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Crystallographic and fluid compositional effects on the halogen (Cl, F, Br, I) incorporation in pyromorphite-group minerals

  • Tatjana Epp EMAIL logo , Michael A.W. Marks , Thomas Ludwig , Mark A. Kendrick , Nelson Eby , Harald Neidhardt , Yvonne Oelmann and Gregor Markl
Published/Copyright: November 2, 2019
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Abstract

Pyromorphite-group minerals (PyGM), mainly pyromorphite [Pb5(PO4)3Cl], mimetite [Pb5(AsO4)3Cl], and vanadinite [Pb5(VO4)3Cl], are common phases that form by supergene weathering of galena. Their formation is strongly influenced by processes at the Earth’s surface and in the soil overlying a lead deposit, and they incorporate high amounts of halogens, mostly Cl and, in some cases, F. The abundance of Br and I in natural PyGM and their potential as process tracers during surface and sub-surface fluid-rock interaction processes has not been investigated in detail due to analytical difficulties. We, therefore, developed methods for the simultaneous determination of Cl, F, Br, and I in PyGM for (1) powdered bulk samples via combustion ion chromatography (CIC) and (2) compositionally zoned crystals by means of secondary ion mass spectrometry (SIMS).

Our study is based on well-characterized samples of pyromorphite (N = 38), mimetite (N = 16), and vanadinite (N = 2) from Schwarzwald (Germany). Natural pyromorphite incorporates more I (up to 26 μg/g) than mimetite (up to 2 μg/g) and vanadinite (up to 1 μg/g), while Br contents are higher in mimetite (up to 20 μg/g) and vanadinite (up to 13 μg/g) compared to pyromorphite (less than 4 μg/g). These results are unexpected, as mimetite and vanadinite have longer As/V-O bonds giving them larger unit cells and larger polyhedral volumes for the Cl site in the Pb26 octahedron than pyromorphite. Accordingly, pyromorphite was expected to preferentially incorporate Br rather than I, but the opposite is observed. Hence, halogen chemistry of PyGM is probably not governed by a crystal-chemical control (alone) but by fluid composition. However, the exact reasons remain enigmatic. This idea is corroborated by spatially resolved SIMS analyses that show that many pyromorphite-group minerals are strongly zoned with respect to their halogen mass ratios (e.g., Br/Cl, Br/I mass ratios). Furthermore, variations in halogen abundance ratios do not correlate with Ca/Pb, P/As, or P/V ratios and therefore may record alternating and season-dependent environmental parameters including biological activity, vegetation density, physico-chemical soil properties, and rainfall rate. We suggest that the zonation reflects multiple single fluid flow episodes and, hence, records surface processes. However, further experiments concerning the fractionation of halogens between fluid and PyGM are needed before halogen ratios in pyromorphite-group minerals can be used as reliable monitors of fluid-driven processes.

Acknowledgments

We are grateful to Thomas Wenzel for his invaluable help with the electron microprobe. Simone Schafflick is thanked for the sample preparation. Further thanks go to Bernd Steinhilber, who helped to develop the ideal method for the analyses. Axel Schmitt is thanked for providing the Macusani glass sample. Furthermore, we thank the Editor Don Baker, the Associate Editor Andrew Madden, and two anonymous reviewers for their constructive feedback that improved this manuscript significantly.

  1. Funding

    This research was funded by the German Research Foundation (DFG) Grant No. MA 2135/23-1 and OE 516/8-1. M.A. Kendrick was supported by an Australian Research Council Future Fellowship (FT13 0100141).

References cited

Bajda, T. (2010) Solubility of mimetite Pb5(AsO43Cl at 5–55 °C. Environmental Chemistry, 7(3), 268–278.10.1071/EN10021Search in Google Scholar

Basta, N., and McGowen, S. (2004) Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil. Environmental Pollution, 127(1), 73–82.10.1016/S0269-7491(03)00250-1Search in Google Scholar

Basu, A., and Schreiber, M.E. (2013) Arsenic release from arsenopyrite weathering: insights from sequential extraction and microscopic studies. Journal of Hazardous Materials, 262, 896–904.10.1016/j.jhazmat.2012.12.027Search in Google Scholar

Behne, W. (1953) Untersuchungen zur Geochemie des Chlor und Brom. Geochimica et Cosmochimica Acta, 3(4), 186–215.10.1016/0016-7037(53)90008-8Search in Google Scholar

Biester, H., Keppler, F., Putschnew, A., Martinez-Cortizas, A., and Petri, M. (2004) Halogen retention, organohalogens, and the role of organic matter decomposition on halogen enrichment in two Chilean peat bos. Environmental Science & Technology, 38(7), 1984–1991.10.1021/es0348492Search in Google Scholar

