Home Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
Article
Licensed
Unlicensed Requires Authentication

Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)

Published/Copyright: August 25, 2010
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 175 Issue 1-2

Abstract

Bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II) crystallizes in the monoclinic system, space group P21/n with a = 6.088(3), b = 13.601(2), c = 14.862(3) Å, α = 90.3(2)° and Z = 2. The intensity data were collected using a CAD-4 diffractometer with MoKα radiation. The structure was determined by Patterson and Fourier methods (R = 0.061 for 1100 MoKα reflections). An interesting result of this structure determination is the confirmation of the square planar coordination of the nickel(II) ion in this complex. The Ni – O and Ni – N bond lengths have values 1.84(1) and 1.93(1) Å, respectively. The two aromatic rings are planar and the angle between these planes is 64.1(3)°.

Published Online: 2010-8-25
Published in Print: 1986-1-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

Articles in the same Issue

  1. New family of silicate phases with the pollucite structure
  2. The crystal structure of cis-3-hydroxy-4a,9,10,10a-tetrahydro-1,4a-ethanophenanthren-2(1H)-one (2-one phenanthrene)
  3. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets
  4. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on double-bifurcated chains and the 4.82 and 4.6.12 3-connected plane nets
  5. Formation of the high temperature phase in vacuum deposited SnSe thin films
  6. Correlation of angular and bond length distortions in TO4 units in crystals
  7. Die Kristallstrukturen von drei Modifikationen des Cu(SeO3)
  8. Crystal structures of N-parabromobenzoyl-α-aminoisobutyric acid and two derivatives
  9. Crystal and molecular structures of N2-dimethylthiosalicylohydrazide, (C6H4)CSNHOHN(CH3)2
  10. Studies on clathrasils. IX*
  11. Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3
  12. Crystal structure of barium nitrite, Ba(NO2)2
  13. Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
  14. Structure of a high-pressure phase Ba9Ge23O53(OH)4
  15. The molecular structure of trans 3,6-dimethyl-6-phenyltetrahydro-2-pyrone in the crystal
  16. Crystal structure of W-type SrZn2Fe16O27, a refinement
  17. Structure of thallium(I) dideuteriumphosphate, TlD2PO4
  18. Crystal structure of bis(3,5-dimethyl-l-guanyl pyrazole) copper(II) nitrate
  19. Crystal growth and physical properties of monoclinic betaine fluoroborate monohydrate, (CH3)3NCH2COO HBF4 · H2O
https://doi.org/10.1524/zkri.1986.175.1-2.117

Articles in the same Issue

  1. New family of silicate phases with the pollucite structure
  2. The crystal structure of cis-3-hydroxy-4a,9,10,10a-tetrahydro-1,4a-ethanophenanthren-2(1H)-one (2-one phenanthrene)
  3. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets
  4. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on double-bifurcated chains and the 4.82 and 4.6.12 3-connected plane nets
  5. Formation of the high temperature phase in vacuum deposited SnSe thin films
  6. Correlation of angular and bond length distortions in TO4 units in crystals
  7. Die Kristallstrukturen von drei Modifikationen des Cu(SeO3)
  8. Crystal structures of N-parabromobenzoyl-α-aminoisobutyric acid and two derivatives
  9. Crystal and molecular structures of N2-dimethylthiosalicylohydrazide, (C6H4)CSNHOHN(CH3)2
  10. Studies on clathrasils. IX*
  11. Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3
  12. Crystal structure of barium nitrite, Ba(NO2)2
  13. Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
  14. Structure of a high-pressure phase Ba9Ge23O53(OH)4
  15. The molecular structure of trans 3,6-dimethyl-6-phenyltetrahydro-2-pyrone in the crystal
  16. Crystal structure of W-type SrZn2Fe16O27, a refinement
  17. Structure of thallium(I) dideuteriumphosphate, TlD2PO4
  18. Crystal structure of bis(3,5-dimethyl-l-guanyl pyrazole) copper(II) nitrate
  19. Crystal growth and physical properties of monoclinic betaine fluoroborate monohydrate, (CH3)3NCH2COO HBF4 · H2O
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 5.11.2025 from https://www.degruyterbrill.com/document/doi/10.1524/zkri.1986.175.1-2.117/html
Scroll to top button