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Crystal and molecular structures of three diimine adducts of diphenyltin dichloride

Veröffentlicht/Copyright: 28. Juli 2010
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 210 Heft 9

Abstract

The crystal structures of three diimine adducts of diphenyltin dichloride have been determined at room temperature. The colorless crystals of the adduct formed with 5-methylphenanthroline, [Ph2SnCl2(5-Mephen)], C25H20Cl2N2Sn, are monoclinic, space group P21/n with unit cell dimensions a = 9.393(5) Å b = 12.896(3) Å, c = 18.034(4) Å, β = 94.48(3)°, Z = 4 and Dx = 1.641Mg m−3. The yellow crystals of the 4,7-dimethylphenanthroline adduct, [Ph2SnCl2(4,7-Me2phen)], C26H22Cl2N2Sn, are monoclinic, space group P21/n with unit cell dimensions a = 9.163(2) Å, b = 17.828(4) Å, c = 14.395(5) Å, β = 101.29(2)°, Z = 4 and Dx = 1.590Mg m−3. Yellow crystals of the 4,5-diazafluorene-9-one adduct, [Ph2SnCl2(4,5-diazafluorene-9-one)], C23H16Cl2N2OSn, are orthorhombic, space group Pbca with unit cell dimensions a = 16.239(2) Å, b = 16.673(2) Å, c = 16.058(2) Å, Z = 8 and Dx = 1.607Mg m−3. The structures were solved by direct methods and refined by a full-matrix least-squares procedure to final R = 0.043 using 2542 reflections for [Ph2SnCl2(5-Mephen)], R = 0.060 using 2521 reflections for [Ph2SnCl2(4,7-Me2phen)], and R = 0.038 using 1919 reflections for [Ph2SnCl2(4,5-diazafluorene-9-one)]. The tin atoms in the three adducts exist in distorted octahedral geometries with the phenyl substituents occupying trans positions. An examinations of the derived parameters in the three structures shows that the two phenanthroline ligands have similar coordinating abilities towards Ph2SnCl2 and that these ligands are stronger Lewis bases than 4,5-diazafluorene-9-one.

Published Online: 2010-7-28
Published in Print: 1995-9-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Artikel in diesem Heft