Biester, H., Hemmerich, S., and Petri, M. (2006) Halogens in porewater of peat bogs—the role of peat decomposition and dissolved organic matter. Biogeosciences Discussions, 2(5), 1457–1486.10.5194/bgd-2-1457-2005Search in Google Scholar

Böhlke, J.K., and Irwin, J.J. (1992) Brine history indicated by argon, krypton, chlorine, bromine, and iodine analyses of fluid inclusions from the Mississippi Valley type lead-fluorite-barite deposits at Hansonburg, New Mexico. Earth and Planetary Science Letters, 110(1), 51–66.10.1016/0012-821X(92)90038-WSearch in Google Scholar

Boyce, J.W., and Hervig, R.L. (2009) Apatite as a monitor of late-stage magmatic processes at Volcán Irazú, Costa Rica. Contributions to Mineralogy and Petrology, 157(2), 135.10.1007/s00410-008-0325-xSearch in Google Scholar

Brook, E. J., Harder, S., Severinghaus, J., Steig, E.J., and Sucher, C.M. (2000) On the origin and timing of rapid changes in atmospheric methane during the last glacial period. Global Biogeochemical Cycles, 14(2), 559–572.10.1029/1999GB001182Search in Google Scholar

Burisch, M., Marks, M.A., Nowak, M., and Markl, G. (2016) The effect of temperature and cataclastic deformation on the composition of upper crustal fluids—An experimental approach. Chemical Geology, 433, 24–35.10.1016/j.chemgeo.2016.03.031Search in Google Scholar

Burmann, F., Keim, M.F., Oelmann, Y., Teiber, H., Marks, M.A., and Markl, G. (2013) The source of phosphate in the oxidation zone of ore deposits: Evidence from oxygen isotope compositions of pyromorphite. Geochimica et Cosmochimica Acta, 123, 427–439.10.1016/j.gca.2013.07.042Search in Google Scholar

Carroll, D. (2012) Rock Weathering. Springer Science & Business Media.Search in Google Scholar

Cicerone, R. J. (1981) Halogens in the atmosphere. Reviews of Geophysics, 19(1), 123–139.10.1029/RG019i001p00123Search in Google Scholar

Dai, Y., and Hughes, J.M. (1989) Crystal structure refinements of vanadinite and pyromorphite. Canadian Mineralogist, 27(2), 189–192.Search in Google Scholar

Dennen, W.H. (1960) Principles of Mineralogy. Ronald Press Company.Search in Google Scholar

Eaton, J.S., Likens, G.E., and Bormann, F.H. (1973) Throughfall and stemflow chemistry in a northern hardwood forest. The Journal of Ecology, 495–508.10.2307/2259041Search in Google Scholar

Eby, G.N. (1990) The A-type granitoids: a review of their occurrence and chemical characteristics and speculations on their petrogenesis. Lithos, 26(1-2), 115–134.10.1016/0024-4937(90)90043-ZSearch in Google Scholar

Ehlers, J., and Gibbard, P.L. (2004) Quaternary glaciations-extent and chronology: Part I: Europe. Elsevier.Search in Google Scholar

Fehn, U., Snyder, G., and Egeberg, P.K. (2000) Dating of Pore Waters with 129I: Relevance for the Origin of Marine Gas Hydrates. Science, 289, 2332–2335.10.1126/science.289.5488.2332Search in Google Scholar PubMed

Fehn, U., Snyder, G.T., and Muramatsu, Y. (2007) Iodine as a tracer of organic material: 129I results from gas hydrate systems and fore arc fluids. Journal of Geochemical Exploration, 95(1), 66–80.10.1016/j.gexplo.2007.05.005Search in Google Scholar

Flis, J., Manecki, M., and Bajda, T. (2007) Solubility of pyromorphite-mimetite solid solutions at 5-65 °C: Variability of thermodynamic stability of minerals from pyromorphite-mimetite series at 5-65 °C. Geochimica et Cosmochimica Acta, 71, p. A285–A285.Search in Google Scholar

Flis, J., Borkiewicz, O., Bajda, T., Manecki, M., and Klasa, J. (2010) Synchrotron-based X‑ray diffraction of the lead apatite series Pb10(PO46Cl2–Pb10(AsO46Cl2 Journal of Synchrotron Radiation, 17(2), 207–214.10.1107/S0909049509048705Search in Google Scholar PubMed

