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The crystal structure of tetramethylammonium tetrafluoroborate, (CH3)4NBF4, and the disorder of the BF4− ion

Published/Copyright: July 28, 2010
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Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 202 Issue 1-2

Abstract

Mr = 160.96, tetragonal, P4/nmm, a = 8.231(3), c = 5.889(3) Å, V = 399.0(3) Å3, Z = 2, Dm = 1.344, Dx = 1.340 g cm−3, λ(MoKα) = 0.7107 Å, μ = 1.32 cm−1, F(000) = 168, R = 0.089 for 267 unique reflections with I > 2σ(I). The interaction compound is formed by the tetramethylammonium cation and the tetrafluoroborate anion. The peculiar feature of this crystal structure, at 298 K, is the disordered distribution of the fluoroborate tetrahedra, which has been also confirmed by NMR measurements.

Published Online: 2010-07-28
Published in Print: 1992

Articles in the same Issue

  1. Structure of p-methylbenzene sulfonamide
  2. The crystal structures of two solid phases of 4-cyano-4′-ethyl-biphenyl
  3. Crystal structure of 2-hydroxy-N-methylbenzamide and 2-hydroxy-N-methylthiobenzamide
  4. Crystal structure of mesogenic material – 2-(4′-Undecoxy phenyl)-5-N-hexyl pyrimidine
  5. Crystal structure of lignocaine hydrochloride – platinum complex
  6. Tobermorite, jennite, and cement gel
  7. On the geometry of Co(II)O6 polyhedra in inorganic compounds
  8. The crystal structure of a rare earth bearing leucophanite: (Ca,RE)CaNa2Be2Si4O12(F,O)2
  9. The crystal structure of tetramethylammonium tetrafluoroborate, (CH3)4NBF4, and the disorder of the BF4− ion
  10. The crystal structure of the conformationally constrained peptide Z-(Aib)6-OBut
  11. The crystal structure of SeO2 at 139 and 286 K
  12. Solid phase conformational analysis of a 13-membered heterocycle: 8,13-Dioxo-1,4,7-trioxacyclotridecane (diethylene glycol cyclic adipate)
  13. Crystal structure of calcium ultraphosphate, Ca2P6O17
  14. Crystal structure of 3-(9-anthryl)-6H-benz[de]anthracen-6-one, C31H18O
  15. Crystal structure of 3-(9-anthryl)-7H-benz[de]anthracen-7-one, C31H18O
  16. Crystal structure of 3-(9-anthryl)-1-methoxy-1H-2,3-dihydrobenz[de]anthracene, C32H24O
  17. Crystal structure of 3-(9-anthryl)-1H-2,3-dihydrobenz[de]anthracene, C31H22
  18. Crystal structure of 1-acetoxy-1,3-di-anthrylpropane, C33H26O2
  19. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(2-furancarboxylato)-copper(II), (H2O)(C4H4OCO2)2Cu(ONC5H4C5H4NO)
  20. Crystal structure of bis(aqua)bis(2,2′-bipiperidine)copper(II) bromide, (NH(CH2)4(CH)2(CH2)4NH)2Cu(OH2)2Br2
  21. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(nitrato)-copper(II), (H2O)(NO3)Cu(ONC5H4C5H4NO)
  22. Crystal structure of μ-bromo-bis(bis(2,2′-bipiperidine)copper(II)) perchlorate, ((NH(CH2)4(CH)2(CH2)4NH)2Cu)2Br(ClO4)3
  23. Crystal structure of high temperature thallium lead antimony sulfide, Tl0.333Pb0.333Sb0.333S
  24. Crystal structure of dibromo-bis(tricarbonyl-η-cyclopentadienyl-molybdenum)-tin(II), Br2((CO)3(C5H5)Mo)2Sn
  25. Crystal structure of dipotassium iron thiohypodiphosphate, K2FeP2S6
  26. Crystal structure of copper mercury tetrathiophosphate, CuHgPS4
  27. Crystal structure of o-hydroxybenzeneazo-β-naphthol, C16H12N2O2
  28. Crystal structure of 1,3-diisopropyl-2,4-diisopropylamino-2,4-dithioxo-1,3,2-λ5,4λ5-diazadiphosphetidine, C12H28N4P2S2
  29. Crystal structure of 2,4-bis(p-methoxyphenyl)-2,4-dithioxo-1,3,2-λ5,4λ5-dithiadiphosphetane, C14H14P2S4
  30. Crystal structure refinement of osmium(II) disulfide, OsS2
  31. Crystal structure refinement of osmium(II) ditelluride, OsTe2
  32. Crystal structure of (E)-2,3,6-trimethoxypentafulvene-1-carbonitrile, (CH3O)3(C6H2)(CN)
  33. Crystal structure of cyclo(C-α-methyl-phenylalanine-proline) (S,S)/(R,S) diastereomeric mixture, C15H18N2O2
  34. Crystal structure of N-tert-butyloxycarbonyl-(S)-pipecolyl-α-aminoisobutyric acid, C15H26N2O5
  35. Crystal structure of (S)-pipecolic acid (2R,3R)-tartrate, C10H17NO8
https://doi.org/10.1524/zkri.1992.202.1-2.81

