Home Structure cristalline et moléculaire du camphosulfonate de l'α-(tétrahydro-4,5,6,7 thiéno (3,2-c) pyridyl-5) (chloro-2 phényl)-acétate de méthyle, C26H32NO6S2Cl. Configuration absolue
Article
Licensed
Unlicensed Requires Authentication

Structure cristalline et moléculaire du camphosulfonate de l'α-(tétrahydro-4,5,6,7 thiéno (3,2-c) pyridyl-5) (chloro-2 phényl)-acétate de méthyle, C26H32NO6S2Cl. Configuration absolue

Published/Copyright: August 25, 2010
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie
From the journal Zeitschrift für Kristallographie Volume 188 Issue 1-2

Abstract

The absolute configuration of the title compound which shows a pharmacologic activity was determined by the Bijvoet difference method. The compound crystallizes in the orthorhombic system, space group P212121, with a = 10.292(2) Å, b = 12.777(2) Å, c = 20.471(2) Å. The final values are R = 0.031 and Rw = 0.032 for 2920 reflections. The results establish that the camphosulfonate, modulus A, has the R configuration and the methyl α-(tetrahydro-4,5,6,7 thieno (3,2-c) pyridin-5-yl)-acetate, modulus B, exhibits the S configuration.

Published Online: 2010-08-25
Published in Print: 1989

Articles in the same Issue

  1. Structure of 2,10-dibromo-3-chloro-7R,8S-epoxychamigrene
  2. Structural determination of a lead-lithium monophosphate, LiPbPO4
  3. Reciprocal lattice scan modes in single crystal diffractometry: a reexamination for cases of mineralogical interest
  4. Experimental charge density in polythionate anions: II. X-ray study of the electron density distribution in potassium tetrathionate, K2S4O6
  5. An uncommon Cu[2+4]O6 coordination polyhedron in the crystal structure of KCu3(OH)2[(AsO4)H(AsO4)] (with a comparison to related structure types)
  6. Some aspects of information theory and phase problem: Effect of heavy atoms on information content in P[unk]
  7. The crystal structure of hexaaquacopper(II) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cuprate(II)
  8. Crystal and molecular structure of an isostere of purine ring system: 7-benzylamino-2-methylmercaptothiazolo [5,4-d] pyrimidine
  9. A novel form of molybdenum (V) phosphate: δ-KMo2P3O13
  10. Structure cristalline et moléculaire du camphosulfonate de l'α-(tétrahydro-4,5,6,7 thiéno (3,2-c) pyridyl-5) (chloro-2 phényl)-acétate de méthyle, C26H32NO6S2Cl. Configuration absolue
  11. Verfeinerung der Kristallstruktur von Holmquistit vom Brandrücken/Weinebene, Koralpe, Österreich
  12. Structural relationships of zeolite frameworks: “5-ring zeolites”
  13. Symmetry restrictions on minimal surfaces related by the Bonnet-transformation
  14. Crystal and molecular structure of N-p-fluorobenzoyl-l-valine
  15. Thermal decay of laser-induced long living metastable electronic states in Na2[Fe(CN)5NO] · 2H2O single crystals
  16. Crystal structures of three substituted ammonium hexachlororhenates(IV)
https://doi.org/10.1524/zkri.1989.188.1-2.85

Articles in the same Issue

  1. Structure of 2,10-dibromo-3-chloro-7R,8S-epoxychamigrene
  2. Structural determination of a lead-lithium monophosphate, LiPbPO4
  3. Reciprocal lattice scan modes in single crystal diffractometry: a reexamination for cases of mineralogical interest
  4. Experimental charge density in polythionate anions: II. X-ray study of the electron density distribution in potassium tetrathionate, K2S4O6
  5. An uncommon Cu[2+4]O6 coordination polyhedron in the crystal structure of KCu3(OH)2[(AsO4)H(AsO4)] (with a comparison to related structure types)
  6. Some aspects of information theory and phase problem: Effect of heavy atoms on information content in P[unk]
  7. The crystal structure of hexaaquacopper(II) bis(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cuprate(II)
  8. Crystal and molecular structure of an isostere of purine ring system: 7-benzylamino-2-methylmercaptothiazolo [5,4-d] pyrimidine
  9. A novel form of molybdenum (V) phosphate: δ-KMo2P3O13
  10. Structure cristalline et moléculaire du camphosulfonate de l'α-(tétrahydro-4,5,6,7 thiéno (3,2-c) pyridyl-5) (chloro-2 phényl)-acétate de méthyle, C26H32NO6S2Cl. Configuration absolue
  11. Verfeinerung der Kristallstruktur von Holmquistit vom Brandrücken/Weinebene, Koralpe, Österreich
  12. Structural relationships of zeolite frameworks: “5-ring zeolites”
  13. Symmetry restrictions on minimal surfaces related by the Bonnet-transformation
  14. Crystal and molecular structure of N-p-fluorobenzoyl-l-valine
  15. Thermal decay of laser-induced long living metastable electronic states in Na2[Fe(CN)5NO] · 2H2O single crystals
  16. Crystal structures of three substituted ammonium hexachlororhenates(IV)
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 5.11.2025 from https://www.degruyterbrill.com/document/doi/10.1524/zkri.1989.188.1-2.85/html?lang=en
Scroll to top button