Averaged Trajectory of Random Walk Fluctuations Having a Fixed Lifetime and its Application in Characterization of Simplest Chemical Equilibrium
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M. Šolc
Abstract
Recently, we found that for a simple first-order reaction having equilibrium constant equal to 1, the amplitudes of equilibrium fluctuations can be, on the discrete time scale (scale of reaction events), satisfactorily described using the random walk approximation for the distribution and mean amplitude of fluctuation having the fixed lifetime 2r reaction events. Below, we propose another characterization of fluctuations in the random walk introducing an averaged trajectory of fluctuations and suggest another formula for the mean amplitude of fluctuations having a fixed length. The results are used in characterization of equilibrium fluctuations of first order reversible chemical reaction having the equilibrium constant equal to 1.
© Oldenbourg Wissenschaftsverlag, München
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Artikel in diesem Heft
- Attacking a Small Beast: Ar–CO, a Prototype for Intermolecular Forces
- The Heats of Chemical Reactions: the Van't-Hoff Equation and Calorimetry
- Ion-Association and Solvation of Some Copper (I), Silver (I) and Tetraalkylammonium Salts in Binary Mixtures of Acetonitrile with n-Butyronitrile and N,N-Dimethylacetamide
- Influence of Molecular Hindered Rotations on NQR Spin Echoes
- Aerobic Oxidation of Benzyl Alcohol by Fe-System Catalyst
- Vapor Pressure Measurements of LiI + C2H5OH Solutions
- Solvation of the Ionic Liquid [C4mim][PF6] in Aqueous Ethanol Solutions from Molar Volume, Viscosity and Conductivity Measurements
- The Thermal Decomposition Kinetics of [Co(bipy)(H2O)4](C4H4O4)·4H2O
- Empirical Models of the Pair-Polarizability Trace and Anisotropy from Polarized and Depolarized Interaction-Induced Light Scattering Spectra for Gaseous Krypton
- Averaged Trajectory of Random Walk Fluctuations Having a Fixed Lifetime and its Application in Characterization of Simplest Chemical Equilibrium
- Book Review
