Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
Four distannoxane derivatives containing the bidentate 2-amidoethyl ligand
-
R. Alan Howie
Veröffentlicht/Copyright:
19. Mai 2011
Abstract
Structures containing cyclic, oxygen bridged complexes of general form (RSnCl2OR‘)2, where R is the bidentate (2-amidoethyl-C,O) ligand, are described. In 1 and 2R‘ is H and Me, respectively, while 3 is the methanol solvate of 1 and 4 a 1 : 1 co-crystal of 1 and 1,2-bis(n-propylsulfinyl)ethane. In all of the structures tin is six-coordinate in an octahedral environment distorted by the bite angle of the bidentate ligand and, most markedly, by the intra-ring O—Sn—O angles involving the bridging oxygen atoms. The creation of three- and two-dimensional connectivity in the supramolecular structures is dominated by intermolecular hydrogen-bonds with the amide NH2 as the donor species.
Keywords: Single crystal structure analysis; X-ray diffraction; 2-Amidoethyl; Bidentate ligand; Organotin(IV) complexes
Published Online: 2011-05-19
Published in Print: 2011-09
© by Oldenbourg Wissenschaftsverlag, Belo Horizonte, Germany
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Kinematic diffraction from a mathematical viewpoint
- Perfect precise colorings of plane regular tilings
- Crystal structure of whiteite-(CaFeMg) from Crosscut Creek, Canada
- Four distannoxane derivatives containing the bidentate 2-amidoethyl ligand
- Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate (IV), (TMA)2[TiF6]
- Powder diffraction and solid state DFT study of the trans-bis(5-methylsalicylato)-bis(N,N-diethylnicotinamide)-diaquacopper(II) complex structure
Schlagwörter für diesen Artikel
Single crystal structure analysis;
X-ray diffraction;
2-Amidoethyl;
Bidentate ligand;
Organotin(IV) complexes
Artikel in diesem Heft
- Kinematic diffraction from a mathematical viewpoint
- Perfect precise colorings of plane regular tilings
- Crystal structure of whiteite-(CaFeMg) from Crosscut Creek, Canada
- Four distannoxane derivatives containing the bidentate 2-amidoethyl ligand
- Temperature dependent lattice distortion and high temperature phase transition of pseudo-cubic bis(tetramethylammonium) hexafluorotitanate (IV), (TMA)2[TiF6]
- Powder diffraction and solid state DFT study of the trans-bis(5-methylsalicylato)-bis(N,N-diethylnicotinamide)-diaquacopper(II) complex structure
