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Establishment of Micellar Catalytic Field Using the p-Nitro-o-Carboxylbenzeneazo-8-Amino-quinoline – Cetyltrimethylammonium Bromide – Co(II) Ternary Complexation
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Hong-Wen Gao
Veröffentlicht/Copyright:
25. September 2009
Abstract
The micellar catalytic field was proposed in surfactant medium by investigating the complexation between p-nitro-o-carboxylbenzeneazo-8-aminoquinoline (NCBAAQ) and Co(II) at pH 8.8. The cationic surfactant, cetyl trimethylammonium bromide (CTAB) was added and the aggregation of NCBAAQ on CTAB obeys the Langmuir isothermal adsorption. The enrichment of NCBAAQ on CTAB micelle resulted in a sensitive and rapid complexation of NCBAAQ with Co(II). The ternary complexation was characterized by the microsurface adsorption – spectral correction (MSASC) technique. Results showed that the complex Co3NCBAAQ12CTAB78 is formed.
Published Online: 2009-9-25
Published in Print: 2003-11-1
© 2003 Oldenbourg Wissenschaftsverlag GmbH
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- Ion–Solvent Interactions and Determination of Single-Ion Gibbs Energies of Transfer from the Studies of the Solubility and Dissociation Constants of Oxalic Acid in Aquo + Methanolic Mixtures
- Formation of Nanoparticles by Photolysis from Metal and Carbon Bearing Molecules
- Electrochemical Behavior and Enhanced Stability of a Thin Film of Prussian Blue Deposited under Magnetic Field
- Influence of Iron Content on the Electrical and Dielectric Properties of La0.7Ba0.3Co1−yFeyO3
- Establishment of Micellar Catalytic Field Using the p-Nitro-o-Carboxylbenzeneazo-8-Amino-quinoline – Cetyltrimethylammonium Bromide – Co(II) Ternary Complexation
- Heteroassociation of Selected Diols with some Tertiary Amines
- Bursting Oscillations in the Revised Mechanism of the Hemin – Hydrogen Peroxide – Sulfite Oscillator
Artikel in diesem Heft
- Ion–Solvent Interactions and Determination of Single-Ion Gibbs Energies of Transfer from the Studies of the Solubility and Dissociation Constants of Oxalic Acid in Aquo + Methanolic Mixtures
- Formation of Nanoparticles by Photolysis from Metal and Carbon Bearing Molecules
- Electrochemical Behavior and Enhanced Stability of a Thin Film of Prussian Blue Deposited under Magnetic Field
- Influence of Iron Content on the Electrical and Dielectric Properties of La0.7Ba0.3Co1−yFeyO3
- Establishment of Micellar Catalytic Field Using the p-Nitro-o-Carboxylbenzeneazo-8-Amino-quinoline – Cetyltrimethylammonium Bromide – Co(II) Ternary Complexation
- Heteroassociation of Selected Diols with some Tertiary Amines
- Bursting Oscillations in the Revised Mechanism of the Hemin – Hydrogen Peroxide – Sulfite Oscillator