  1. The intensity of forbidden reflections of pyrope: Umweganregung or symmetry reduction?
  2. Darstellung und Kristallstruktur von fehlordnungsfreiem Bismuttriiodid
  3. Al2GeO4(OH)2: Rietveld refinement and stereochemical discussion
  4. Crystal structure of bis(N-methyl-3-ethoxysalicylideneaminato)-copper(II)
  5. Molecular structure and intermolecular organization in the crystalline 1:2 complex of Zn(II)-tetra(3-hydroxyphenyl)porphyrin with dimethylsulphoxide
  6. Crystal and molecular structures of three diimine adducts of diphenyltin dichloride
  7. Trigonal planar geometry of silver in bis[acetatotriphenylphosphinesilver(I)] hemihydrate, [CH3CO2Ag · P(C6H5)3]2 · ½ H2O
  8. Crystal structure and molecular packing analysis of 1,5-anhydropentitols and per-O-acetyl derivatives
  9. Crystal structure of oxonium hexachloroplatinate(IV), (H3O)2PtCl6
  10. Crystal structure of titanium(III) borate, TiBO3
  11. Crystal structure of thorium tetrarhenium disilicide, ThRe4Si2
  12. Crystal structure of hafnium(IV) chloride, HfCl4
  13. Crystal structure of indium aluminium ditelluride, InAlTe2
  14. Crystal structure of thallium tetrabromoferrate(III), TlFeBr4
  15. Crystal structure of caesium tetraiodoferrate(III), CsFeI4
  16. Redetermination of the crystal structures of lithium zinc iodide, Li2ZnI4, and sodium zinc chloride, Na2ZnCl4
  17. Crystal structures of oxoselenoantimonates(III) of sodium and rubidium, Na6(Sb12O18)(SbSe3)2(Na1.86Sb0.14)((OH)2.28(H2O)4.02) and Rb6(Sb12O18)(SbSe3)2Sb0.22((OH)0.66(H2O)3.48)
  18. Crystal structure of carbonyl(η5-cyclopentadienyl)[(R)-(+)-iminphos]-iron(II)-hexafluorophosphate, ([(R)-(+)-iminphos] = (+)-diphenyl(2-{[(R)-1-phenylethylimino]methyl}phenyl)-phosphane), C33H29FePNO(PF6)
  19. Crystal structure of bis(tricyclohexylphosphine)gold(I) bis(1,2-dicyanoethylene-1,2-dithiolato)aurate(III),Au(P(C6H11)3)2Au(C2(CN)2S2)2
  20. Crystal structure of catena-bis[μ-(diphenyldithiophospinato)-digold](Au–Au), C12H10AuPS2
  21. Crystal structure of 5-(2,6-dichlorophenyl)-4-ethoxycarbonyl-3-phenyl-δ2-isoxazoline, C18H15Cl2NO3
  22. Crystal structure of N,N,N′,N′-bis(cyclohexylethyl)thiuram disulphide, C9H16NS2
  23. Crystal structure of 3-(2-furyl)acrylic acid, C7H6O3
  24. Crystal structure of 1-trimethylammonium-4-dimethylaminobenzene ozonide, (CH3)2N(C6H4)N(CH3)3O3
  25. Crystal structure of tetraphenylphosphonium hexaaquadichloropraseodym(III) dihydrate, (P(C6H5)4(PrCl2(H2O)6)Cl2(H2O)2
  26. Crystal structure of 1,1-biscyclopentadienyl-2,4-bis(trimethylsilyl)-3-(t-butylethynyl)-7-(t-butyl)zirconacyclohepta-2,4,5,6-tetraene, C32H46Si2Zr
  27. Crystal structure of (Z)-2,3-bis(3,4-dimethoxyphenyl)-2-propen-1-ol–benzene(2/1), C22H25O5
  28. Crystal structure of 2,2′-anhydro-5-ethyluridine, C11H14N2O5
  29. Crystal structure of (E)-5-(1-butenyl)-2′-deoxyuridine, C13H18N2O5
  30. Crystal structure of bis(1-aza-bicylo[2.2.2]octane)-dicyano-mercury(II), Hg(C7H13N)2(CN)2
  31. Crystal structure of diaquabis(isothiocyanato)bis(1,3,5,7-tetraazatricyclo[3.3.1.1]decane)nickel(II) tetraaquabis(isothiocyanato)nickel(II) water(1/1/2), (Ni(NCS)2(C6H12N4)2(H2O)2)(Ni(NCS)2(H2O)4)(H2O)2
  32. Crystal structure of trimethyl-dibenzo[b,e]2-azabicyclo[2.2.2]octane-2,3,3-carboxylate, C21H19NO6
  33. Crystal structure of bis(2-nitro-4-trifluoromethyl-benzenesulfonyl)imide sodium salt monohydrate, Na(C6H3NO2CF3SO2)2N(H2O)
  34. Crystal structure of tricarbonyl{5-ethoxycarbonyl-([2.2]metacyclophane)}-anti-chromium, (C19H20O2)Cr(CO)3
  35. Crystal structure of tricarbonyl{5-ethoxycarbonyl-{dispiro-[1,3-dithiane-2,1′-[2.2]metacyclophane-10′,2″[1,3]dithiane]-(B)}}-anti-chromium, (C25H28O2S4)Cr(CO)3
  36. Redetermination of the crystal structure of bis(N-2-hydroxyethylsalicylideneaminato)copper(II), Cu(C9H10NO2)2
  37. Redetermination of the crystal structure of bis(N-phenylsalicylideneaminato)copper(II), Cu(C13H10NO)2
https://doi.org/10.1524/zkri.1995.210.9.669

