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Subsolidus hydrogen partitioning between nominally anhydrous minerals in garnet-bearing peridotite

  • Sylvie Demouchy EMAIL logo , Svyatoslav Shcheka , Carole M.M. Denis and Catherine Thoraval
Published/Copyright: September 5, 2017
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American Mineralogist
From the journal American Mineralogist Volume 102 Issue 9

Abstract

Hydrogen distribution between nominally anhydrous minerals (NAMs) of a garnet-lherzolite under subsolidus conditions has been investigated. Separated NAMs from a garnet-peridotite from Patagonia (Chile) are annealed together (olivine, orthopyroxene, clinopyroxene, and garnet) using a piston-cylinder at 3 GPa and 1100 °C using talc-pyrex cell assembly for 10, 25, and 100 h. The talc-pyrex assembly provides enough hydrogen in the system to re-equilibrate the hydrogen concentrations at high pressure. The three coexisting nominally anhydrous minerals (NAMs, i.e., olivine, orthopyroxene, and clinopyroxene) were successfully analyzed using FTIR. The resulting hydrogen concentrations exceed significantly the initial hydrogen concentration by a factor of 13 for olivine and a factor of 3 for both pyroxenes. Once mineral-specific infrared calibrations are applied, the average concentrations in NAMs are 115 ± 12 ppm wt H2O for olivine, 635 ± 75 ppm wt H2O for orthopyroxene, and 1214 ± 137 ppm wt H2O for clinopyroxene, garnet grains are dry. Since local equilibrium seems achieved over time (for 100 h), the calculated concentration ratios are interpreted as mineral-to-mineral hydrogen partition coefficients (i.e., Nernst’s law) for a garnet-peridotite assemblage. It yields, based on mineral-specific infrared calibrations, DOpx/Ol = 5 ± 1, DCpx/Ol = 10 ± 2, and DCpx/Opx = 1.9 ± 0.4. While DCpx/Opx is in agreement (within error) with previous results from experimental studies and concentration ratios observed in mantle-derived peridotites, the DPx/Ol from this study are significantly lower than the values reported from mantle-derived xenoliths and also at odd with several previous experimental studies where melt and/or hydrous minerals co-exists with NAMs. The results confirm the sensitivity of hydrogen incorporation in olivine regarding the amount of water-derived species (H) in the system and/or the amount of water in the coexisting silicate melt. The results are in agreement with an important but incomplete dehydration of mantle-derived olivine occurring at depth, during transport by the host magma or during slow lava flow cooling at the surface. The rapid concentration modification in mantle pyroxenes also points out that pyroxenes might not be a hydrogen recorder as reliable as previously thought.

Keywords: Olivine; pyroxenes; hydrogen; partition coefficient; upper mantle

Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.

Acknowledgments

The authors thank the associated editor and two reviewers for very constructive comments. S.D. deeply thanks J.-A. Padròn-Navarta for fruitful discussion on peridotite melting curves, H. Schulze for outstanding capsule polishing, H. Fisher for perfect capsule manufacture, and D. Maurin for the management of the FTIR lab at the University of Montpellier. This study was financially supported by DFG Core facility: High-pressures laboratories of Bayerisches Geoinstitut, Bayreuth University, Germany (KE501/10-1).

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Received: 2017-1-26
Accepted: 2017-5-4
Published Online: 2017-9-5
Published in Print: 2017-9-26

© 2017 by Walter de Gruyter Berlin/Boston

Articles in the same Issue

  1. Highlights and Breakthroughs
  2. Looking for “missing” nitrogen in the deep Earth
  3. Actinides in Geology, Energy, and the Environment
  4. Crystal structure of richetite revisited: Crystallographic evidence for the presence of pentavalent uranium
  5. Actinides in Geology, Energy, and the Environment
  6. Mobilization and agglomeration of uraninite nanoparticles: A nano-mineralogical study of samples from the Matoush Uranium ore deposit
  7. Actinides in Geology, Energy, and the Environment
  8. Radiation damage in sulfides: Radioactive galena from burning heaps, after coal mining in the Lower Silesian basin (Czech Republic)
  9. Special Collection: Mechanisms, Rates, and Timescales of Geochemical Transport Processes in the Crust and Mantle
  10. Element mobility during regional metamorphism in crustal and subduction zone environments with a focus on the rare earth elements (REE)
  11. Special Collection: Water in Nominally Hydrous and Anhydrous Minerals
  12. Subsolidus hydrogen partitioning between nominally anhydrous minerals in garnet-bearing peridotite
  13. Special Collection: Water in Nominally Hydrous and Anhydrous Minerals
  14. OH defects in quartz as monitor for igneous, metamorphic, and sedimentary processes
  16. Quantitative electron backscatter diffraction (EBSD) data analyses using the dictionary indexing (DI) approach: Overcoming indexing difficulties on geological materials
  18. Trace element inventory of meteoritic Ca-phosphates
  20. Insights into solar nebula formation of pyrrhotite from nanoscale disequilibrium phases produced by H2S sulfidation of Fe metal
  22. Unraveling the presence of multiple plagioclase populations and identification of representative two-dimensional sections using a statistical and numerical approach
  24. Refractive indices of minerals and synthetic compounds
  26. Can we use pyroxene weathering textures to interpret aqueous alteration conditions? Yes and No
  28. Phase relations and formation of K-bearing Al-10 Å phase in the MORB+H2O system: Implications for H2O- and K-cycles in subduction zones
  30. Effect of alkalis on the reaction of clinopyroxene with Mg-carbonate at 6 GPa: Implications for partial melting of carbonated lherzolite
  32. Synthesis and crystal structure of LiNbO3-type Mg3Al2Si3O12: A possible indicator of shock conditions of meteorites
  34. Single crystal synthesis of δ-(Al,Fe)OOH
  35. Letter
  36. EosFit-Pinc: A simple GUI for host-inclusion elastic thermobarometry
  38. New Mineral Names
https://doi.org/10.2138/am-2017-6089
Keywords for this article
Olivine; pyroxenes; hydrogen; partition coefficient; upper mantle

Articles in the same Issue

  1. Highlights and Breakthroughs
  2. Looking for “missing” nitrogen in the deep Earth
  3. Actinides in Geology, Energy, and the Environment
  4. Crystal structure of richetite revisited: Crystallographic evidence for the presence of pentavalent uranium
  5. Actinides in Geology, Energy, and the Environment
  6. Mobilization and agglomeration of uraninite nanoparticles: A nano-mineralogical study of samples from the Matoush Uranium ore deposit
  7. Actinides in Geology, Energy, and the Environment
  8. Radiation damage in sulfides: Radioactive galena from burning heaps, after coal mining in the Lower Silesian basin (Czech Republic)
  9. Special Collection: Mechanisms, Rates, and Timescales of Geochemical Transport Processes in the Crust and Mantle
  10. Element mobility during regional metamorphism in crustal and subduction zone environments with a focus on the rare earth elements (REE)
  11. Special Collection: Water in Nominally Hydrous and Anhydrous Minerals
  12. Subsolidus hydrogen partitioning between nominally anhydrous minerals in garnet-bearing peridotite
  13. Special Collection: Water in Nominally Hydrous and Anhydrous Minerals
  14. OH defects in quartz as monitor for igneous, metamorphic, and sedimentary processes
  16. Quantitative electron backscatter diffraction (EBSD) data analyses using the dictionary indexing (DI) approach: Overcoming indexing difficulties on geological materials
  18. Trace element inventory of meteoritic Ca-phosphates
  20. Insights into solar nebula formation of pyrrhotite from nanoscale disequilibrium phases produced by H2S sulfidation of Fe metal
  22. Unraveling the presence of multiple plagioclase populations and identification of representative two-dimensional sections using a statistical and numerical approach
  24. Refractive indices of minerals and synthetic compounds
  26. Can we use pyroxene weathering textures to interpret aqueous alteration conditions? Yes and No
  28. Phase relations and formation of K-bearing Al-10 Å phase in the MORB+H2O system: Implications for H2O- and K-cycles in subduction zones
  30. Effect of alkalis on the reaction of clinopyroxene with Mg-carbonate at 6 GPa: Implications for partial melting of carbonated lherzolite
  32. Synthesis and crystal structure of LiNbO3-type Mg3Al2Si3O12: A possible indicator of shock conditions of meteorites
  34. Single crystal synthesis of δ-(Al,Fe)OOH
  35. Letter
  36. EosFit-Pinc: A simple GUI for host-inclusion elastic thermobarometry
  38. New Mineral Names
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