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Sorption study of strontium onto hydrated cement phases using a sequential desorption method

  • T. Iwaida , S. Nagasaki und S. Tanaka
Veröffentlicht/Copyright: 25. September 2009

We studied the sorption behavior of Sr onto calcium-silicate-hydrates (C-S-H), calcium-aluminate-hydrates ettringite (AFt), monosulphate (AFm), and hydrogarnet (C3AH6) by applying a sequential desorption method. The results showed that:

- The distribution coefficients (Kd) of Sr sorption onto C-S-H increased with decreasing Ca/Si ratios of C-S-H. This Kd change is explained with the zeta potentials of C-S-H at various Ca/Si ratios and with the change of surface functional group,

- Sr is sorbed on C-S-H through plural sorption forms. The observation that some Sr is desorbed by EDTA and nitric acid suggests that a replacement of Ca with Sr takes place in the C-S-H structure, and

- Sr is structurally incorporated into AFt, AFm, and C3AH6.

Published Online: 2009-9-25
Published in Print: 2000-8-1

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