Artikel in diesem Heft

  1. The intensity of forbidden reflections of pyrope: Umweganregung or symmetry reduction?
  2. Darstellung und Kristallstruktur von fehlordnungsfreiem Bismuttriiodid
  3. Al2GeO4(OH)2: Rietveld refinement and stereochemical discussion
  4. Crystal structure of bis(N-methyl-3-ethoxysalicylideneaminato)-copper(II)
  5. Molecular structure and intermolecular organization in the crystalline 1:2 complex of Zn(II)-tetra(3-hydroxyphenyl)porphyrin with dimethylsulphoxide
  6. Crystal and molecular structures of three diimine adducts of diphenyltin dichloride
  7. Trigonal planar geometry of silver in bis[acetatotriphenylphosphinesilver(I)] hemihydrate, [CH3CO2Ag · P(C6H5)3]2 · ½ H2O
  8. Crystal structure and molecular packing analysis of 1,5-anhydropentitols and per-O-acetyl derivatives
  9. Crystal structure of oxonium hexachloroplatinate(IV), (H3O)2PtCl6
  10. Crystal structure of titanium(III) borate, TiBO3
  11. Crystal structure of thorium tetrarhenium disilicide, ThRe4Si2
  12. Crystal structure of hafnium(IV) chloride, HfCl4
  13. Crystal structure of indium aluminium ditelluride, InAlTe2
  14. Crystal structure of thallium tetrabromoferrate(III), TlFeBr4
  15. Crystal structure of caesium tetraiodoferrate(III), CsFeI4
  16. Redetermination of the crystal structures of lithium zinc iodide, Li2ZnI4, and sodium zinc chloride, Na2ZnCl4
  17. Crystal structures of oxoselenoantimonates(III) of sodium and rubidium, Na6(Sb12O18)(SbSe3)2(Na1.86Sb0.14)((OH)2.28(H2O)4.02) and Rb6(Sb12O18)(SbSe3)2Sb0.22((OH)0.66(H2O)3.48)
  18. Crystal structure of carbonyl(η5-cyclopentadienyl)[(R)-(+)-iminphos]-iron(II)-hexafluorophosphate, ([(R)-(+)-iminphos] = (+)-diphenyl(2-{[(R)-1-phenylethylimino]methyl}phenyl)-phosphane), C33H29FePNO(PF6)
  19. Crystal structure of bis(tricyclohexylphosphine)gold(I) bis(1,2-dicyanoethylene-1,2-dithiolato)aurate(III),Au(P(C6H11)3)2Au(C2(CN)2S2)2
  20. Crystal structure of catena-bis[μ-(diphenyldithiophospinato)-digold](Au–Au), C12H10AuPS2
  21. Crystal structure of 5-(2,6-dichlorophenyl)-4-ethoxycarbonyl-3-phenyl-δ2-isoxazoline, C18H15Cl2NO3
  22. Crystal structure of N,N,N′,N′-bis(cyclohexylethyl)thiuram disulphide, C9H16NS2
  23. Crystal structure of 3-(2-furyl)acrylic acid, C7H6O3
  24. Crystal structure of 1-trimethylammonium-4-dimethylaminobenzene ozonide, (CH3)2N(C6H4)N(CH3)3O3
  25. Crystal structure of tetraphenylphosphonium hexaaquadichloropraseodym(III) dihydrate, (P(C6H5)4(PrCl2(H2O)6)Cl2(H2O)2
  26. Crystal structure of 1,1-biscyclopentadienyl-2,4-bis(trimethylsilyl)-3-(t-butylethynyl)-7-(t-butyl)zirconacyclohepta-2,4,5,6-tetraene, C32H46Si2Zr
  27. Crystal structure of (Z)-2,3-bis(3,4-dimethoxyphenyl)-2-propen-1-ol–benzene(2/1), C22H25O5
  28. Crystal structure of 2,2′-anhydro-5-ethyluridine, C11H14N2O5
  29. Crystal structure of (E)-5-(1-butenyl)-2′-deoxyuridine, C13H18N2O5
  30. Crystal structure of bis(1-aza-bicylo[2.2.2]octane)-dicyano-mercury(II), Hg(C7H13N)2(CN)2
  31. Crystal structure of diaquabis(isothiocyanato)bis(1,3,5,7-tetraazatricyclo[3.3.1.1]decane)nickel(II) tetraaquabis(isothiocyanato)nickel(II) water(1/1/2), (Ni(NCS)2(C6H12N4)2(H2O)2)(Ni(NCS)2(H2O)4)(H2O)2
  32. Crystal structure of trimethyl-dibenzo[b,e]2-azabicyclo[2.2.2]octane-2,3,3-carboxylate, C21H19NO6
  33. Crystal structure of bis(2-nitro-4-trifluoromethyl-benzenesulfonyl)imide sodium salt monohydrate, Na(C6H3NO2CF3SO2)2N(H2O)
  34. Crystal structure of tricarbonyl{5-ethoxycarbonyl-([2.2]metacyclophane)}-anti-chromium, (C19H20O2)Cr(CO)3
  35. Crystal structure of tricarbonyl{5-ethoxycarbonyl-{dispiro-[1,3-dithiane-2,1′-[2.2]metacyclophane-10′,2″[1,3]dithiane]-(B)}}-anti-chromium, (C25H28O2S4)Cr(CO)3
  36. Redetermination of the crystal structure of bis(N-2-hydroxyethylsalicylideneaminato)copper(II), Cu(C9H10NO2)2
  37. Redetermination of the crystal structure of bis(N-phenylsalicylideneaminato)copper(II), Cu(C13H10NO)2
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