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Molecular structure and intermolecular organization in the crystalline 1:2 complex of Zn(II)-tetra(3-hydroxyphenyl)porphyrin with dimethylsulphoxide

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 210 Issue 9

Abstract

Zn (II)-tetra(3-hydroxyphenyl)porphyrin (C44H28N4O4Zn) was obtained as solvate (1:2) by recrystallization of the commercially available metalloporphyrin derivative from dimethylsulphoxide (DMSO). The crystals are monoclinic, space group C2/c, with a = 1883.9(4) pm, b = 1200.9(2) pm, c = 2084.6(5) pm and β = 117.45(2)°. They consist of five-coordinated square-pyramidal metalloporphyrin units, involving one DMSO ligand at the axial position. These units are cross-linked in the lattice by an extensive network of hydrogen bonds. The second molecule of the DMSO approaches the other side of the porphyrin core. It is not linked to the metal center, but takes part in H-bonding interactions with adjacent porphyrin molecules. The 1:2 porphyrin-DMSO clusters are orientationally disordered in the crystal lattice.

Published Online: 2010-7-28
Published in Print: 1995-9-1

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Articles in the same Issue

  1. The intensity of forbidden reflections of pyrope: Umweganregung or symmetry reduction?
  2. Darstellung und Kristallstruktur von fehlordnungsfreiem Bismuttriiodid
  3. Al2GeO4(OH)2: Rietveld refinement and stereochemical discussion
  4. Crystal structure of bis(N-methyl-3-ethoxysalicylideneaminato)-copper(II)
  5. Molecular structure and intermolecular organization in the crystalline 1:2 complex of Zn(II)-tetra(3-hydroxyphenyl)porphyrin with dimethylsulphoxide
  6. Crystal and molecular structures of three diimine adducts of diphenyltin dichloride
  7. Trigonal planar geometry of silver in bis[acetatotriphenylphosphinesilver(I)] hemihydrate, [CH3CO2Ag · P(C6H5)3]2 · ½ H2O
  8. Crystal structure and molecular packing analysis of 1,5-anhydropentitols and per-O-acetyl derivatives
  9. Crystal structure of oxonium hexachloroplatinate(IV), (H3O)2PtCl6
  10. Crystal structure of titanium(III) borate, TiBO3
  11. Crystal structure of thorium tetrarhenium disilicide, ThRe4Si2
  12. Crystal structure of hafnium(IV) chloride, HfCl4
  13. Crystal structure of indium aluminium ditelluride, InAlTe2
  14. Crystal structure of thallium tetrabromoferrate(III), TlFeBr4
  15. Crystal structure of caesium tetraiodoferrate(III), CsFeI4
  16. Redetermination of the crystal structures of lithium zinc iodide, Li2ZnI4, and sodium zinc chloride, Na2ZnCl4