Flis, J., Manecki, M., and Badja, T. (2011) Solubility of pyromorphite Pb5(PO43Cl– mimetite Pb5(AsO43Cl solid solution series. Geochimica et Cosmochimica Acta, 75(7), 1858–1868.10.1016/j.gca.2011.01.021Search in Google Scholar

Förtsch, E., and Wondratschek, H. (1965) Zur Kristallchemie der Minerale der Pyromorphit-Gruppe. Naturwissenschaften, 52(8), 182.10.1007/BF00623239Search in Google Scholar

Fuge, R. (1988) Sources of halogens in the environment, influences on human and animal health. Environmental Geochemistry and Health, 10(2), 51–61.10.1007/BF01758592Search in Google Scholar PubMed

Fuge, R., and Johnson, C.C. (1986) The geochemistry of iodine—a review. Environmental Geochemistry and Health, 8(2), 31–54.10.1007/BF02311063Search in Google Scholar

Gao, S., Luo, T.-C., Zhang, B.-R., Zhang, H.-F., Han, Y.-w., Zhao, Z.-D., and Hu, Y.-K. (1998) Chemical composition of the continental crust as revealed by studies in East China. Geochimica et Cosmochimica Acta, 62(11), 1959–1975.10.1016/S0016-7037(98)00121-5Search in Google Scholar

Gerke, T.L., Scheckel, K.G., and Schock, M.R. (2009) Identification and distribution of vanadinite (Pb5(V5+O43Cl) in lead pipe corrosion by-products. Environmental Science & Technology, 43(12), 4412–4418.10.1021/es900501tSearch in Google Scholar

Gieskes, J.M., and Mahn, C. (2007) Halide systematics in interstitial waters of ocean drilling sediment cores. Applied Geochemistry, 22(3), 515–533.10.1016/j.apgeochem.2006.12.003Search in Google Scholar

Göb, S., Loges, A., Nolde, N., Bau, M., Jacob, D.E., and Markl, G. (2013) Major and trace element compositions (including REE) of mineral, thermal, mine and surface waters in SW Germany and implications for water–rock interaction. Applied Geochemistry, 33, 127–152.10.1016/j.apgeochem.2013.02.006Search in Google Scholar

Hålenius, U., Hatert, F., Pasero, M., and Mills, S.J. (2017) New minerals and nomenclature modifications approved in 2017. Mineralogical Magazine, 81(5), 1279–1286.10.1180/minmag.2017.081.072Search in Google Scholar

Harlov, D.E. (2015) Apatite: A fingerprint for metasomatic processes. Elements, 11(3), 171–176.10.2113/gselements.11.3.171Search in Google Scholar

Harlov, D.E., Wirth, R., and Förster, H.-J. (2005) An experimental study of dissolution–reprecipitation in fluorapatite: fluid infiltration and the formation of monazite. Contributions to Mineralogy and Petrology, 150(3), 268–286.10.1007/s00410-005-0017-8Search in Google Scholar

Hautmann, S., and Lippolt, H. (2000) 40Ar/39Ar dating of central European K–Mn oxides—a chronological framework of supergene alteration processes during the Neogene. Chemical Geology, 170(1-4), 37–80.10.1016/S0009-2541(99)00241-7Search in Google Scholar

Herrmann, A.G. (1980) Bromide distribution between halite and NaCl-saturated seawater. Chemical Geology, 28, 171–177.10.1016/0009-2541(80)90043-1Search in Google Scholar

Hofmann, B., and Eikenberg, J. (1991) The Krunkelbach uranium deposit, Schwarzwald, Germany; correlation of radiometric ages (U-Pb, U-Xe-Kr, K-Ar, 230Th-234U). Economic Geology, 86(5), 1031–1049.10.2113/gsecongeo.86.5.1031Search in Google Scholar

Huang, W., Bishop, A., and Brown, R. (1986) The effect of fluid/rock ratio on feldspar dissolution and illite formation under reservoir conditions. Clay Minerals, 21(4), 585–601.10.1180/claymin.1986.021.4.10Search in Google Scholar

Janicka, U., Bajda, T., and Manecki, M. (2012) Synthesis and solubility of brompyromorphite Pb5(PO43Br. Mineralogia Polonica, 43(1-2), 129–135.10.2478/v10002-012-0004-4Search in Google Scholar

Jenny, H. (1941) Factors of Soil Formation. McGraw‐Hill, New York.10.1097/00010694-194111000-00009Search in Google Scholar

Johansson, E., Sandén, P., and Öberg, G. (2003) Organic chlorine in deciduous and coniferous forest soils in southern Sweden. Soil Science, 168(5), 347–355.10.1097/01.ss.0000070909.55992.91Search in Google Scholar

