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Influence of added and differently attached methyl groups on the crystal structure of 2,6-diphenyl substituted p-nitrophenol
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Sanrda Kurjatschij
Published/Copyright:
November 24, 2010
Abstract
In order to find out the consequences of a methyl substitution on the crystalline packing behaviour of the parent compound 2,6-diphenyl-4-nitrophenol, three analogous nitrophenols being substituted at different positions of the lateral phenyl rings were comparatively studied with regard to their crystal structures. While the molecular structures do not suggest marked differences, the network structures do, showing dependency on the presence and positional substitution of the methyl groups. This is revealed by the formation of weakly O—H…π bonded dimers or supramolecular chains, more strongly hold together through interacting OH and nitro groups.
Keywords: Nitrophenols; Tolyl substitution; Hydrogen bonding; Single crystal structure analysis; X-ray diffraction
Published Online: 2010-11-24
Published in Print: 2011-03
© by Oldenbourg Wissenschaftsverlag, Freiberg, Germany
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Keywords for this article
Nitrophenols;
Tolyl substitution;
Hydrogen bonding;
Single crystal structure analysis;
X-ray diffraction
Articles in the same Issue
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