  17. Crystal structures of oxoselenoantimonates(III) of sodium and rubidium, Na6(Sb12O18)(SbSe3)2(Na1.86Sb0.14)((OH)2.28(H2O)4.02) and Rb6(Sb12O18)(SbSe3)2Sb0.22((OH)0.66(H2O)3.48)
  18. Crystal structure of carbonyl(η5-cyclopentadienyl)[(R)-(+)-iminphos]-iron(II)-hexafluorophosphate, ([(R)-(+)-iminphos] = (+)-diphenyl(2-{[(R)-1-phenylethylimino]methyl}phenyl)-phosphane), C33H29FePNO(PF6)
  19. Crystal structure of bis(tricyclohexylphosphine)gold(I) bis(1,2-dicyanoethylene-1,2-dithiolato)aurate(III),Au(P(C6H11)3)2Au(C2(CN)2S2)2
  20. Crystal structure of catena-bis[μ-(diphenyldithiophospinato)-digold](Au–Au), C12H10AuPS2
  21. Crystal structure of 5-(2,6-dichlorophenyl)-4-ethoxycarbonyl-3-phenyl-δ2-isoxazoline, C18H15Cl2NO3
  22. Crystal structure of N,N,N′,N′-bis(cyclohexylethyl)thiuram disulphide, C9H16NS2
  23. Crystal structure of 3-(2-furyl)acrylic acid, C7H6O3
  24. Crystal structure of 1-trimethylammonium-4-dimethylaminobenzene ozonide, (CH3)2N(C6H4)N(CH3)3O3
  25. Crystal structure of tetraphenylphosphonium hexaaquadichloropraseodym(III) dihydrate, (P(C6H5)4(PrCl2(H2O)6)Cl2(H2O)2
  26. Crystal structure of 1,1-biscyclopentadienyl-2,4-bis(trimethylsilyl)-3-(t-butylethynyl)-7-(t-butyl)zirconacyclohepta-2,4,5,6-tetraene, C32H46Si2Zr
  27. Crystal structure of (Z)-2,3-bis(3,4-dimethoxyphenyl)-2-propen-1-ol–benzene(2/1), C22H25O5
  28. Crystal structure of 2,2′-anhydro-5-ethyluridine, C11H14N2O5
  29. Crystal structure of (E)-5-(1-butenyl)-2′-deoxyuridine, C13H18N2O5
  30. Crystal structure of bis(1-aza-bicylo[2.2.2]octane)-dicyano-mercury(II), Hg(C7H13N)2(CN)2
  31. Crystal structure of diaquabis(isothiocyanato)bis(1,3,5,7-tetraazatricyclo[3.3.1.1]decane)nickel(II) tetraaquabis(isothiocyanato)nickel(II) water(1/1/2), (Ni(NCS)2(C6H12N4)2(H2O)2)(Ni(NCS)2(H2O)4)(H2O)2
  32. Crystal structure of trimethyl-dibenzo[b,e]2-azabicyclo[2.2.2]octane-2,3,3-carboxylate, C21H19NO6
  33. Crystal structure of bis(2-nitro-4-trifluoromethyl-benzenesulfonyl)imide sodium salt monohydrate, Na(C6H3NO2CF3SO2)2N(H2O)
  34. Crystal structure of tricarbonyl{5-ethoxycarbonyl-([2.2]metacyclophane)}-anti-chromium, (C19H20O2)Cr(CO)3
  35. Crystal structure of tricarbonyl{5-ethoxycarbonyl-{dispiro-[1,3-dithiane-2,1′-[2.2]metacyclophane-10′,2″[1,3]dithiane]-(B)}}-anti-chromium, (C25H28O2S4)Cr(CO)3
  36. Redetermination of the crystal structure of bis(N-2-hydroxyethylsalicylideneaminato)copper(II), Cu(C9H10NO2)2
  37. Redetermination of the crystal structure of bis(N-phenylsalicylideneaminato)copper(II), Cu(C13H10NO)2
https://doi.org/10.1524/zkri.1995.210.9.665