John, T., Scambelluri, M., Frische, M., Barnes, J.D., and Bach, W. (2011) Dehydration of subducting serpentinite: implications for halogen mobility in subduction zones and the deep halogen cycle. Earth and Planetary Science Letters, 308(1-2), 65–76.10.1016/j.epsl.2011.05.038Search in Google Scholar

Johns, W., and Huang, W. (1967) Distribution of chlorine in terrestrial rocks. Geochimica et Cosmochimica Acta, 31(1), 35–49.10.1016/0016-7037(67)90096-8Search in Google Scholar

Johnson, L., Burgess, R., Turner, G., Milledge, H., and Harris, J. (2000) Noble gas and halogen geochemistry of mantle fluids: comparison of African and Canadian diamonds. Geochimica et Cosmochimica Acta, 64(4), 717–732.10.1016/S0016-7037(99)00336-1Search in Google Scholar

Kabata-Pendias, A. (2011) Trace Elements in Soils and Plants. CRC Press, 534 p.10.1201/b10158Search in Google Scholar

Kalt, A., Altherr, R., and Hanel, M. (2000) The Variscan basement of the Schwarzwald. European Journal of Mineralogy, 12, 1–43.Search in Google Scholar

Kampf, A.R., and Housley, R.M. (2011) Fluorphosphohedyphane, Ca2Pb3(PO43F, the first apatite supergroup mineral with essential Pb and F. American Mineralogist, 96, 423–429.10.2138/am.2011.3586Search in Google Scholar

Keim, M.F., and Markl, G. (2015) Weathering of galena: Mineralogical processes, hydrogeochemical fluid path modeling, and estimation of the growth rate of pyromorphite. American Mineralogist, 100, 1584–1594.10.2138/am-2015-5183Search in Google Scholar

Kendrick, M.A. (2012) High precision Cl, Br and I determinations in mineral standards using the noble gas method. Chemical Geology, 292, 116–126.10.1016/j.chemgeo.2011.11.021Search in Google Scholar

Kendrick, M.A., and Burnard, P. (2013) Noble gases and halogens in fluid inclusions: A journey through the Earth’s crust. The Noble Gases as Geochemical Tracers. P. Burnard, p. 319–369. Springer-Verlag, Berlin.10.1007/978-3-642-28836-4_11Search in Google Scholar

Kendrick, M., and Phillips, D. (2009) New constraints on the release of noble gases during in vacuo crushing and application to scapolite Br–Cl–I and 40Ar/39Ar age determinations. Geochimica et Cosmochimica Acta, 73(19), 5673–5692.10.1016/j.gca.2009.06.032Search in Google Scholar

Kendrick, M., Phillips, D., Wallace, M., and Miller, J.M. (2011) Halogens and noble gases in sedimentary formation waters and Zn–Pb deposits: A case study from the Lennard Shelf, Australia. Applied Geochemistry, 26(12), 2089–2100.10.1016/j.apgeochem.2011.07.007Search in Google Scholar

Kendrick, M.A., Kamenetsky, V.S., Phillips, D., and Honda, M. (2012) Halogen systematics (Cl, Br, I) in mid-ocean ridge basalts: a Macquarie Island case study. Geochimica et Cosmochimica Acta, 81, 82–93.10.1016/j.gca.2011.12.004Search in Google Scholar

Kendrick, M.A., Arculus, R., Burnard, P., and Honda, M. (2013) Quantifying brine assimilation by submarine magmas: Examples from the Galápagos Spreading Centre and Lau Basin. Geochimica et Cosmochimica Acta, 123, 150–165.10.1016/j.gca.2013.09.012Search in Google Scholar

Kendrick, M.A., Jackson, M.G., Kent, A.J.R., Hauri, E.H., Wallace, P.J., and Woodhead, J. (2014) Contrasting behaviours of CO2 S, H2O and halogens (F, Cl, Br, and I) in enriched-mantle melts from Pitcairn and Society seamounts. Chemical Geology, 370, 69–81.10.1016/j.chemgeo.2014.01.019Search in Google Scholar

Kendrick, M.A., Honda, M., and Vanko, D.A. (2015) Halogens and noble gases in Mathematician Ridge meta-gabbros, NE Pacific: implications for oceanic hydrothermal root zones and global volatile cycles. Contributions to Mineralogy and Petrology, 170(5-6), 43.10.1007/s00410-015-1192-xSearch in Google Scholar

