XRD data are a = 5.259(2), c = 12.590(5) Å, V = 301.55 ų. Single-crystal XRD data shows russoite is hexagonal, space group P622, a = 5.2411(7), c = 12.5948(25) Å, V = 299.6 ų, Z = 2. The crystal structure was refined to R = 0.0518 for 311 reflections with I > 2σ(I) using as starting model a russoite synthetic analogue (Edstrand and Blomqvist 1955). The refinement revealed a different location of the ammonium cation and H₂O groups compare to that reported for the synthetic phase. As for other minerals of phylloarsenite family (lucabindiite, torrecillasite, and gajardoite), the crystal structure of russoite contains electrically neutral As₂O₃ sheets formed by As³⁺O₃ pyramids that share O atoms to form six-membered rings. These sheets are topologically identical to those found in lucabindiite and gajardoite. Ammonium cations are located between the sheets and the halide anions are outside of them. Additional ammonium cations and H₂O are in a layer between two levels of chloride anions interacting with each other via hydrogen bonds. The name russoite honors Massimo Russo (b. 1960), researcher at Osservatorio Vesuviano, Istituto Nazionale di Geofisica e Vulcanologia, Napoli, for his contributions to the mineralogy of Italian volcanoes. Holotype material is deposited in the Reference Collection of the DCSSI, Università degli Studi di Milano, Italy. D.B.

References cited

Edstrand, M., and Blomqvist, G. (1955) The crystal structure of NH₄Cl·As₂O₃·½H₂O. Arkiv för Kemi, 8, 245–256.Edstrand M., Blomqvist G. , 1955"The crystal structure of NH₄Cl·As₂O₃·½H₂O" Arkiv för Kemi, vol. 8, p. 245–256–.

Sbacchiite*

I. Campostrini, F. Demartin, and M. Russo (2019) Sbacchiite, Ca₂AlF₇, a new fumarolic mineral from the Vesuvius volcano, Napoli, Italy. European Journal of Mineralogy, 31(1), 153–158.

Sbacchiite (IMA 2017-097), Ca₂AlF₇, orthorhombic, is a new mineral discovered in a fossil fumarole “cotunnite pit” (active since eruption in 1944) at the eastern rim of the crater of Vesuvius volcano, Napoli, Italy (40°49ʹ 21.98ʺ N; 14°25ʹ 43.66ʺ E). The temperature in the fumarole have reached a maximum of ~ 800 °C in 1950 and then was decreasing to ~460 °C in 1960 and to ~7080 °C currently. Sbacchiite occurs in small aggregates closely associating with gearsksutite, usovite, creedite, and opal. Other minerals discovered in the fumarole are artroeite, ammineite, fluornatrocoulsellite, and parascandolaite. The formation of sbacchiite took place between 1948 and 1960 or shortly thereafter being a high-temperature encrustation resulted from extracting aluminium and calcium from the rocks by HF activity. The mineral was found in only one specimen of ~7 cm, later trimmed to a few. Sbacchiite crystals transparent or translucent, colorless, with vitreous luster and white streak. They have a very steep bipyramidal habit, are elongated by [100], and truncated by {100} pinakoid. The mineral is brittle with no distinct cleavage and no apparent twinning. Mohs hardness was not determined; D_meas = 3.08(2), D_calc = 3.116 g/cm³. Sbacchiite is optically biaxial (+), α = 1.379(4), β = 1.384(4), γ = 1.390(4) (white light), 2V_meas = 83 (2), 2V_calc = 85.1. The average of six electron probe EDS analyses (performed under 20 kV excitation voltage, 10 pA beam current, and 2 μm beam diameter to minimize the damage and deammonation under the beam) on unpolished flat surface [wt% (range)] is: Ca 33.41 (32.98–34.57), Mg 0.26 (0.17–0.30), Al 10.97 (10.78–11.14), F 54.67 (54.06–55.22), total 99.31. The empirical formula based on 10 apfu is Ca_2.02Mg_0.03Al_0.99F_6.97. The strongest X‑ray powder diffraction lines are [d Å (I%; hkl)]: 3.840 (45; 200), 3.563 (85; 201), 3.499 (100; 020), 2.899 (55; 013), 2.750 (30; 212), 2.281 (20; 104), 2.255 (52; 302), 2.173 (36; 131). The unit-cell parameters refined from powder data are a = 7.674(1), b = 6.996(1), c = 9.553(1) Å, V = 512.9 ų. Single-crystal XRD data obtained on a crystal fragment of 0.05 × 0.01 × 0.01 mm shows sbacchiite is orthorhombic, space group Pnma, a = 7.665(2), b = 6.993(1), c = 9.566(2) Å, V = 512.2 ų, Z = 4. The crystal structure was solved starting from the atomic positions of synthetic Ca₂AlF₇ (Domsele and Hoppe 1980) and refined to R = 0.0479 for 457 observed I>2σ(I) reflections. It represents a framework of “isolated” [AlF₆] octahedra, [Ca(1)F₇] distorted pentagonal bipyramids and [Ca(2) F₇₊₁] distorted polyhedra. Ca( 1) and Ca(2) polyhedra are linked by common edges alternating along [010] and along [001]. Along [100], only the Ca(1) pentagonal bipyramids are connected by bridging corners. anions. One face of [AlF₆] octahedra is shared with the adjacent Ca(2) polyhedron and, on the opposite face, an edge and a corner are shared with two adjacent Ca(1) polyhedra. All fluorine atoms in five F sites are threefold coordinated. The sbacchiite structure has some common features with those of carlhintzeite Ca₂AlF₇·H₂O (where “isolated” [AlF₆] octahedra have also been observed but in different environment) and jakobssonite, CaAlF₅ (containing instead vertex-sharing chains of [AlF₆] octahedra, interconnected by chains of [CaF₇] pentagonal bipyramids. The name honors Massimo Sbacchi (b. 1958), biologist and mineral collector, for his long-time field collaboration and continuous supply of interesting material for study. A holotype specimen is deposited at the Dipartimento di Chimica, Università degli Studi di Milano, Italy. Cotype is in the Museum of Osservatorio Vesuviano (Ercolano, Napoli), Italy. D.B.

