The high-pressure anisotropic thermoelastic properties of a potential inner core carbon-bearing phase, Fe7C3, by single-crystal X-ray diffraction
-
Xiaojing Lai
, Feng Zhu , Jiachao Liu , Dongzhou Zhang , Yi Hu , Gregory J. Finkelstein , Przemyslaw Dera and Bin Chen
Abstract
Carbon has been suggested as one of the light elements existing in the Earth’s core. Under core conditions, iron carbide Fe7C3 is likely the first phase to solidify from a Fe-C melt and has thus been considered a potential component of the inner core. The crystal structure of Fe7C3, however, is still under debate, and its thermoelastic properties are not well constrained at high pressures. In this study, we performed synchrotron-based single-crystal X-ray diffraction experiment using an externally heated diamond-anvil cell to determine the crystal structure and thermoelastic properties of Fe7C3 up to 80 GPa and 800 K. Our diffraction data indicate that Fe7C3 adopts an orthorhombic structure under experimentally investigated conditions. The pressure-volume-temperature data for Fe7C3 were fitted by the high-temperature Birch-Murnaghan equation of state, yielding ambient-pressure unit-cell volume V0 = 745.2(2) Å3, bulk modulus K0 = 167(4) GPa, its first pressure derivative
Acknowledgments
This work was performed at GeoSoilEnviroCARS (The University of Chicago, Sector 13), Advanced Photon Source, Argonne National Laboratory. GeoSoilEnviroCARS is supported by the National Science Foundation-Earth Sciences (EAR-1128799) and Department of Energy-GeoSciences (DE-FG02-94ER14466). The use of gas loading system was supported by GeoSoilEnviroCARS and by the Consortium for Materials Properties Research in Earth Sciences (COMPRES) under National Science Foundation Cooperative Agreement EAR -1606856. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357. Development of the ATREX software, which was used for experimental data analysis was supported by National Science Foundation (NSF) EAR GeoInformatics grant 1440005. Development of the X-ray Atlas instrument was funded by NSF EAR Infrastructure and Facilities grant 1541516. This work was supported by NSF grant EAR-1555388 to B.C. and in part supported by the Bullard award from the University of Hawai’i at Mānoa to X.L. We thank the technical support from Sergey Tkachev. We are grateful to Danielle Gray for the valuable discussion. We thank the Associate Editor R. Sinmyo, the two anonymous reviewers and the Technical Editor for their constructive comments. School of Ocean and Earth Science and Technology (SOEST) contribution 10424. Hawaii Institute of Geophysics and Planetology (HIGP) contribution 2354.
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Articles in the same Issue
- Highlights and Breakthroughs
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- In-situ dating of metamorphism in Adirondack anorthosite
- A new style of rare metal granite with Nb-rich mica: The Early Cretaceous Huangshan rare-metal granite suite, northeast Jiangxi Province, southeast China
- Tectonic controls on Ni and Cu contents of primary mantle-derived magmas for the formation of magmatic sulfide deposits
- The high-pressure anisotropic thermoelastic properties of a potential inner core carbon-bearing phase, Fe7C3, by single-crystal X-ray diffraction
- Eruption triggering by partial crystallization of mafic enclaves at Chaos Crags, Lassen Volcanic Center, California
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- Micro- and nano-scale study of deformation induced mineral transformations in Mg-phyllosilicate-rich fault gouges from the Galera Fault Zone (Betic Cordillera, SE Spain)
- High-pressure study of dravite tourmaline: Insights into the accommodating nature of the tourmaline structure
- Positively oriented trigons on diamonds from the Snap Lake kimberlite dike, Canada: Implications for fluids and kimberlite cooling rates
- Comparison of Rietveld-compatible structureless fitting analysis methods for accurate quantification of carbon dioxide fixation in ultramafic mine tailings
- Polyphase solid-inclusions formed by interactions between infiltrating fluids and precursor minerals enclosed in garnet of UHP rocks from the Dabie Shan, China
- Changes in physical properties of 4C pyrrhotite (Fe7S8) across the 32 K Besnus transition
- A rapid and precise quantitative electron probe chemical mapping technique and its application to an ultrahigh-pressure eclogite from the Moldanubian Zone of the Bohemian Massif (Nové Dvory, Czech Republic)
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- Letter
- Fe-Ni ideality during core formation on Earth
- New Mineral Names
Articles in the same Issue
- Highlights and Breakthroughs
- A closer look at shocked meteorites: Discovery of new high-pressure minerals
- In-situ dating of metamorphism in Adirondack anorthosite
- A new style of rare metal granite with Nb-rich mica: The Early Cretaceous Huangshan rare-metal granite suite, northeast Jiangxi Province, southeast China
- Tectonic controls on Ni and Cu contents of primary mantle-derived magmas for the formation of magmatic sulfide deposits
- The high-pressure anisotropic thermoelastic properties of a potential inner core carbon-bearing phase, Fe7C3, by single-crystal X-ray diffraction
- Eruption triggering by partial crystallization of mafic enclaves at Chaos Crags, Lassen Volcanic Center, California
- Sn-isotope fractionation as a record of hydrothermal redox reactions
- Surface energy of fayalite and its effect on Fe-Si-O oxygen buffers and the olivine-spinel transition
- Micro- and nano-scale study of deformation induced mineral transformations in Mg-phyllosilicate-rich fault gouges from the Galera Fault Zone (Betic Cordillera, SE Spain)
- High-pressure study of dravite tourmaline: Insights into the accommodating nature of the tourmaline structure
- Positively oriented trigons on diamonds from the Snap Lake kimberlite dike, Canada: Implications for fluids and kimberlite cooling rates
- Comparison of Rietveld-compatible structureless fitting analysis methods for accurate quantification of carbon dioxide fixation in ultramafic mine tailings
- Polyphase solid-inclusions formed by interactions between infiltrating fluids and precursor minerals enclosed in garnet of UHP rocks from the Dabie Shan, China
- Changes in physical properties of 4C pyrrhotite (Fe7S8) across the 32 K Besnus transition
- A rapid and precise quantitative electron probe chemical mapping technique and its application to an ultrahigh-pressure eclogite from the Moldanubian Zone of the Bohemian Massif (Nové Dvory, Czech Republic)
- Stracherite, BaCa6(SiO4)2[(PO4)(CO3)]F, the first CO3-bearing intercalated hexagonal antiperovskite from Negev Desert, Israel
- Letter
- Fe-Ni ideality during core formation on Earth
- New Mineral Names