Kendrick, M.A., Hémond, C., Kamenetsky, V. S., Danyushevsky, L., Devey, C.W., Rodemann, T., and Perfit, M.R. (2017) Seawater cycled throughout Earth’s mantle in partially serpentinized lithosphere. Nature Geoscience, 10(3), 222.10.1038/ngeo2902Search in Google Scholar

Kendrick, M.A., D’Andres, J., Holden, P., and Ireland, T. (2018) Halogens (F, Cl, Br, I) in Thirteen USGS, GSJ and NIST International Rock and Glass Reference Materials. Geostandards and Geoanalytical Research.10.1111/ggr.12229Search in Google Scholar

Knyazev, A., Chernorukov, N., and Bulanov, E. (2011) Phase diagram of apatite system Ca10(PO46Cl2–Pb10(PO46Cl2 Thermochimica Acta, 526(1-2), 72–77.10.1016/j.tca.2011.08.028Search in Google Scholar

Krám, P., Hruška, J., Wenner, B.S., Discoll, C.T., and Johnson, C.E. (1997) The biogeochemistry of basic cations in two forest catchments with contrasting lithology in the Czech Republic. Biogeochemistry, 37(2), 173–202.10.1023/A:1005742418304Search in Google Scholar

Kusebauch, C., John, T., Barnes, J.D., Klügel, A., and Austrheim, H.O. (2015a) Halogen element and stable chlorine isotope fractionation caused by fluid–rock interaction (Bamble Sector, SE Norway). Journal of Petrology, 56(2), 299–324.10.1093/petrology/egv001Search in Google Scholar

Kusebauch, C., John, T., Whitehouse, M.J., and Engvik, A.K. (2015b) Apatite as probe for the halogen composition of metamorphic fluids (Bamble Sector, SE Norway). Contributions to Mineralogy and Petrology, 170(4), 34.10.1007/s00410-015-1188-6Search in Google Scholar

Låg, J., and Steinnes, E. (1976) Regional distribution of halogens in Norwegian forest soils. Geoderma, 16(4), 317–325.10.1016/0016-7061(76)90015-XSearch in Google Scholar

Leri, A.C., and Myneni, S.C. (2012) Natural organobromine in terrestrial ecosystems. Geochimica et Cosmochimica Acta, 77, 1–10.10.1016/j.gca.2011.11.012Search in Google Scholar

Loganathan, P., Liu, Q., Hedley, M.J., and Gray, C.W. (2007) Chemical fractionation of fluorine in soils with a long-term phosphate fertiliser history. Soil Research, 45, 390–396. doi: https://doi.org/10.1071/SR0703010.1071/SR07030Search in Google Scholar

Lovett, G.M., Likens, G.E., Buso, D.C., Driscoll, C.T., and Bailey, S.W. (2005) The biogeochemistry of chlorine at Hubbard Brook, New Hampshire, USA. Biogeochemistry, 72(2), 191–232.10.1007/s10533-004-0357-xSearch in Google Scholar

Lyubetskaya, T., and Korenaga, J. (2007) Chemical composition of Earth’s primitive mantle and its variance: 1. Method and results. Journal of Geophysical Research: Solid Earth, 112(B3).10.1029/2005JB004223Search in Google Scholar

Markl, G., Marks, M.A., Holzäpfel, J., and Wenzel, T. (2014) Major, minor, and trace element composition of pyromorphite-group minerals as recorder of supergene weathering processes from the Schwarzwald mining district, SW Germany. American Mineralogist, 99, 1133–1146.10.2138/am.2014.4789Search in Google Scholar

Marks, M.A., Wenzel, T., Whitehouse, M.J., Loose, M., Zack, T., Barth, M., Worgard, L., Krasz, V., Eby, G.N., and Stosnach, H. (2012) The volatile inventory (F, Cl, Br, S, C) of magmatic apatite: An integrated analytical approach. Chemical Geology, 291, 241–255.10.1016/j.chemgeo.2011.10.026Search in Google Scholar

Marks, M.A., Kendrick, M.A., Eby, G.N., Zack, T., and Wenzel, T. (2017) The F, Cl, Br and I Contents of Reference Glasses BHVO-2G, BIR-1G, BCR-2G, GSD-1G, GSE-1G, NIST SRM 610 and NIST SRM 612. Geostandards and Geoanalytical Research, 41(1), 107–122.10.1111/ggr.12128Search in Google Scholar

McCaffrey, M., Lazar, B., and Holland, H. (1987) The evaporation path of seawater and the coprecipitation of Br and K+ with halite. Journal of Sedimentary Research, 57(5), 928–937.Search in Google Scholar

