Surface-Confined Coordination Chemistry with Porphyrins and Phthalocyanines: Aspects of Formation, Electronic Structure, and Reactivity
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Michael Gottfried
Abstract
Recent years have seen rapid progress in the field of surface-confined coordination chemistry. Adsorbed metal complexes of tetrapyrroles (porphyrins, phthalocyanines, corroles) are especially interesting in this context, since they combine a planar structure-determining element with an active site. While earlier studies of adsorbed metallo-tetrapyrroles mainly addressed aspects of molecular self-assembly, the focus of interest has shifted gradually to electronic structure and chemical reactivity. This article gives an overview of recent advances in the field of surface chemistry with tetrapyrroles. In particular, the following aspects will be discussed: intramolecular conformation and supramolecular ordering, electronic interaction with the substrate, surface-confined synthesis, and ligand-related effects such as the surface trans effect.
© by Oldenbourg Wissenschaftsverlag, München, Germany
Artikel in diesem Heft
- Preface - Special Topic Issue dedicated to Prof. Dr. Klaus Christmann on the occasion of his 65th birthday
- Interaction of Hydrogen with Bimetallic Surfaces
- Aspects of Molecular Chirality at Metal Surfaces
- Surface-Confined Coordination Chemistry with Porphyrins and Phthalocyanines: Aspects of Formation, Electronic Structure, and Reactivity
- Ligand Effect in Hydrogen Adsorption on Epitaxial Nickel Films
- CO Oxidation over a Pt(100) Surface in a Ternary Gas Mixture of CO, NO, and Oxygen
- Theoretical Approaches to Surface Kinetics: A Perspective
- Modification of the Growth of Iron on Ag(111) by Predeposited Organic Monolayers
- Synthesis, Structure, and Valency Verification of a Mn6IIIO2-Cluster
- Modern Nanotemplates Based on Graphene and Single Layer h-BN
- Size and Structure of Palladium Clusters Determined by XRD and HREM
- On the CO-Oxidation over Oxygenated Ruthenium
- The Adsorption of Ethene on Pd(111) and Ordered Sn/Pd(111) Surface Alloys
Artikel in diesem Heft
- Preface - Special Topic Issue dedicated to Prof. Dr. Klaus Christmann on the occasion of his 65th birthday
- Interaction of Hydrogen with Bimetallic Surfaces
- Aspects of Molecular Chirality at Metal Surfaces
- Surface-Confined Coordination Chemistry with Porphyrins and Phthalocyanines: Aspects of Formation, Electronic Structure, and Reactivity
- Ligand Effect in Hydrogen Adsorption on Epitaxial Nickel Films
- CO Oxidation over a Pt(100) Surface in a Ternary Gas Mixture of CO, NO, and Oxygen
- Theoretical Approaches to Surface Kinetics: A Perspective
- Modification of the Growth of Iron on Ag(111) by Predeposited Organic Monolayers
- Synthesis, Structure, and Valency Verification of a Mn6IIIO2-Cluster
- Modern Nanotemplates Based on Graphene and Single Layer h-BN
- Size and Structure of Palladium Clusters Determined by XRD and HREM
- On the CO-Oxidation over Oxygenated Ruthenium
- The Adsorption of Ethene on Pd(111) and Ordered Sn/Pd(111) Surface Alloys
