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Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra
I. Crystal structure of chloromenite, Cu9O2(SeO3)4Cl6
Veröffentlicht/Copyright:
28. Juli 2010
Abstract
The crystal structure of chloromenite, Cu9O2(SeO3)4Cl6, a = 14.170(3) Å, b = 6.262(1) Å, c = 12.999(3) Å, β = 113.05(1)°, V = 1061.3(4) Å3, Z = 2, space group I2/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F2) = 0.128). The structure is based on unbranched zweier single chains {uB, 11∞} [O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar [uB, l1∞}[O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.
Published Online: 2010-7-28
Published in Print: 1998-12-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Artikel in diesem Heft
- Surface crystallography by low energy electron diffraction
- Growth and characterization of the new double sulphate, Li3Rb(SO4)2 · H2O
- Crystal structure determination of Ag2Ga by single crystal X-ray diffraction
- Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra
- Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra
- Crystal structures of manganese hydrogen sulfates – Mn(HSO4)2, Mn(HSO4)2 · H2O and Mn(HSO4)2(H2SO4)2
- The low-temperature structure and phase transition of hemimorphite, Zn4Si2O7(OH)2 · H2O
- The crystal and molecular structures of R2SnCl2(1,10-phenanthroline), R = iPr, Cy, CH2Ph and R2 = Me, Ph: a comparison between solid state and theoretical structures
Artikel in diesem Heft
- Surface crystallography by low energy electron diffraction
- Growth and characterization of the new double sulphate, Li3Rb(SO4)2 · H2O
- Crystal structure determination of Ag2Ga by single crystal X-ray diffraction
- Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra
- Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra
- Crystal structures of manganese hydrogen sulfates – Mn(HSO4)2, Mn(HSO4)2 · H2O and Mn(HSO4)2(H2SO4)2
- The low-temperature structure and phase transition of hemimorphite, Zn4Si2O7(OH)2 · H2O
- The crystal and molecular structures of R2SnCl2(1,10-phenanthroline), R = iPr, Cy, CH2Ph and R2 = Me, Ph: a comparison between solid state and theoretical structures