Articles in the same Issue

  1. Structure of p-methylbenzene sulfonamide
  2. The crystal structures of two solid phases of 4-cyano-4′-ethyl-biphenyl
  3. Crystal structure of 2-hydroxy-N-methylbenzamide and 2-hydroxy-N-methylthiobenzamide
  4. Crystal structure of mesogenic material – 2-(4′-Undecoxy phenyl)-5-N-hexyl pyrimidine
  5. Crystal structure of lignocaine hydrochloride – platinum complex
  6. Tobermorite, jennite, and cement gel
  7. On the geometry of Co(II)O6 polyhedra in inorganic compounds
  8. The crystal structure of a rare earth bearing leucophanite: (Ca,RE)CaNa2Be2Si4O12(F,O)2
  9. The crystal structure of tetramethylammonium tetrafluoroborate, (CH3)4NBF4, and the disorder of the BF4− ion
  10. The crystal structure of the conformationally constrained peptide Z-(Aib)6-OBut
  11. The crystal structure of SeO2 at 139 and 286 K
  12. Solid phase conformational analysis of a 13-membered heterocycle: 8,13-Dioxo-1,4,7-trioxacyclotridecane (diethylene glycol cyclic adipate)
  13. Crystal structure of calcium ultraphosphate, Ca2P6O17
  14. Crystal structure of 3-(9-anthryl)-6H-benz[de]anthracen-6-one, C31H18O
  15. Crystal structure of 3-(9-anthryl)-7H-benz[de]anthracen-7-one, C31H18O
  16. Crystal structure of 3-(9-anthryl)-1-methoxy-1H-2,3-dihydrobenz[de]anthracene, C32H24O
  17. Crystal structure of 3-(9-anthryl)-1H-2,3-dihydrobenz[de]anthracene, C31H22
  18. Crystal structure of 1-acetoxy-1,3-di-anthrylpropane, C33H26O2
  19. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(2-furancarboxylato)-copper(II), (H2O)(C4H4OCO2)2Cu(ONC5H4C5H4NO)
  20. Crystal structure of bis(aqua)bis(2,2′-bipiperidine)copper(II) bromide, (NH(CH2)4(CH)2(CH2)4NH)2Cu(OH2)2Br2
  21. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(nitrato)-copper(II), (H2O)(NO3)Cu(ONC5H4C5H4NO)
  22. Crystal structure of μ-bromo-bis(bis(2,2′-bipiperidine)copper(II)) perchlorate, ((NH(CH2)4(CH)2(CH2)4NH)2Cu)2Br(ClO4)3
  23. Crystal structure of high temperature thallium lead antimony sulfide, Tl0.333Pb0.333Sb0.333S
  24. Crystal structure of dibromo-bis(tricarbonyl-η-cyclopentadienyl-molybdenum)-tin(II), Br2((CO)3(C5H5)Mo)2Sn
  25. Crystal structure of dipotassium iron thiohypodiphosphate, K2FeP2S6
  26. Crystal structure of copper mercury tetrathiophosphate, CuHgPS4
  27. Crystal structure of o-hydroxybenzeneazo-β-naphthol, C16H12N2O2
  28. Crystal structure of 1,3-diisopropyl-2,4-diisopropylamino-2,4-dithioxo-1,3,2-λ5,4λ5-diazadiphosphetidine, C12H28N4P2S2
  29. Crystal structure of 2,4-bis(p-methoxyphenyl)-2,4-dithioxo-1,3,2-λ5,4λ5-dithiadiphosphetane, C14H14P2S4
  30. Crystal structure refinement of osmium(II) disulfide, OsS2
  31. Crystal structure refinement of osmium(II) ditelluride, OsTe2
  32. Crystal structure of (E)-2,3,6-trimethoxypentafulvene-1-carbonitrile, (CH3O)3(C6H2)(CN)
  33. Crystal structure of cyclo(C-α-methyl-phenylalanine-proline) (S,S)/(R,S) diastereomeric mixture, C15H18N2O2
  34. Crystal structure of N-tert-butyloxycarbonyl-(S)-pipecolyl-α-aminoisobutyric acid, C15H26N2O5
  35. Crystal structure of (S)-pipecolic acid (2R,3R)-tartrate, C10H17NO8
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