Home Crystal structure of 2-hydroxy-N-methylbenzamide and 2-hydroxy-N-methylthiobenzamide
Article
Licensed
Unlicensed Requires Authentication

Crystal structure of 2-hydroxy-N-methylbenzamide and 2-hydroxy-N-methylthiobenzamide

Published/Copyright: July 28, 2010
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 202 Issue 1-2

Abstract

2-Hydroxy-N-methyl-benzamide, C8H9NO2; monoclinic; P21–C22; a = 4.041(6) Å, b = 17.02(2) Å, c = 5.462(6) Å, β = 92.7(2)°; Z = 2. 2-Hydroxy-N-methylthiobenzamide, C8H9NOS; Pbca-D2h15; a = 8.359(1) Å, b = 10.891(2) Å, c = 17.917(3) Å; Z = 8. The structures were determined by direct methods from single crystal X-ray data; refinements gave Rw = 0.041 and 0.038. The hydrogen bonds of the hydroxyl groups are in both compounds intramoleculare: O–H…O = 2.510(2) Å and O–H…S = 2.936(2) Å; angles at these bridging H atoms are: 161(2)° and 150(3)°. On the contrary the hydrogen bonds from the N atoms (donor atoms) are intermoleculare. The acceptor atoms are in both cases O atoms of hydroxyl groups of neighbouring molecules: N–H…O = 2.976(3) Å and 3.100(3) Å, angles at the H atoms are: 153(5)° and 154(3)°.

Published Online: 2010-07-28
Published in Print: 1992

Articles in the same Issue

  1. Structure of p-methylbenzene sulfonamide
  2. The crystal structures of two solid phases of 4-cyano-4′-ethyl-biphenyl
  3. Crystal structure of 2-hydroxy-N-methylbenzamide and 2-hydroxy-N-methylthiobenzamide
  4. Crystal structure of mesogenic material – 2-(4′-Undecoxy phenyl)-5-N-hexyl pyrimidine
  5. Crystal structure of lignocaine hydrochloride – platinum complex
  6. Tobermorite, jennite, and cement gel
  7. On the geometry of Co(II)O6 polyhedra in inorganic compounds
  8. The crystal structure of a rare earth bearing leucophanite: (Ca,RE)CaNa2Be2Si4O12(F,O)2
  9. The crystal structure of tetramethylammonium tetrafluoroborate, (CH3)4NBF4, and the disorder of the BF4− ion
  10. The crystal structure of the conformationally constrained peptide Z-(Aib)6-OBut
  11. The crystal structure of SeO2 at 139 and 286 K
  12. Solid phase conformational analysis of a 13-membered heterocycle: 8,13-Dioxo-1,4,7-trioxacyclotridecane (diethylene glycol cyclic adipate)
  13. Crystal structure of calcium ultraphosphate, Ca2P6O17
  14. Crystal structure of 3-(9-anthryl)-6H-benz[de]anthracen-6-one, C31H18O
  15. Crystal structure of 3-(9-anthryl)-7H-benz[de]anthracen-7-one, C31H18O
  16. Crystal structure of 3-(9-anthryl)-1-methoxy-1H-2,3-dihydrobenz[de]anthracene, C32H24O
  17. Crystal structure of 3-(9-anthryl)-1H-2,3-dihydrobenz[de]anthracene, C31H22
  18. Crystal structure of 1-acetoxy-1,3-di-anthrylpropane, C33H26O2
  19. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(2-furancarboxylato)-copper(II), (H2O)(C4H4OCO2)2Cu(ONC5H4C5H4NO)
  20. Crystal structure of bis(aqua)bis(2,2′-bipiperidine)copper(II) bromide, (NH(CH2)4(CH)2(CH2)4NH)2Cu(OH2)2Br2
  21. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(nitrato)-copper(II), (H2O)(NO3)Cu(ONC5H4C5H4NO)
  22. Crystal structure of μ-bromo-bis(bis(2,2′-bipiperidine)copper(II)) perchlorate, ((NH(CH2)4(CH)2(CH2)4NH)2Cu)2Br(ClO4)3
  23. Crystal structure of high temperature thallium lead antimony sulfide, Tl0.333Pb0.333Sb0.333S
  24. Crystal structure of dibromo-bis(tricarbonyl-η-cyclopentadienyl-molybdenum)-tin(II), Br2((CO)3(C5H5)Mo)2Sn
  25. Crystal structure of dipotassium iron thiohypodiphosphate, K2FeP2S6
  26. Crystal structure of copper mercury tetrathiophosphate, CuHgPS4
  27. Crystal structure of o-hydroxybenzeneazo-β-naphthol, C16H12N2O2
  28. Crystal structure of 1,3-diisopropyl-2,4-diisopropylamino-2,4-dithioxo-1,3,2-λ5,4λ5-diazadiphosphetidine, C12H28N4P2S2
  29. Crystal structure of 2,4-bis(p-methoxyphenyl)-2,4-dithioxo-1,3,2-λ5,4λ5-dithiadiphosphetane, C14H14P2S4
  30. Crystal structure refinement of osmium(II) disulfide, OsS2
  31. Crystal structure refinement of osmium(II) ditelluride, OsTe2
  32. Crystal structure of (E)-2,3,6-trimethoxypentafulvene-1-carbonitrile, (CH3O)3(C6H2)(CN)
  33. Crystal structure of cyclo(C-α-methyl-phenylalanine-proline) (S,S)/(R,S) diastereomeric mixture, C15H18N2O2
  34. Crystal structure of N-tert-butyloxycarbonyl-(S)-pipecolyl-α-aminoisobutyric acid, C15H26N2O5
  35. Crystal structure of (S)-pipecolic acid (2R,3R)-tartrate, C10H17NO8
https://doi.org/10.1524/zkri.1992.202.1-2.17