References cited

Domsele, R., and Hoppe, R. (1980) The crystal structure of Ca₂AlF₇ Zeitschrift für Kristallographie, 153, 317–328.Domsele R., Hoppe R. , 1980"The crystal structure of Ca₂AlF₇" Zeitschrift für Kristallographie, vol. 153, p. 317–328–.

New Data

Oyelite

I.V. Pekov, N.V. Zubkova, N.V. Chukanov, V.O. Yapaskurt, S.N. Britvin, A.V. Kasatkin, and D.Y. Pushcharovky (2019) Oyelite: new mineralogical data, crystal structure model and refined formula Ca₅BSi₄O₁₃(OH)₃⋅4H₂O. European Journal of Mineralogy, 31(3), 595–608.

The new data on chemistry, IR spectroscopy and a unique, novel structure type refinement for an “old” mineral oyelite were obtained on the specimen from its new location at Bazhenovskoe asbestos deposit, town of Asbest, Urals, Russia. Published data on that mineral were revisited. The new ideal formula is Ca₅BSi₄O₁₃(OH)₃⋅4H₂O. The mineral is triclinic, P1, a = 7.2557(5), b = 10.7390(11), c = 11.2399(8) Å, α = 89.432(7), β = 89.198(6), γ = 72.097(8)°, V = 833.30 ų, Z = 2. The mineral was first reported (Heller and Taylor 1956) from the Crestmore quarries, Riverside County, California, U.S.A., as “the 10 Å hydrate” related to tobermorite. Considered relation to tobermorite was based on incomplete (no B was detected) semi-quantitative chemical data and some similarity of powder XRD patterns with refined parameters of orthorhombic unit cell: a = 11.2, b = 7.32, c = 20.5 Å. As it appeared later (Murdoch 1961) the mineral from Crestmore contains several percent of B₂O₃. In 1980, “10 Å tobermorite” was described from the Fuka Mine, Fuka, Bitchu-cho, Okayama Prefecture, Japan (Kusachi et al. 1980). Next, the mineral was submitted and approved by IMA as a new mineral oyelite (IMA 1980-103) presumably belonging to the tobermorite group (Kusachi et al. 1981). The description was based on specimens from the Fuka Mine (holotype) and from Crestmore. The simplified formula was suggested as Ca₁₀Si₈B₂O₂₉·nH₂O (n = 9.5–12.5) with orthorhombic unit-cell dimensions a = 11.25, b = 7.25, c = 20.46 Å. In 1986 oyelite was reported from Suisho-dani, Ise City, Mie Prefecture, Japan, and formula was adjusted to Ca₁₀Si₈B₂O₂₉·12H₂O. Next find in Kalahari Manganese Field, South Africa, in the N’Chwaning II mine (Von Bezing et al. 1991) produced spectacular oyelite specimens well-known and desirable for mineral collectors, however the quality of crystals did not allow the structural study. Raman spectroscopy and thermal studies were added, parameters of the orthorhombic or pseudo-orthorhombic sub-cell were given as a′ = 5.578(6), b′ = 3.596(4), c′ = 20.46(2) Å, and the simplified formula was modified to Ca₅BSi₄O₁₄(OH)·6H₂O (Biagioni et al. 2012). Oyelite is a hydrothermal mineral formed in late-stage assemblages related to various geological formations. At Crestmore and Fuka, the oyelite-bearing parageneses are related to classic calcic skarns, at Suisho-dani to rodingite embedded in serpentinite and at N’Chwaning to