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Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3

Published/Copyright: August 25, 2010
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 175 Issue 1-2

Abstract

Tetraethylammonium calcium triazide is formed by the reaction of tetraethylammonium azide with calcium azide in aqueous solution. The crystals are monoclinic, a = 7.154(2), b = 7.112(2), c = 7.154(2) Å, β = 96.05(1)°, space group P2/m, Z = 1. Additional weak reflections on highly exposed X-ray films point to the existence of a superlattice with each cell length six times the original value (Z = 216). The crystal structure for the simple monoclinic cell was investigated by X-ray methods, R = 0.051. Calcium is octahedrally coordinated to six azide groups, the structure corresponds to a monoclinic distorted perovskite. The tetraethylammonium groups could not be completely localized, and they were approximated by a model consisting of several partially occupied lattice positions.

Published Online: 2010-8-25
Published in Print: 1986-1-1

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Articles in the same Issue

  1. New family of silicate phases with the pollucite structure
  2. The crystal structure of cis-3-hydroxy-4a,9,10,10a-tetrahydro-1,4a-ethanophenanthren-2(1H)-one (2-one phenanthrene)
  3. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets
  4. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on double-bifurcated chains and the 4.82 and 4.6.12 3-connected plane nets
  5. Formation of the high temperature phase in vacuum deposited SnSe thin films
  6. Correlation of angular and bond length distortions in TO4 units in crystals
  7. Die Kristallstrukturen von drei Modifikationen des Cu(SeO3)
  8. Crystal structures of N-parabromobenzoyl-α-aminoisobutyric acid and two derivatives
  9. Crystal and molecular structures of N2-dimethylthiosalicylohydrazide, (C6H4)CSNHOHN(CH3)2
  10. Studies on clathrasils. IX*
  11. Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3
  12. Crystal structure of barium nitrite, Ba(NO2)2
  13. Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
  14. Structure of a high-pressure phase Ba9Ge23O53(OH)4
  15. The molecular structure of trans 3,6-dimethyl-6-phenyltetrahydro-2-pyrone in the crystal
  16. Crystal structure of W-type SrZn2Fe16O27, a refinement
  17. Structure of thallium(I) dideuteriumphosphate, TlD2PO4
  18. Crystal structure of bis(3,5-dimethyl-l-guanyl pyrazole) copper(II) nitrate
  19. Crystal growth and physical properties of monoclinic betaine fluoroborate monohydrate, (CH3)3NCH2COO HBF4 · H2O
https://doi.org/10.1524/zkri.1986.175.1-2.105

Articles in the same Issue

  1. New family of silicate phases with the pollucite structure
  2. The crystal structure of cis-3-hydroxy-4a,9,10,10a-tetrahydro-1,4a-ethanophenanthren-2(1H)-one (2-one phenanthrene)
  3. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on insertion of 2-connected vertices into 3-connected plane nets
  4. Enumeration of 4-connected 3-dimensional nets and classification of framework silicates. 3D nets based on double-bifurcated chains and the 4.82 and 4.6.12 3-connected plane nets
  5. Formation of the high temperature phase in vacuum deposited SnSe thin films
  6. Correlation of angular and bond length distortions in TO4 units in crystals
  7. Die Kristallstrukturen von drei Modifikationen des Cu(SeO3)
  8. Crystal structures of N-parabromobenzoyl-α-aminoisobutyric acid and two derivatives
  9. Crystal and molecular structures of N2-dimethylthiosalicylohydrazide, (C6H4)CSNHOHN(CH3)2
  10. Studies on clathrasils. IX*
  11. Preparation and structure determination of tetraethylammonium calcium azide, [N(C2H5)4]Ca(N3)3
  12. Crystal structure of barium nitrite, Ba(NO2)2
  13. Crystal structure of bis(N-2-phenyl-ethyl salicylideneiminato)nickel(II)
  14. Structure of a high-pressure phase Ba9Ge23O53(OH)4
  15. The molecular structure of trans 3,6-dimethyl-6-phenyltetrahydro-2-pyrone in the crystal
  16. Crystal structure of W-type SrZn2Fe16O27, a refinement
  17. Structure of thallium(I) dideuteriumphosphate, TlD2PO4
  18. Crystal structure of bis(3,5-dimethyl-l-guanyl pyrazole) copper(II) nitrate
  19. Crystal growth and physical properties of monoclinic betaine fluoroborate monohydrate, (CH3)3NCH2COO HBF4 · H2O
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