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Formation of the Silver Hydride Ion AgH+ upon the Reduction of Silver Ions by H· in Aqueous Solution. A Pulse Radiolysis Study
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A. Sarkar
Veröffentlicht/Copyright:
25. September 2009
The reaction of hydrogen atoms and of alcohol radicals with monovalent silver ions is studied in aqueous solution by means of pulse radiolysis. In acidic aqueous solutions containing silver ions and an alcohol, hydrogen atoms react with silver ions to form AgH+ with a rate constant of k=1.5 × 1010dm3mol-1s-1. This complex dissociates into free silver atoms and hydrogen ions with a first order rate constant of 2 × 107s-1. A reaction of alcohol radicals with silver ions could not be observed in aqueous solutions containing either methanol, ethanol or 2-propanol during times of up to 15ms; the rate constant would therefore have to be smaller than 1 × 104dm3mol-1s-1.
Received: 2006-5-10
Accepted: 2006-9-27
Published Online: 2009-9-25
Published in Print: 2007-3-1
© Oldenbourg Wissenschaftsverlag
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- Preface – Professor Dr. Arnim Henglein on the occasion of his 80th birthday
- Surface Chemistry of Semiconductor Nanocrystals
- Synthesis and Assembling of Semiconductor and Metal Nanocrystals
- The Electronic Role of the TiO2 Light-Scattering Layer in Dye-Sensitized Solar Cells
- Primary Processes During the Photodeposition of Ag Clusters on TiO2 Nanoparticles
- Photoactivity of Sol–Gel Derived Nitridated ZnxTiyOz-Films
- Photothermal Properties of Gold Nanoparticles
- Electro-Assisted Photo-Luminescence of Colloidal Germanium Nanoparticles
- Cobalt-Doped ZnO Nanorods Fabricated by a Simple Wet Chemical Route in Alcoholic Solution
- Influence of the Choice of Indium Precursor and Ligand on the Synthesis of InP Nanocrystals
- Formation of the Silver Hydride Ion AgH+ upon the Reduction of Silver Ions by H· in Aqueous Solution. A Pulse Radiolysis Study
- An Electrochemical Model for Gold Colloid Formation via Citrate Reduction
- Synthesis of Monodisperse PbS Nanoparticles and Their Assembly into Highly Ordered 3D Colloidal Crystals
Schlagwörter für diesen Artikel
Silver Hydride Ion;
Silver Ion;
Hydrogen Atom;
Alkyl Radical;
Pulse Radiolysis
Artikel in diesem Heft
- Preface – Professor Dr. Arnim Henglein on the occasion of his 80th birthday
- Surface Chemistry of Semiconductor Nanocrystals
- Synthesis and Assembling of Semiconductor and Metal Nanocrystals
- The Electronic Role of the TiO2 Light-Scattering Layer in Dye-Sensitized Solar Cells
- Primary Processes During the Photodeposition of Ag Clusters on TiO2 Nanoparticles
- Photoactivity of Sol–Gel Derived Nitridated ZnxTiyOz-Films
- Photothermal Properties of Gold Nanoparticles
- Electro-Assisted Photo-Luminescence of Colloidal Germanium Nanoparticles
- Cobalt-Doped ZnO Nanorods Fabricated by a Simple Wet Chemical Route in Alcoholic Solution
- Influence of the Choice of Indium Precursor and Ligand on the Synthesis of InP Nanocrystals
- Formation of the Silver Hydride Ion AgH+ upon the Reduction of Silver Ions by H· in Aqueous Solution. A Pulse Radiolysis Study
- An Electrochemical Model for Gold Colloid Formation via Citrate Reduction
- Synthesis of Monodisperse PbS Nanoparticles and Their Assembly into Highly Ordered 3D Colloidal Crystals