McCann, T. (Ed.). (2008) The Geology of Central Europe: Mesozioc and cenozoic. Geological Society of London.10.1144/CEV2PSearch in Google Scholar

Metz, R., and Richter, M. (1957) Die Blei-Zink-Erzgänge des Schwarzwaldes. Beihefte zum Geologischen Jahrbuch, Beiheft, 29, 277.Search in Google Scholar

Morel, P., Von Blanckenburg, F., Schaller, M., Kubik, P.W., and Hinderer, M. (2003) Lithology, landscape dissection and glaciation controls on catchment erosion as determined by cosmogenic nuclides in river sediment (the Wutach Gorge, Black Forest). Terra Nova, 15(6), 398–404.10.1046/j.1365-3121.2003.00519.xSearch in Google Scholar

Muramatsu, Y., and Wedepohl, K.H. (1998) The distribution of iodine in the Earth’s crust. Chemical Geology, 147(3-4), 201–216.10.1016/S0009-2541(98)00013-8Search in Google Scholar

Muramatsu, Y., Fehn, U., and Yoshida, S. (2001) Recycling of iodine in fore-arc areas: evidence from the iodine brines in Chiba, Japan. Earth and Planetary Science Letters, 192(4), 583–593.10.1016/S0012-821X(01)00483-6Search in Google Scholar

Muramatsu, Y., Doi, T., Tomaru, H., Fehn, U., Takeuchi, R., and Matsumoto, R. (2007) Halogen concentrations in pore waters and sediments of the Nankai Trough, Japan: Implications for the origin of gas hydrates. Applied Geochemistry, 22(3), 534–556.10.1016/j.apgeochem.2006.12.015Search in Google Scholar

Neal, C., Robinson, M., Reynolds, B., Neal, M., Rowland, P., Grant, S., Norris, D., Williams, B., Sleep, D., and Lawlor, A. (2010) Hydrology and water quality of the headwaters of the River Severn: Stream acidity recovery and interactions with plantation forestry under an improving pollution climate. Science of the Total Environment, 408(21), 5035–5051.10.1016/j.scitotenv.2010.07.047Search in Google Scholar PubMed

Nodvin, S.C., Driscoll, C.T., and Likens, G.E. (1986) Simple partitioning of anions and dissolved organic carbon in a forest soil. Soil Science, 142, 27–35.10.1097/00010694-198607000-00005Search in Google Scholar

Nriagu, J.O. (1973) Lead orthophosphates-III. Stabilities of fluoropyromorphite and bromopyromorphite at 25° C. Geochimica et Cosmochimica Acta, 37(7), 1735–1743.10.1016/0016-7037(73)90159-2Search in Google Scholar

Oades, J.M. (1993) The role of biology in the formation, stabilization and degradation of soil structure. In Soil Structure/Soil Biota Interrelationships (pp. 377–400). Elsevier.10.1016/B978-0-444-81490-6.50033-9Search in Google Scholar

Öberg, G., and Bastviken, D. (2012) Transformation of chloride to organic chlorine in terrestrial environments: variability, extent, and implications. Critical Reviews in Environmental Science and Technology, 42(23), 2526–2545.10.1080/10643389.2011.592753Search in Google Scholar

Öberg, G., and Sandén, P. (2005) Retention of chloride in soil and cycling of organic matter-bound chlorine. Hydrological Processes: An International Journal, 19(11), 2123–2136.10.1002/hyp.5680Search in Google Scholar

Oelmann, Y., Kreutziger, Y., Temperton, V.M., Buchmann, N., Roscher, C., Schumacher, J., Schulze, E.-D., Weisser, W.W., and Wilcke, W. (2007) Nitrogen and phosphorus budgets in experimental grasslands of variable diversity. Journal of Environmental Quality, 36(2), 396–407.10.2134/jeq2006.0217Search in Google Scholar PubMed

Okudera, H. (2013) Relationships among channel topology and atomic displacements in the structures of Pb5(BO43Cl with B= P (pyromorphite), V (vanadinite), and As (mimetite). American Mineralogist, 98, 1573–1579.10.2138/am.2013.4417Search in Google Scholar

Oliva, P., Viers, J., and Dupré, B. (2003) Chemical weathering in granitic environments. Chemical Geology, 202, 225–256.10.1016/j.chemgeo.2002.08.001Search in Google Scholar

Palme, H., and O’Neill, H.St.C. (2003) Cosmochemical estimates of mantle composition. Treatise on Geochemistry, 2, 568.Search in Google Scholar

