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Die Kristallstrukturen von KCd(N3)3 · H2O und K2Cd(N3)4
Veröffentlicht/Copyright:
25. August 2010
Abstract
KCd(N3)3 · H2O crystallizes in space group Pnma with a = 11.991(2), b = 3.712(1), c = 17.292(2) Å and Z = 4. K2Cd(N3)4 crystallizes in space group C2/m with a = 14.272(2), b = 3.787(1), c = 8.887(2), β = 92.83(2)° and Z = 2.
The structures have been determined from single crystal X-ray data. The final R-values are 0.074 and 0.063 respectively.
In both structures cadmium is surrounded octahedrally by six azide groups; the Cd(N3)6-octahedra share edges. Potassium is coordinated by seven azide groups and two water molecules in KCd(N3)3 · H2O and by eight azide groups in K2Cd(N3)4. In both structures all azide groups are approximately parallel, with mean N – N = 1.17(5) Å.
Published Online: 2010-08-25
Published in Print: 1982
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- The crystal structure of 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose1
- The crystal structure of 1,2,3,4,6-penta-O-acetyl-β-d-glucopyranose1
- The crystal structure of 2-(2′,5′-dinitrophenoxy)-tetrahydropyran1
- The calculation of the electrostatic lattice energy of polar crystals by slice-wise summation, with an application to BeO
- Intermediates in thermal decomposition of nickel(II) complexes: The crystal structures of Ni(SCN)2(NH3)2 and Ni(SCN)2
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- Crystal structure of synthetic K2Mg(CO3)2
- Temperature dependence of electrogyration in alums
- Der lineare elektrooptische Effekt von α-Quarz: eine Neubestimmung
- Elektrooptische und elektrostriktive Eigenschaften der trigonalen Tartrate Rb2(d-C4H4O6) und Cs2(d-C4H4O6)
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Artikel in diesem Heft
- The crystal structure of simonite, TlHgAs3S6
- The distribution of Fe3+ and Ga3+ between octahedral and tetrahedral sites in garnets, Y3(Fe,Ga)5O12, at different temperaturesa
- The slipping scheme of the double crankshaft structures in tectosilicates and its mineralogical implication
- A new method for determining the lattice parameters from powder patterns of orthorhombic crystals
- Cation distributions in (Fe1 – zMez)3(PO4)2 graftonite-type solid solutions determined by Mössbauer spectroscopy
- Die Kristallstruktur von Tl8Cd3(N3)14
- The crystal structure of 6-bromo-2-cyano-4′-diethylamino-4-nitro-6′-propionamidoazobenzene
- The crystal structure of 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose1
- The crystal structure of 1,2,3,4,6-penta-O-acetyl-β-d-glucopyranose1
- The crystal structure of 2-(2′,5′-dinitrophenoxy)-tetrahydropyran1
- The calculation of the electrostatic lattice energy of polar crystals by slice-wise summation, with an application to BeO
- Intermediates in thermal decomposition of nickel(II) complexes: The crystal structures of Ni(SCN)2(NH3)2 and Ni(SCN)2
- An application of strengthened translation functions: The crystal structure of 2-methyl-3-phenyl-4,4-dicyanomethylbutanoate, C14H14N2O2
- Crystal structure of synthetic K2Mg(CO3)2
- Temperature dependence of electrogyration in alums
- Der lineare elektrooptische Effekt von α-Quarz: eine Neubestimmung
- Elektrooptische und elektrostriktive Eigenschaften der trigonalen Tartrate Rb2(d-C4H4O6) und Cs2(d-C4H4O6)
- Die Kristallstrukturen von KCd(N3)3 · H2O und K2Cd(N3)4