strata-bound manganese ores in metamorphosed volcanogenic-sedimentary rocks. At Bazhenovskoe deposit oyelite found in rodingite body at the Southern open pit. It is associated with tatarinovite, pectolite, xonotlite, and calcite in cavities in rodingite consisting of pale pinkish orange grossular with subordinate white to pale gray diopside. Oyelite forms elongated lamellar crystals up to 0.3 × 4 mm, divergent and combined in fan-shaped aggregates or radial rosettes up to 8 mm in diameter and their clusters up to 7 × 12 mm. Single crystals of oyelite are colorless, and aggregates are pearly-white. The chemical composition of oyelite crystal used for single-crystal study determined by electron probe WDS analysis is [wt%]: CaO 42.29, B₂O₃ 5.38, SiO₂ 36.65, H₂O 15.07 [by structure and based on (OH)₃(H₂O)₄ pfu], total 99.39. The empirical formula is Ca_4.96B_1.02Si_4.01O₁₃(OH)₃·4H₂O. The bands in IR absorption spectra of the oyelite are (cm^–1): 2200–3500 (O–H-stretching); including bands at 2885–2905 and 2233–2239 (acid OH groups forming strong and very strong hydrogen bonds, respectively); 1500–1800 (H–O– H bending); 1220–1270 and 850–1100 (B–O- and Si–O-stretching modes, respectively); 500–800 (mixed B–O–H, Si–O–H, O–Si–O and O–B–O bending modes); 400–500 (Si–O–Si stretching). The bands at 3969–3315 and 1350 cm^–1 are assigned to BO–H and SiO···H stretching vibrations, respectively. The difference between the IR spectra of oyelite from Bazhenovskoe and N’Chwaning and that of tobermorite is discussed. The strongest lines in the powder X‑ray diffraction pattern are [d Å (I%; hkl)]: 10.22 (71; 010), 4.921 (29; 012,012), 3.409 (23; 121,2 11,121,030), 3.067 (24; 212), 3.031 (38; 023,2 12), 2.917 (100; 202,032,222), 2.812 (42, 2 31,004). The crystal structure of oyelite was solved by direct methods and refined to R₁ = 12.01%. It contains two different kinds of tetrahedral units of different topology, both linear and running along [100]. The first type (I) is the borosilicate chain [BSi₂O₇(OH)₂]^∞ consisting of disilicate groups Si₂O₇ connected via single BO₂(OH)₂ tetrahedra. The second type (II) is the interrupted chain (“dotted line”) formed by Si₂O₆(OH) disilicate groups bonded to each other by very strong H-bonds. The tetrahedral units I and II are linked to (010) layers of sevenfold-coordinated Ca polyhedra of three different types: CaO₆(H₂O), CaO₃(H₂O)₄, and CaO₆OH. The structural formula of oyelite is Ca₅[BSi₂O₇(OH)₂][Si₂O₆(OH)]·4H₂O. The structure can be considered as “the intermediate link” between inosilicates with wollastonite-type chains and sorosilicates with isolated disilicate groups. Oyelite is crystal-chemically close to vistepite, SnMn₄B₂Si₄O₁₆(OH)₂, in part of the tetrahedral BSiO-chain, and also to some Ca-rich silicates, mostly of tobermorite-supergroup, in the structure of the layered motif built by Ca-centred polyhedra. Yu.U.

References cited

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