Park, C.F. Jr., and MacDiarmid, R.A. (1975) Ore Deposits. Freeman.Search in Google Scholar

Park, K.S., Sims, R.C., Dupont, R.R., Doucette, W.J., and Matthews, J.E. (1990) Fate of PAH compounds in two soil types: influence of volatilization, abiotic loss and biological activity. Environmental Toxicology and Chemistry: An International Journal, 9(2), 187–195.10.1002/etc.5620090208Search in Google Scholar

Pasero, M., Kampf, A.R., Ferraris, C., Pekov, I.V., Rakovan, J., and White, T.J. (2010) Nomenclature of the apatite supergroup minerals. European Journal of Mineralogy, 22(2), 163–179.10.1127/0935-1221/2010/0022-2022Search in Google Scholar

Pfaff, K., Romer, R.L., and Markl, G. (2009) U-Pb ages of ferberite, chalcedony, agate,‘U-mica’and pitchblende: constraints on the mineralization history of the Schwarzwald ore district. European Journal of Mineralogy, 21(4), 817–836.10.1127/0935-1221/2009/0021-1944Search in Google Scholar

Pichavant, M., Herrera, J.V., Boulmier, S., Joron, J.L., Juteau, M., Marin, L., Sheppard, S.M.F., Treuil, M., and Vernet, M. (1987) The Macusani glasses, SE Peru: evidence of chemical fractionation in peraluminous magmas. In B.O. Mysen, Ed., Magmatic Processes: Physicochemical Principles, p. 359–373. The Geochemical Society, Washington, D.C.Search in Google Scholar

Redon, P.-O., Jolivet, C., Saby, N.P., Abdelouas, A., and Thiry, Y. (2013) Occurrence of natural organic chlorine in soils for different land uses. Biogeochemistry, 114(1-3), 413–419.10.1007/s10533-012-9771-7Search in Google Scholar

Reich, M., and Vasconcelos, P.M. (2015) Geological and economic significance of supergene metal deposits. Elements, 11(5), 305–310.10.2113/gselements.11.5.305Search in Google Scholar

Roddick, J. (1983) High precision intercalibration of 40Ar-39Ar standards. Geochimica et Cosmochimica Acta, 47(5), 887–898.10.1016/0016-7037(83)90154-0Search in Google Scholar

Ruby, M.V., Davis, A., and Nicholson, A. (1994) In situ formation of lead phosphates in soils as a method to immobilize lead. Environmental Science & Technology, 28(4), 646–654.10.1021/es00053a018Search in Google Scholar PubMed

Rudnick, R.L., and Shan, G. (2003) Composition of the continental crust. Treatise on Geochemistry, 3, 659.10.1016/B0-08-043751-6/03016-4Search in Google Scholar

Schnetger, B., and Muramatsu, Y. (1996) Determination of halogens, with special reference to iodine, in geological and biological samples using pyrohydrolysis for preparation and inductively coupled plasma mass spectrometry and ion chromatography for measurement. Analyst, 121(11), 1627–1631.10.1039/an9962101627Search in Google Scholar PubMed

Seelig, U., and Bucher, K. (2010) Halogens in water from the crystalline basement of the Gotthard rail base tunnel (central Alps). Geochimica et Cosmochimica Acta, 74(9), 2581–2595.10.1016/j.gca.2010.01.030Search in Google Scholar

Seybold, C.A., Herrick, J.E., and Brejda, J.J. (1999) Soil resilience: a fundamental component of soil quality. Soil Science, 164, 224–234.10.1097/00010694-199904000-00002Search in Google Scholar

Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751–767.10.1107/S0567739476001551Search in Google Scholar

Siegel, F.R. (2002) Environmental Geochemistry of Potentially Toxic Metals. Springer.10.1007/978-3-662-04739-2Search in Google Scholar

Siemann, M.G., and Schramm, M. (2000) Thermodynamic modelling of the Br partition between aqueous solutions and halite. Geochimica et Cosmochimica Acta, 64(10), 1681–1693.10.1016/S0016-7037(99)00385-3Search in Google Scholar

Staude, S., Bons, P.D., and Markl, G. (2009) Hydrothermal vein formation by extension-driven dewatering of the middle crust: An example from SW Germany. Earth and Planetary Science Letters, 286(3-4), 387–395.10.1016/j.epsl.2009.07.012Search in Google Scholar

Svensson, T., Lovett, G.M., and Likens, G.E. (2012) Is chloride a conservative ion in forest ecosystems? Biogeochemistry, 107, 125–134. doi: 10.1007/ s10533-010-9538-y.10.1007/s10533-010-9538-ySearch in Google Scholar