Articles in the same Issue

  1. Structure of p-methylbenzene sulfonamide
  2. The crystal structures of two solid phases of 4-cyano-4′-ethyl-biphenyl
  3. Crystal structure of 2-hydroxy-N-methylbenzamide and 2-hydroxy-N-methylthiobenzamide
  4. Crystal structure of mesogenic material – 2-(4′-Undecoxy phenyl)-5-N-hexyl pyrimidine
  5. Crystal structure of lignocaine hydrochloride – platinum complex
  6. Tobermorite, jennite, and cement gel
  7. On the geometry of Co(II)O6 polyhedra in inorganic compounds
  8. The crystal structure of a rare earth bearing leucophanite: (Ca,RE)CaNa2Be2Si4O12(F,O)2
  9. The crystal structure of tetramethylammonium tetrafluoroborate, (CH3)4NBF4, and the disorder of the BF4− ion
  10. The crystal structure of the conformationally constrained peptide Z-(Aib)6-OBut
  11. The crystal structure of SeO2 at 139 and 286 K
  12. Solid phase conformational analysis of a 13-membered heterocycle: 8,13-Dioxo-1,4,7-trioxacyclotridecane (diethylene glycol cyclic adipate)
  13. Crystal structure of calcium ultraphosphate, Ca2P6O17
  14. Crystal structure of 3-(9-anthryl)-6H-benz[de]anthracen-6-one, C31H18O
  15. Crystal structure of 3-(9-anthryl)-7H-benz[de]anthracen-7-one, C31H18O
  16. Crystal structure of 3-(9-anthryl)-1-methoxy-1H-2,3-dihydrobenz[de]anthracene, C32H24O
  17. Crystal structure of 3-(9-anthryl)-1H-2,3-dihydrobenz[de]anthracene, C31H22
  18. Crystal structure of 1-acetoxy-1,3-di-anthrylpropane, C33H26O2
  19. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(2-furancarboxylato)-copper(II), (H2O)(C4H4OCO2)2Cu(ONC5H4C5H4NO)
  20. Crystal structure of bis(aqua)bis(2,2′-bipiperidine)copper(II) bromide, (NH(CH2)4(CH)2(CH2)4NH)2Cu(OH2)2Br2
  21. Crystal structure of aqua-2,2′-bipyridine-N,N′-dioxide-bis(nitrato)-copper(II), (H2O)(NO3)Cu(ONC5H4C5H4NO)
  22. Crystal structure of μ-bromo-bis(bis(2,2′-bipiperidine)copper(II)) perchlorate, ((NH(CH2)4(CH)2(CH2)4NH)2Cu)2Br(ClO4)3
  23. Crystal structure of high temperature thallium lead antimony sulfide, Tl0.333Pb0.333Sb0.333S
  24. Crystal structure of dibromo-bis(tricarbonyl-η-cyclopentadienyl-molybdenum)-tin(II), Br2((CO)3(C5H5)Mo)2Sn
  25. Crystal structure of dipotassium iron thiohypodiphosphate, K2FeP2S6
  26. Crystal structure of copper mercury tetrathiophosphate, CuHgPS4
  27. Crystal structure of o-hydroxybenzeneazo-β-naphthol, C16H12N2O2
  28. Crystal structure of 1,3-diisopropyl-2,4-diisopropylamino-2,4-dithioxo-1,3,2-λ5,4λ5-diazadiphosphetidine, C12H28N4P2S2
  29. Crystal structure of 2,4-bis(p-methoxyphenyl)-2,4-dithioxo-1,3,2-λ5,4λ5-dithiadiphosphetane, C14H14P2S4
  30. Crystal structure refinement of osmium(II) disulfide, OsS2
  31. Crystal structure refinement of osmium(II) ditelluride, OsTe2
  32. Crystal structure of (E)-2,3,6-trimethoxypentafulvene-1-carbonitrile, (CH3O)3(C6H2)(CN)
  33. Crystal structure of cyclo(C-α-methyl-phenylalanine-proline) (S,S)/(R,S) diastereomeric mixture, C15H18N2O2
  34. Crystal structure of N-tert-butyloxycarbonyl-(S)-pipecolyl-α-aminoisobutyric acid, C15H26N2O5
  35. Crystal structure of (S)-pipecolic acid (2R,3R)-tartrate, C10H17NO8
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 29.9.2025 from https://www.degruyterbrill.com/document/doi/10.1524/zkri.1992.202.1-2.17/html
Scroll to top button