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Destruction of 1,1-dichloroethylene/air mixture under gamma-ray irradiation
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Y.-X. Sun
Veröffentlicht/Copyright:
25. September 2009
Summary
Radiation-induced decomposition of 1,1-dichloroethylene(1,1-DCE)) in air was investigated in the experiment. The model gas prepared by mixing 1,1-dichloroethylene vapor with air was sealed in batch reactors and subjected to gamma irradiation. Inorganic products (CO+CO2) and organic products were analyzed by means of a TOC analyzer and gas-chromatography, respectively. It was found that chloroacetyl chloride (CH2ClCOCl) was present as the main organic product while inorganic products (CO+CO2) occurred in quantities below 10 based on relative carbon balance. Energy consumption of 1,1-DCE by using gamma-ray irradiation was compared with that by using electron beam irradiation.
Published Online: 2009-9-25
Published in Print: 2003-5-1
© 2003 Oldenbourg Wissenschaftsverlag GmbH
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Artikel in diesem Heft
- Preparation of 1-(2-pyridylazo)-2-naphthol functionalized benzophenone/naphthalene and their uses in solid phase extractive preconcentration/separation of uranium(VI)
- Solubility of crystalline thorium dioxide
- Tc(IV) chemistry in mixed chloride/sulphate acidic media. Formation of polyoxopolymetallic species
- The substitution reactions of [Tc(tu)6]3+ with CyDTA and citrate
- Investigation of chemical equilibrium kinetics by the electromigration method
- Equilibrium constants in aqueous lanthanide and actinide chemistry from time-resolved fluorescence spectroscopy: The role of ground and excited state reactions
- Destruction of 1,1-dichloroethylene/air mixture under gamma-ray irradiation
- Additivity rule and its application to the sorption of radionuclides on soils
- Globule formation of a clay mineral and a rapid method for the treatment of liquid radioactive waste