Articles in the same Issue

  1. The intensity of forbidden reflections of pyrope: Umweganregung or symmetry reduction?
  2. Darstellung und Kristallstruktur von fehlordnungsfreiem Bismuttriiodid
  3. Al2GeO4(OH)2: Rietveld refinement and stereochemical discussion
  4. Crystal structure of bis(N-methyl-3-ethoxysalicylideneaminato)-copper(II)
  5. Molecular structure and intermolecular organization in the crystalline 1:2 complex of Zn(II)-tetra(3-hydroxyphenyl)porphyrin with dimethylsulphoxide
  6. Crystal and molecular structures of three diimine adducts of diphenyltin dichloride
  7. Trigonal planar geometry of silver in bis[acetatotriphenylphosphinesilver(I)] hemihydrate, [CH3CO2Ag · P(C6H5)3]2 · ½ H2O
  8. Crystal structure and molecular packing analysis of 1,5-anhydropentitols and per-O-acetyl derivatives
  9. Crystal structure of oxonium hexachloroplatinate(IV), (H3O)2PtCl6
  10. Crystal structure of titanium(III) borate, TiBO3
  11. Crystal structure of thorium tetrarhenium disilicide, ThRe4Si2
  12. Crystal structure of hafnium(IV) chloride, HfCl4
  13. Crystal structure of indium aluminium ditelluride, InAlTe2
  14. Crystal structure of thallium tetrabromoferrate(III), TlFeBr4
  15. Crystal structure of caesium tetraiodoferrate(III), CsFeI4
  16. Redetermination of the crystal structures of lithium zinc iodide, Li2ZnI4, and sodium zinc chloride, Na2ZnCl4
  17. Crystal structures of oxoselenoantimonates(III) of sodium and rubidium, Na6(Sb12O18)(SbSe3)2(Na1.86Sb0.14)((OH)2.28(H2O)4.02) and Rb6(Sb12O18)(SbSe3)2Sb0.22((OH)0.66(H2O)3.48)
  18. Crystal structure of carbonyl(η5-cyclopentadienyl)[(R)-(+)-iminphos]-iron(II)-hexafluorophosphate, ([(R)-(+)-iminphos] = (+)-diphenyl(2-{[(R)-1-phenylethylimino]methyl}phenyl)-phosphane), C33H29FePNO(PF6)
  19. Crystal structure of bis(tricyclohexylphosphine)gold(I) bis(1,2-dicyanoethylene-1,2-dithiolato)aurate(III),Au(P(C6H11)3)2Au(C2(CN)2S2)2
  20. Crystal structure of catena-bis[μ-(diphenyldithiophospinato)-digold](Au–Au), C12H10AuPS2
  21. Crystal structure of 5-(2,6-dichlorophenyl)-4-ethoxycarbonyl-3-phenyl-δ2-isoxazoline, C18H15Cl2NO3
  22. Crystal structure of N,N,N′,N′-bis(cyclohexylethyl)thiuram disulphide, C9H16NS2
  23. Crystal structure of 3-(2-furyl)acrylic acid, C7H6O3
  24. Crystal structure of 1-trimethylammonium-4-dimethylaminobenzene ozonide, (CH3)2N(C6H4)N(CH3)3O3
  25. Crystal structure of tetraphenylphosphonium hexaaquadichloropraseodym(III) dihydrate, (P(C6H5)4(PrCl2(H2O)6)Cl2(H2O)2
  26. Crystal structure of 1,1-biscyclopentadienyl-2,4-bis(trimethylsilyl)-3-(t-butylethynyl)-7-(t-butyl)zirconacyclohepta-2,4,5,6-tetraene, C32H46Si2Zr
  27. Crystal structure of (Z)-2,3-bis(3,4-dimethoxyphenyl)-2-propen-1-ol–benzene(2/1), C22H25O5
  28. Crystal structure of 2,2′-anhydro-5-ethyluridine, C11H14N2O5
  29. Crystal structure of (E)-5-(1-butenyl)-2′-deoxyuridine, C13H18N2O5
  30. Crystal structure of bis(1-aza-bicylo[2.2.2]octane)-dicyano-mercury(II), Hg(C7H13N)2(CN)2
  31. Crystal structure of diaquabis(isothiocyanato)bis(1,3,5,7-tetraazatricyclo[3.3.1.1]decane)nickel(II) tetraaquabis(isothiocyanato)nickel(II) water(1/1/2), (Ni(NCS)2(C6H12N4)2(H2O)2)(Ni(NCS)2(H2O)4)(H2O)2
  32. Crystal structure of trimethyl-dibenzo[b,e]2-azabicyclo[2.2.2]octane-2,3,3-carboxylate, C21H19NO6
  33. Crystal structure of bis(2-nitro-4-trifluoromethyl-benzenesulfonyl)imide sodium salt monohydrate, Na(C6H3NO2CF3SO2)2N(H2O)
  34. Crystal structure of tricarbonyl{5-ethoxycarbonyl-([2.2]metacyclophane)}-anti-chromium, (C19H20O2)Cr(CO)3
  35. Crystal structure of tricarbonyl{5-ethoxycarbonyl-{dispiro-[1,3-dithiane-2,1′-[2.2]metacyclophane-10′,2″[1,3]dithiane]-(B)}}-anti-chromium, (C25H28O2S4)Cr(CO)3
  36. Redetermination of the crystal structure of bis(N-2-hydroxyethylsalicylideneaminato)copper(II), Cu(C9H10NO2)2
  37. Redetermination of the crystal structure of bis(N-phenylsalicylideneaminato)copper(II), Cu(C13H10NO)2
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