A contribution to the crystal chemistry of DL-malates
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Michel Fleck
Abstract
The crystal structures of twelve different DL-malates have been determined and refined from single-crystal X-ray diffraction data. In addition, powder diffrac-tion data were used for the refinement of the lattice pa-rameters. The title compounds are the neutral DL-malates Li2(C4H4O5)·2H2O (space group P21/c), Mn(C4H4O5)·3H2O (Pbca), Cd(C4H4O5)·3H2O (P21/n), Sr2(C4H4O5)2·5H2O (P1̅) and Ba(C4H4O5). 2H2O (P1̅) as well as the acid DL-malates RbH(C4H4O5) (Fdd2), CsH(C4H4O5)·H2O (P21/n), MgH2(C4H4O5)2·4H2O (C2/c), CaH2(C4H4O5)2·2H2O (C2/c), ZnH2(C4H5O5)2·4H2O (C2/c), LiH3(C4H4O5)2 (P1̅), CsH3(C4H4O5)2 (P1̅). A comparison of DL-malate structures and a scheme of structural characterization according to cation polyhedra connection is proposed.
© 2001 Oldenbourg Wissenschaftsverlag GmbH
Artikel in diesem Heft
- Thermal expansion of decagonal Al70.7Co13.3Ni16.0 in the temperature range 15–300 K
- The intermediate phase of strontium chromate aluminate sodalite
- Crystal structure and elastic properties of betaine fumarate and of betaine maleate, two isomers of ((CH3)3NCH2COOH . OOC(CH)2COOH
- Synthesis, electronic and crystal structure of a new organic semiconductor tetramethyltetrathiafulvalene-trinitroresorcinol (2:1), (TMTTF)2(C6H2N3O8)
- Synthesis and crystal structure determination of 6-phenyl-5-phenylsulfonyl-1,2,3,4-tetrahydropyrimidine-2-thione from neutron powder diffraction data
- A contribution to the crystal chemistry of DL-malates
- Absorption correction for crystal-environment attachments from direction cosines
- Book Review
Artikel in diesem Heft
- Thermal expansion of decagonal Al70.7Co13.3Ni16.0 in the temperature range 15–300 K
- The intermediate phase of strontium chromate aluminate sodalite
- Crystal structure and elastic properties of betaine fumarate and of betaine maleate, two isomers of ((CH3)3NCH2COOH . OOC(CH)2COOH
- Synthesis, electronic and crystal structure of a new organic semiconductor tetramethyltetrathiafulvalene-trinitroresorcinol (2:1), (TMTTF)2(C6H2N3O8)
- Synthesis and crystal structure determination of 6-phenyl-5-phenylsulfonyl-1,2,3,4-tetrahydropyrimidine-2-thione from neutron powder diffraction data
- A contribution to the crystal chemistry of DL-malates
- Absorption correction for crystal-environment attachments from direction cosines
- Book Review
