New copper selenites. Part A: K2Cu2(SeO3)3 and K2Cu3(SeO3)4
Abstract
The new compounds K2Cu2(SeO3)3 and K2Cu3(SeO3)4 were synthesized in the course of low-hydrothermal experiments on natrochalcite-type selenate representatives. The crystal structures were determined by direct methods from single-crystal X-ray diffraction data. K2Cu2(SeO3)3: space group Cmcm, Z = 4, a = 5.312(1) Å, b = 9.858(3) Å, c = 17.595(5) Å, V = 921.4(4) Å3, R1 = 0.023. K2Cu3(SeO3)4: space group P[unk], Z = 1, a = 5.443(1) Å, b = 7.158(2) Å, c = 8.369(3) Å, α = 95.26(2)°, β = 108.58(2)°, γ = 92.17(2)°, V = 307.0(2) Å3; R1 = 0.035. Both compounds contain sheets built from edge- or cornersharing CuOn polyhedra (n = 5,6) and trigonal pyramidal selenite groups. These units are linked via the potassium atoms. In K2Cu2(SeO3)3 one of the two selenite groups is strongly disordered.
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- Peculiarities of crystal structures of rare-earth metal sulfides with the period 4 Å
- X-ray powder diffraction ab initio structure solution of materials from solid state synthesis: the copper oxide case
- New copper selenites. Part A: K2Cu2(SeO3)3 and K2Cu3(SeO3)4
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- Crystal and molecular structure of bis(5,7-dimethyl-[1,2,4]triazololium-N3-[1,5-a]pyrimidine) hexachlorostannate: [Hdmtp]2[SnCl6]
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- An Introduction to X-Ray Crystallography
- Density-Functional Methods in Chemistry and Materials Science
- Devices based on Low-dimensional Semiconductor Structures
- Kristallographie. Eine Einführung für Naturwissenschaftler
- Books Received
Artikel in diesem Heft
- Peculiarities of crystal structures of rare-earth metal sulfides with the period 4 Å
- X-ray powder diffraction ab initio structure solution of materials from solid state synthesis: the copper oxide case
- New copper selenites. Part A: K2Cu2(SeO3)3 and K2Cu3(SeO3)4
- Ordering in DyFe6Sn6 studied by conventional X-ray single crystal diffraction
- New polymorphic and pseudosymmetrical cobalt selenite monohydrates, CoSe03 · H2O II and CoSeO3 · H2O III
- The crystal structures of NaMgPO4, Na2CaMg(PO4)2 and Na18Ca13Mg5(PO4)18: new examples for glaserite related structures
- Compression of cadmium orthosilicate, Cd2SiO4: a high-pressure single-crystal diffraction study
- Structure of 5-nitro-2-tosylaminobenzaldehyde di(morpholin-4-yl)aminal complex with carbon tetrachloride
- X-ray structure of and refinement strategy for disordered triphenyl(2-pyridinethiolato)tin(IV): [Ph3Sn(2-pyS)]
- Crystal and molecular structure of bis(5,7-dimethyl-[1,2,4]triazololium-N3-[1,5-a]pyrimidine) hexachlorostannate: [Hdmtp]2[SnCl6]
- The crystal and molecular structure of {8-[2-(6-methoxy-2-naphthyl)-1-ethynyl]-1-naphthyl}-trimethylstannane: [Me3Sn(C10H6C=CC10H6OMe)]
- An Introduction to X-Ray Crystallography
- Density-Functional Methods in Chemistry and Materials Science
- Devices based on Low-dimensional Semiconductor Structures
- Kristallographie. Eine Einführung für Naturwissenschaftler
- Books Received
