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High Time Resolution Multifrequency EPR of Radical Pair Intermediates in Photosynthetic Reaction Centers: Structure Determination on a Nanosecond Time Scale
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G. Link
, U. Heinen , T. Berthold , E. Ohmes , J.-U. Weidner und G. Kothe
Veröffentlicht/Copyright:
25. September 2009
Abstract
The primary steps of photosynthesis proceed via light-induced radical pairs as short-lived intermediates. In this paper we discuss novel coherence phenomena which can be observed for these species. It is demonstrated that the analysis of quantum beat oscillations in combination with multifrequency EPR and a magnetically oriented sample represents a powerful structural tool. We expect that this is of general interest, since the detailed structure of radical pair intermediates can be determined on a nanosecond time scale.
Published Online: 2009-9-25
Published in Print: 2004-1-1
© 2004 Oldenbourg Wissenschaftsverlag GmbH
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Artikel in diesem Heft
- EXAFS Spectroscopy – Fundamentals, Measurement Techniques, Data Evaluation and Applications in the Field of Phthalocyanines
- Kinetic Hydrogen/Deuterium Isotope Effects in Multiple Proton Transfer Reactions
- Nanomaterials as Flow Regulators in Dry Powders
- Scanning Electrochemical Microscopy as a Versatile Tool for Modifying Surfaces
- The Absorption Spectrum of Anisole and the Anisole/CO2 1:1-Cluster. The Influence of Intermolecular Interaction on Intramolecular Vibrations
- The Kinetics and Quantum Dynamics of Intramolecular Rearrangements in Highly Symmetrical Complexes: The Berry Pseudorotation
- High Time Resolution Multifrequency EPR of Radical Pair Intermediates in Photosynthetic Reaction Centers: Structure Determination on a Nanosecond Time Scale
- Book Reviews