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TPO transfer from a rhenium(V) complex onto a salicylaldoxime-bridged complex with [MnIII3O] core
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Małgorzata Hołyńska
Published/Copyright:
April 2, 2012
Abstract
A triangular Mn(III) complex with an [MnIII3μ3-O(sao)3] unit (sao – doubly deprotonated salicyläaldoxime) and unprecedented coordination by a TPO (triphenylphosphine oxide) ligand is the result of a transfer of the TPO ligand from a rhenium(V) complex onto a pre-formed [MnIII3O] unit. In the crystal structure, isomeric complex molecules with different patterns of their terminal substituents form hydrogen-bonded dimers.
Published Online: 2012-04-02
Published in Print: 2012-06
© by Oldenbourg Wissenschaftsverlag, Marburg, Germany
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Articles in the same Issue
- Reconstructions of electron density by the Maximum Entropy Method from X-ray powder diffraction data based on incomplete and complete crystal structure models: a case study of apatites with different intercalated metal atoms
- X-ray powder diffraction investigation of the faulted crystal structure of MnH2P3O10 · 2H2O
- Exit wave reconstruction from focal series of HRTEM images, single crystal XRD and total energy studies on SbxWO3+y (x ∼ 0.11)
- TPO transfer from a rhenium(V) complex onto a salicylaldoxime-bridged complex with [MnIII3O] core
- X-ray crystal structures of solvated bisimidazole derivatives including a half-way analogous lophine-type compound
- Supramolecular isomerism in coordination polymers sustained by hydrogen bonding: bis[Zn(S2CN(Me)CH2CH2OH)2](N,N‘-bis(pyridin-3-ylmethyl)thioxalamide)
- Structures of 1-(substituted-phenyl)-4-hydroxymethyl- and -4-fluoromethyl-1,2,3-triazoles
- Crystal structure of betulinic acid-DMSO solvate