Teiber, H., Marks, M.A., Wenzel, T., Siebel, W., Altherr, R., and Markl, G. (2014) The distribution of halogens (F, Cl, Br) in granitoid rocks. Chemical Geology, 374, 92–109.10.1016/j.chemgeo.2014.03.006Search in Google Scholar

Teiber, H., Scharrer, M., Marks, M.A., Arzamastsev, A.A., Wenzel, T., and Markl, G. (2015) Equilibrium partitioning and subsequent re-distribution of halogens among apatite–biotite–amphibole assemblages from mantle-derived plutonic rocks: Complexities revealed. Lithos, 220, 221–237.10.1016/j.lithos.2015.02.015Search in Google Scholar

Tomaru, H., Fehn, U., Lu, Z., Takeuchi, R., Inagaki, F., Imachi, H., Kotani, R., Matsumoto, R., and Aoike, K. (2009) Dating of dissolved iodine in pore waters from the gas hydrate occurrence offshore Shimokita Peninsula, Japan: 129I results from the D/V Chikyu Shakedown Cruise. Resource Geology, 59(4), 359–373.10.1111/j.1751-3928.2009.00103.xSearch in Google Scholar

Walter, B.F., Burisch, M., Fusswinkel, T., Marks, M.A.W., Steele-MacInnis, M., Wälle, M., Apukhtina, O.B., and Markl, G. (2018) Multi-reservoir fluid mixing processes in rift-related hydrothermal veins, Schwarzwald, SW-Germany. Journal of Geochemical Exploration, 186, 158–186.10.1016/j.gexplo.2017.12.004Search in Google Scholar

Walter, B.F., Burisch, M., and Markl, G. (2016) Long-term chemical evolution and modification of continental basement brines—a field study from the Schwarzwald, SW Germany. Geofluids, 16(3), 604–623.10.1111/gfl.12167Search in Google Scholar

Wang, L.-X., Ma, C.-Q., Zhang, C., Zhu, Y.-X., and Marks, M.A. (2018) Halogen geochemistry of I- and A-type granites from Jiuhuashan region (South China): Insights into the elevated fluorine in A-type granite. Chemical Geology, 478, 164–182.10.1016/j.chemgeo.2017.09.033Search in Google Scholar

Webster, J.D., and Piccoli, P.M. (2015) Magmatic apatite: A powerful, yet deceptive, mineral. Elements, 11(3), 177–182.10.2113/gselements.11.3.177Search in Google Scholar

Whitfield, M., and Turner, D. (1979) Water–rock partition coefficients and the composition of seawater and river water. Nature, 278, 132–137.10.1038/278132a0Search in Google Scholar

Wilson, T. (1975) Salinity and the major elements of seawater, Chemical Oceanography, 1 JP Riley, G. Skirrow Academic Press, San Diego, Calif.Search in Google Scholar

Wondratschek, H. (1963) Untersuchungen zur Kristallchemie der Blei-Apatite (Pyromorphite). Neues Jahrbuch für Mineralogie Abhandlungen, 99, 113–160.Search in Google Scholar

Wong, G., and Brewer, P. (1974) Determination and distribution of iodate in South-Atlantic waters. Journal of Marine Research, 32(1), 25–36.Search in Google Scholar

Wu, W., Xu, S., Yang, J., and Yin, H. (2008) Silicate weathering and CO2 consumption deduced from the seven Chinese rivers originating in the Qinghai-Tibet Plateau. Chemical Geology, 249(3-4), 307–320.10.1016/j.chemgeo.2008.01.025Search in Google Scholar

Yuita, K., Shibuya, M., and Nozaki, T. (1978) The accumulation of bromine and iodine in Japanese soils. Abstract 11th Soil Science Congress Edmonton, Alberta, 260.Search in Google Scholar

Yuita, K., Kihou, N., Ichihasi, H., Yabusaki, S., Fujiwara, H., Kurishima, K., and Noda, T. (2006) Behavior of iodine in a forest plot, an upland field and a paddy field in the upland area of Tsukuba, Japan: Seasonal variations in iodine concentration in precipitation and soil water and estimation of the annual iodine accumulative amount in soil horizons. Soil Science and Plant Nutrition, 52(1), 122–132.10.1111/j.1747-0765.2006.00012.xSearch in Google Scholar

Received: 2019-03-28
Accepted: 2019-07-26
Published Online: 2019-11-02
Published in Print: 2019-11-26

© 2019 Walter de Gruyter GmbH, Berlin/Boston

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