Surface area and porosity of primary silicate minerals
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Susan L. Brantley
Abstract
Surface area is important in quantifying mineral-water reaction rates. Specific surface area (SSA) was measured to investigate controls on this parameter for several primary silicate minerals (PSM) used to estimate rates of weathering. The SSA measured by gas adsorption for a given particle size of relatively impurity-free, laboratory-ground samples generally increases in the order: quartz ≈ olivine ≈ albite < oligoclase ≈ bytownite < hornblende ≈ diopside. Reproducibility of BET SSA values range from ±70% (SSA < 1000 cm2/g) to ± 5% (SSA > 4000 cm2/g) and values measured with N2 were observed to be up to 50% larger than values measured with Kr. For laboratory-ground Amelia albite and San Carlos olivine, SSA can be calculated using log (SSA, cm2/g) = b + m log (d), where d = grain diameter (μm), b = 5.2 ± 0.2 and m = -1.0 ± 0.1. A similar equation was previously published for laboratory-ground quartz. Some other samples showed SSA higher than predicted by these equations. In some cases, high SSA is attributed to significant second phase particulate content, but for other laboratory-ground samples, high SSA increased with observed hysteresis in the adsorption-desorption isotherms. Such hysteresis is consistent with the presence of pores with diameters in the range 2 to 50 nm (mesopores). In particular, porosity that contributes to BET-measured SSA is inferred for examples of laboratory-ground diopside, hornblende, and all compositions of plagioclase except albite, plus naturally weathered quartz, plagioclase, and potassium feldspar. Previous workers documented similar porosity in laboratory-ground potassium feldspar.
Surface area measured by gas adsorption may not be appropriate for extrapolation of interfacelimited rates of dissolution of many silicates if internal surface is present and if it does not dissolve equivalently to external surface. In addition, the large errors associated in measuring SSA of coarse and/or impurity-containing silicates suggest that surface area-normalized kinetics in both field and laboratory systems will be difficult to estimate precisely. Quantification of the porosity in laboratory- ground and naturally weathered samples may help to alleviate some of the discrepancy between laboratory- and field-based estimates of weathering rate
© 2015 by Walter de Gruyter Berlin/Boston
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Artikel in diesem Heft
- Patterns of mineral occurrence in metamorphic rocks
- A double magmatic heat pump at the core-mantle boundary
- High-temperature contact metamorphism of calc-silicate xenoliths in the Kiglapait Intrusion, Labrador
- Multiple pyroxene and amphibole assemblages in the amphibolite facies: Bulk compositional controls
- Margarite-corundum phyllites from the Appalachian orogen of South Carolina: Mineralogy and metamorphic history
- Continuous metamorphic gradient documented by graphitization and K-Ar age, southeast Otago, New Zealand
- Kyanite eclogite thermobarometry and evidence for thrusting of UHP over HP metamorphic rocks, Nordøyane, Western Gneiss Region, Norway
- Monazite geochronology of UHP and HP metamorphism, deformation, and exhumation, Nordøyane, Western Gneiss Region, Norway
- Solubilities of noble metals in Fe-containing silicate melts as derived from experiments in Fe-free systems
- Water speciation in silicate glasses and melts: Langmuir limited site model
- The ab initio study of the stability of low temperature Al/Si ordered albite, NaAlSi3O8
- The heat capacity of MgCr2O4, FeCr2O4, and Cr2O3 at low temperatures and derived thermodynamic properties
- Thermodynamics of the R3̅ to R3̅c phase transition in the ilmenite-hematite solid solution
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- Charge contrast imaging of geological materials in the environmental scanning electron microscope
- Chemical fine structure of Franciscan jadeitic pyroxene from Ward Creek, Cazadero area, California
- Crystal structure of CaMg2Al6O12, a new Al-rich high pressure form
- The crystal structure of “Tetragonal Almandine-Pyrope Phase” (TAPP): A reexamination
- The crystal structure of tetranatrolite from Mont Saint-Hilaire, Québec, and its chemical and structural relationship to paranatrolite and gonnardite
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- Dukeite, Bi3+24Cr86+O57(OH)6(H2O)3, a new mineral from Brejaúba, Minas Gerais, Brazil: Description and crystal structure
- Pseudosinhalite is a structural isotype of chondrodite
- Structure type and bulk modulus of Fe3S, a new iron-sulfur compound
- Single crystal elasticity of lawsonite
- In situ measurement of viscosity of liquids in the Fe-FeS system at high pressures and temperatures
