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In-situ measurements of magmatic volatile elements, F, S, and Cl, by electron microprobe, secondary ion mass spectrometry, and heavy ion elastic recoil detection analysis

  • Estelle F. Rose-Koga ORCID logo EMAIL logo , Kenneth T. Koga ORCID logo , Jean-Luc Devidal , Nobumichi Shimizu , Marion Le Voyer , Celia Dalou and Max Döbeli
Published/Copyright: April 29, 2020
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American Mineralogist
From the journal American Mineralogist Volume 105 Issue 5

Abstract

Electron probe and ion probe are the two most used instruments for in situ analysis of halogens in geological materials. The comparison of these two methods on widely distributed glass standards (example: MPI-DING glasses, Jochum et al., G-cubed, 2006) provides a basis for establishing laboratory method, independent geochemical data sets for these elements. We report analyses of F, S, and Cl concentrations in three geological glass samples (EPMA) and 10 referenced standards (EPMA and SIMS). Furthermore, F and Cl absolute abundances have been determined independently for three of the standards (KL2-G, ATHO-G, and KE12), via heavy ion elastic recoil detection analysis (HIERDA), to certify the accuracy of the cross-calibration EPMA-SIMS. The detection limits for EPMA are a 150 μg·g-1 for F, 20 μg·g-1 for S and Cl, and for SIMS < 48 μg·g-1 for F, < 3 μg·g-1 for S, and <19 μg·g-1 for Cl. On SiO2-rich glass-standards, F and Cl measurements by HIERDA highlight a weak matrix effect during SIMS analysis of F and Cl. With the HIERDA independently measured value, we therefore propose an alternative calibration function to empirically correct this matrix effect on the SIMS measurements of F, S, and Cl.

Keywords: F; Cl; SIMS; EPMA; ERDA; melt inclusion; Halogens in Planetary Systems

‡ Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.

Acknowledgments and funding

E.F.R-K. thanks O. Sigmarsson for the Sletta sample. E.F.R-K. and K.T.K. acknowledge support from Region Auvergne Rhone Alpes (SCUSI program). This is Laboratory of Excellence ClerVolc contribution number 386.

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Received: 2019-07-21
Accepted: 2019-12-21
Published Online: 2020-04-29
Published in Print: 2020-05-26

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Texture constraints on crystal size distribution methodology: An application to the Laki fissure eruption
  2. Hydrogenation reactions of carbon on Earth: Linking methane, margarine, and life
  3. Abiotic and biotic processes that drive carboxylation and decarboxylation reactions
  4. In-situ measurements of magmatic volatile elements, F, S, and Cl, by electron microprobe, secondary ion mass spectrometry, and heavy ion elastic recoil detection analysis
  5. MSA Centennial Symposium
  6. An evolutionary system of mineralogy. Part I: Stellar mineralogy (>13 to 4.6 Ga)
  7. A structural study of size-dependent lattice variation: In situ X-ray diffraction of the growth of goethite nanoparticles from 2-line ferrihydrite
  8. Cassiterite crystallization experiments in alkali carbonate aqueous solutions using a hydrothermal diamond-anvil cell
  9. New insights into the nature of glauconite
  10. Kaolinization of 2:1 type clay minerals with different swelling properties
  11. The quintet completed: The partitioning of sulfur between nominally volatile-free minerals and silicate melts
  12. 222Rn and 220Rn emanations from powdered samples of samarskite as a function of annealing temperature
  13. Polymerization during melting of ortho- and meta-silicates: Effects on Q species stability, heats of fusion, and redox state of mid-ocean range basalts (MORBs)
  14. Formation of native arsenic in hydrothermal base metal deposits and related supergene U6+ enrichment: The Michael vein near Lahr, SW Germany
  15. Lingbaoite, AgTe3, a new silver telluride from the Xiaoqinling gold district, central China
  16. Oxygen isotope fractionation between gypsum and its formation waters: Implications for past chemistry of the Kawah Ijen volcanic lake, Indonesia
  17. Presentation of the 2018 MSA Award of the Mineralogical Society of America to Laura Nielsen Lammers
  18. Acceptance of the 2018 MSA Award of the Mineralogical Society of America
  19. Presentation of the Dana Medal of the Mineralogical Society of America for 2019 to Matthew J. Kohn
  20. Acceptance of the Dana Medal of the Mineralogical Society of America for 2019
  21. Presentation of the Mineralogical Society of America Award for 2019 to Olivier Namur
  22. Acceptance of the Mineralogical Society of America Award for 2019
  23. Presentation of the 2019 MSA Distinguished Public Service Medal to Rodney C. Ewing
  24. Acceptance of Distinguished Public Service Award of the Mineralogical Society of America for 2019
  25. Presentation of the 2019 Roebling Medal of the Mineralogical Society of America to Peter R. Buseck
  26. Acceptance of the 2019 Roebling Medal of the Mineralogical Society of America
  27. Erratum
  28. Erratum
https://doi.org/10.2138/am-2020-7221
Keywords for this article
F; Cl; SIMS; EPMA; ERDA; melt inclusion; Halogens in Planetary Systems

