Startseite Surfactants in action: chemistry, behavior, and industrial applications
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Surfactants in action: chemistry, behavior, and industrial applications

  • Bharti Budhalakoti EMAIL logo , Pooja Sharma ORCID logo und Navin Chandra Kothiyal
Veröffentlicht/Copyright: 25. Juli 2025

Abstract

Surfactants, or surface-active agents, are multifunctional amphiphilic compounds essential across numerous industrial and domestic applications. This review provides an in-depth analysis of surfactant chemistry, focusing on their diverse structures, interfacial behaviors, and self-assembly mechanisms, including micelle formation and emulsification. It outlines the classification of surfactants – anionic, cationic, non-ionic, and zwitterionic – while also exploring innovative types such as biosurfactants, sugar-based, lignin-derived, algal-based, and gemini surfactants. The growing emphasis on environmentally friendly and biodegradable surfactants sourced from renewable materials is highlighted, reflecting a shift away from conventional petroleum-derived options. The review examines key properties like surface tension reduction, wettability enhancement, foaming, detergency, and emulsification, linking them to their wide-ranging applications in sectors such as petrochemicals, pharmaceuticals, nanotechnology, paper manufacturing, and biotechnology. Finally, it underscores the crucial role of surfactants in fostering sustainable advancements and their potential for driving future technological innovations.


Corresponding author: Bharti Budhalakoti, Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar, 144 011, Punjab, India; and Hermann Gmeiner Degree College, Bhimtal, 263136, Uttarakhand, India, E-mail:

Acknowledgement

The authors express their gratitude to the Director and Head of the Department of Chemistry at Dr. B.R. Ambedkar National Institute of Technology for necessary laboratory facilities.

  1. Research ethics: Not applicable.

  2. Informed consent: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

  3. Author contributions: All authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors declare the following financial interests/personal relationships which may be considered as potential competing interests.

  6. Research funding: None declared.

  7. Data availability: Not applicable.

References

1. Rosen, M. J.; Kunjappu, J. T. Surfactants and Interfacial Phenomena. In Surfactants and Interfacial Phenomena, 4th ed.; Wiley: New Jersey, 2012.10.1002/9781118228920Suche in Google Scholar

2. Free, M. L. The Use of Surfactants to Enhance Particle Removal from Surfaces. In Developments in Surface Contamination and Cleaning, 2nd ed; William Andrew: New York, 2016.10.1016/B978-0-323-29960-2.00013-7Suche in Google Scholar

3. Nikam, B. K.; Jadhav, V. B.; Borse, M. S. Influence of Alcohols on the Lower Consolute Behavior and Thermodynamic Approach of Triton X-114 Aqueous Two-phase Systems. J. Indian Chem. Soc. 2022, 99 (8), 100572; https://doi.org/10.1016/j.jics.2022.100572.Suche in Google Scholar

4. Vakh, C.; Koronkiewicz, S. Surfactants Application in Sample Preparation Techniques: Insights, Trends, and Perspectives. Trac. Trends Anal. Chem. 2023, 165, 117143; https://doi.org/10.1016/j.trac.2023.117143.Suche in Google Scholar

5. Kulkarni, V. S.; Shaw, C. Surfactants, Lipids, and Surface Chemistry. In Essential Chemistry for Formulators of Semisolid and Liquid Dosages; Elsevier: Netherlands, 2016.10.1016/B978-0-12-801024-2.05001-9Suche in Google Scholar

6. Badmus, S. O.; Amusa, H. K.; Oyehan, T. A.; Saleh, T. A. