U-Pb LA-ICP-MS dating of apatite in mafic rocks: Evidence for a major magmatic event at the Devonian-Carboniferous boundary in the Armorican Massif (France)
-
Anthony Pochon
, Marc Poujol
Abstract
Apatite is a ubiquitous accessory mineral found in most magmatic rocks and is often the only U-bearing mineral available to date mafic rocks because primary zircon and/or baddeleyite are not present. In this paper, U-Pb LA-ICP-MS dating of apatite was applied to seven different dike and sill samples of dolerite from the Variscan belt of Brittany (Armorican Massif, western France). These dolerites, which are characterized by a within-plate tholeiite geochemical signature, are organized in several dense swarms across the belt. Their geochemical compositions are homogeneous although they intrude a large geographical area subdivided into several domains each characterized by different tectonic-metamorphic settings. Their emplacement ages were so far poorly constrained due to the difficulty to date these mafic rocks using either the 40Ar/39Ar or the U-Pb methods on classical minerals like mica, plagioclase, or zircon. Although the closure temperature of apatite is lower than the emplacement temperature of the magma, physical models show that the time needed to solidify and cool these mafic dikes and sills below the apatite closure temperature is basically of the order of 100 years or less. Consequently, the U-Pb dates obtained on apatite can be interpreted as the emplacement ages for these mafic intrusions. Our results demonstrate that, in all cases, the apatite grains do carry enough radiogenic Pb to be dated by in situ U-Pb analyses and yield a 207Pb-corrected mean age of 363.4 ± 5.8 Ma. These results reveal the existence of a major and short-lived magmatic event in the Variscan belt of Brittany during the Devonian-Carboniferous transition, a feature further highlighted by field evidence. Beyond the geological implications of these results, U-Pb LA-ICP-MS dating of apatite appears to represent an ideal tool to date small size mafic intrusions.
Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html.
Acknowledgments
This work was supported by the French Geological Survey (BRGM), the region of Brittany, the OSUR, the CNRS-INSU and CESSUR program, and the Ulysses program (PHC). The authors thank the following groups and chief-geologists for allowing access to their granulate quarries: Y. Lemaitre and R. Le Droff from the “Pigeon Carrière” group, L. Seguin from the Eurovia group, the employees from the Hervé group, and the Nivet group. G. Wille (BRGM) is acknowledged for the microprobe analytical analyses. We particularly thank X. Le Coz and Y. Lepagnot from Géosciences Rennes laboratory for the thin sections and rock crushing preparations, respectively. We also address our thanks to the SARM (Nancy) for the whole-rock geochemistry. Constructive reviews by D. Chew, D. Harlov, and an anonymous reviewer have greatly improved the manuscript.
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- Influence of the octahedral cationic-site occupancies on the framework vibrations of Li-free tourmalines, with implications for estimating temperature and oxygen fugacity in host rocks
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- In situ X-ray observation of 10 Å phase stability at high pressure
- Research Article
- New mineral names
- Book Review
- Book Review: Pore-Scale Geochemical Processes, RIMG Volume 80
- Book Review
- Book Review: Highly Siderophile and Strongly Chalcophile Elements in High-Temperature Geochemistry and Cosmochemistry, RIMG Volume 81
Articles in the same Issue
- Highlights and Breakthroughs
- Melts, mush, and more: Evidence for the state of intermediate-to-silicic arc magmatic systems
- Investigating petrologic indicators of magmatic processes in volcanic rocks
- Nucleation rates of spherulites in natural rhyolitic lava
- Review
- Silicic magma reservoirs in the Earth’s crust
- Special Collection: New Advances in Subduction Zone Magma Genesis
- Petrogenesis of antecryst-bearing arc basalts from the Trans-Mexican Volcanic Belt: Insights into along-arc variations in magma-mush ponding depths, H2O contents, and surface heat flux
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Wayneburnhamite, Pb9Ca6(Si2O7)3(SiO4)3, an apatite polysome: The Mn-free analog of ganomalite from Crestmore, California
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- U-Pb LA-ICP-MS dating of apatite in mafic rocks: Evidence for a major magmatic event at the Devonian-Carboniferous boundary in the Armorican Massif (France)
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- Quantification of CO2 concentration in apatite
- Special Collection: Apatite: a Common Mineral, Uncommonly Versatile
- Phosphate minerals in the H group of ordinary chondrites, and fluid activity recorded by apatite heterogeneity in the Zag H3-6 regolith breccia
- Special Collection: Apatite: A Common Mineral, Uncommonly Versatile
- In situ elemental and isotopic analysis of fluorapatite from the Taocun magnetite-apatite deposit, Eastern China: Constraints on fluid metasomatism
- Special Collection: Geology and Geobiology of Lassen Volcanic National Park
- Acido-thermotolerant fungi from Boiling Springs Lake, LVNP: Potential for lignocellulosic biofuels
- Research Article
- Solid solution along the synthetic LiAISi2O6-LiFeSi2O6 (spodumene-ferri-spodumene) join: A general picture of solid solutions, bond lengths, lattice strains, steric effects, symmetries, and chemical compositions of Li clinopyroxenes
- Research Article
- Formation of hydrous stishovite from coesite in high-pressure hydrothermal environments
- Research Article
- Raman characterization of synthetic magnesian calcites
- Research Article
- Yangite, PbMnSi3O8·H2O, a new mineral species with double wollastonite silicate chains, from the Kombat mine, Namibia
- Research Article
- Ideal wollastonite and the structural relationship between the pyroxenoids and pyroxenes
- Research Article
- Influence of the octahedral cationic-site occupancies on the framework vibrations of Li-free tourmalines, with implications for estimating temperature and oxygen fugacity in host rocks
- Research Article
- In situ X-ray observation of 10 Å phase stability at high pressure
- Research Article
- New mineral names
- Book Review
- Book Review: Pore-Scale Geochemical Processes, RIMG Volume 80
- Book Review
- Book Review: Highly Siderophile and Strongly Chalcophile Elements in High-Temperature Geochemistry and Cosmochemistry, RIMG Volume 81