Single Ionic Volumes in Acetonitrile–Organic Cosolvent Mixtures at 298.15 K
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Henryk Piekarski
Abstract
Densities of binary nonaqueous mixtures of acetonitrile (AN) with 2-methoxyethanol (ME), N,N-dimethylacetamide (DMA) and propylene carbonate (PC) were determined over the whole composition range at 298.15 K. The excess molar volumes and the partial molar volumes of both components were calculated from these data. Densities of solutions of NaI, NaBPh4 and Ph4PI in solvent mixtures AN + ME and AN + DMA and of NaI solutions in mixtures of AN + PC were measured over the whole composition range of the mixed solvents at an electrolyte concentration equal 0.05 mol dm−3. From these densities, apparent molar volumes of electrolytes and ions were evaluated and analyzed. The relationship between the apparent molar volumes of ions and (κT/ε) parameter was tested and discussed.
© 2004 Oldenbourg Wissenschaftsverlag GmbH
Artikel in diesem Heft
- Preface
- Hofmeister Ion Effects on the Phase Diagrams of Water-Propylene Glycol Propyl Ethers
- Ab Initio Quantum Chemical and Molecular Dynamics Simulation Study of Lithium Iodide in Acetonitrile
- The Liquid Structure of Various Nitriles and N,N-Dimethylformamide Studied by the X-Ray Diffraction Method Using a CCD Detector
- Single Ionic Volumes in Acetonitrile–Organic Cosolvent Mixtures at 298.15 K
- Brownian Simulations Contribution to the Study of Ionic Dynamics in Aqueous Solutions
- Effects of Polarization on the Extents and Kinetics of Adsorption of Ionic and Neutral Aromatic Heterocyclics Exhibiting Orientation Transitions at a Porous C Electrode
- Reliable Thermodynamic Properties of Electrolyte Solutions – A Survey of Existing Data Sources
- Hydration of Molecular Anions with Oxygen Sites – a Monte Carlo Study
Artikel in diesem Heft
- Preface
- Hofmeister Ion Effects on the Phase Diagrams of Water-Propylene Glycol Propyl Ethers
- Ab Initio Quantum Chemical and Molecular Dynamics Simulation Study of Lithium Iodide in Acetonitrile
- The Liquid Structure of Various Nitriles and N,N-Dimethylformamide Studied by the X-Ray Diffraction Method Using a CCD Detector
- Single Ionic Volumes in Acetonitrile–Organic Cosolvent Mixtures at 298.15 K
- Brownian Simulations Contribution to the Study of Ionic Dynamics in Aqueous Solutions
- Effects of Polarization on the Extents and Kinetics of Adsorption of Ionic and Neutral Aromatic Heterocyclics Exhibiting Orientation Transitions at a Porous C Electrode
- Reliable Thermodynamic Properties of Electrolyte Solutions – A Survey of Existing Data Sources
- Hydration of Molecular Anions with Oxygen Sites – a Monte Carlo Study
