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Structural investigation of dichlorobis(benzimidazole)Zn(II) complex
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E. Sahin
Published/Copyright:
September 25, 2009
Abstract
The molecular structure of the title complex [ZnCl2(C7H6N2)2] was investigated by X-ray diffraction and IR spectroscopy. The Zn(II) complex crystallizes triclinically (P1̅ (no 2); a = 7.440(2) Å, b = 7.734(2) Å, c = 13.3127(4) Å, α = 85.91(2)°, β = 85.97(2)°, γ = 83.05(5)°, Z = 3; V = 757.3(3) Å3). In the molecular structure, the Zn atom is coordinated tetrahedrally by two Cl– anions and two benzimidazole ligands.
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Published Online: 2009-9-25
Published in Print: 2003-5-1
© 2003 Oldenbourg Wissenschaftsverlag GmbH
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Articles in the same Issue
- Solution of the structure and disorder of Ln13Br18B3 (Ln = Gd, Tb)
- Anomalous thermal expansion behaviour of Na8[AlSiO4]6(NO3)2-sodalite: P4̅3n to Pm3̅n phase transition by untilting and contraction of TO4 units
- Crystal structure of new hexahydrate dicobalt pyrophosphate Co2P2O7·6H2O: comparison with Co2P2O72H2O, α-, β- and γ-Co2P2O7
- Crystal structures and Raman spectra of Cu(OH)F and Cu3(OH)2F4
- Crystal chemistry of lead oxide phosphates: crystal structures of Pb4O(PO4)2, Pb8O5(PO4)2 and Pb10(PO4)6O
- Structural distortion of the α, β, and γ polymorphs of glycine on cooling
- Synthesis, structural and spectral studies of N-p-methylbenzyliden-N-phenyl-p,p′-dimethoxybenzoyl acetic acid hydrazide
- Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(–)-1-phenyl-ethyl ammonium percholorate
- Structural investigation of dichlorobis(benzimidazole)Zn(II) complex
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