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Structure investigations of Tl(I)-arsenates(V): Tl3(AsO4), Tl2Cu(I)(AsO4) and TlCu(II)2(AsO4)(AsO3OH)
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July 28, 2010
Abstract
The three Tl(I)-arsenates(V) Tl3AsO4) [a = 8.517(3) Å, c = 5.233(2) Å, space group P63, Z = 2], Tl2Cu(I)(AsO4) [a = 6.000(3) Å, = 5.343(2) Å, c = 8.616(3) Å, β = 98.05(3)°, space group P21, Z = 2], and TlCu(II)2(AsO4)(AsO3OH) [a = 6.407(2) Å, b = 11.245(4) Å, c = 10.173(3) Å, β = 98.64(2)°], space group P21/c, Z = 4] have been synthesized under hydrothermal conditions. Their structures were determined from single crystal X-ray diffraction data.
Published Online: 2010-7-28
Published in Print: 1998-1-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- A grid search procedure of positioning a known molecule in an unknown crystal structure with the use of powder diffraction data
- On the indexing of 3T mica polytype
- Symmetry analysis and the atomic distortions of the phase transitions in CsZnPO4
- The magnetic structure of braunite Mn2+Mn3+6O8/SiO4
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- Pulverdiffraktometrische Untersuchungen am System Sr3−xCaxAl2O6 sowie Einkristallstrukturanalysen für die Fälle x = 1,395(8), 1,62(1) und 2,12(1)
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