Articles in the same Issue

  1. Texture constraints on crystal size distribution methodology: An application to the Laki fissure eruption
  2. Hydrogenation reactions of carbon on Earth: Linking methane, margarine, and life
  3. Abiotic and biotic processes that drive carboxylation and decarboxylation reactions
  4. In-situ measurements of magmatic volatile elements, F, S, and Cl, by electron microprobe, secondary ion mass spectrometry, and heavy ion elastic recoil detection analysis
  5. MSA Centennial Symposium
  6. An evolutionary system of mineralogy. Part I: Stellar mineralogy (>13 to 4.6 Ga)
  7. A structural study of size-dependent lattice variation: In situ X-ray diffraction of the growth of goethite nanoparticles from 2-line ferrihydrite
  8. Cassiterite crystallization experiments in alkali carbonate aqueous solutions using a hydrothermal diamond-anvil cell
  9. New insights into the nature of glauconite
  10. Kaolinization of 2:1 type clay minerals with different swelling properties
  11. The quintet completed: The partitioning of sulfur between nominally volatile-free minerals and silicate melts
  12. 222Rn and 220Rn emanations from powdered samples of samarskite as a function of annealing temperature
  13. Polymerization during melting of ortho- and meta-silicates: Effects on Q species stability, heats of fusion, and redox state of mid-ocean range basalts (MORBs)
  14. Formation of native arsenic in hydrothermal base metal deposits and related supergene U6+ enrichment: The Michael vein near Lahr, SW Germany
  15. Lingbaoite, AgTe3, a new silver telluride from the Xiaoqinling gold district, central China
  16. Oxygen isotope fractionation between gypsum and its formation waters: Implications for past chemistry of the Kawah Ijen volcanic lake, Indonesia
  17. Presentation of the 2018 MSA Award of the Mineralogical Society of America to Laura Nielsen Lammers
  18. Acceptance of the 2018 MSA Award of the Mineralogical Society of America
  19. Presentation of the Dana Medal of the Mineralogical Society of America for 2019 to Matthew J. Kohn
  20. Acceptance of the Dana Medal of the Mineralogical Society of America for 2019
  21. Presentation of the Mineralogical Society of America Award for 2019 to Olivier Namur
  22. Acceptance of the Mineralogical Society of America Award for 2019
  23. Presentation of the 2019 MSA Distinguished Public Service Medal to Rodney C. Ewing
  24. Acceptance of Distinguished Public Service Award of the Mineralogical Society of America for 2019
  25. Presentation of the 2019 Roebling Medal of the Mineralogical Society of America to Peter R. Buseck
  26. Acceptance of the 2019 Roebling Medal of the Mineralogical Society of America
  27. Erratum
  28. Erratum
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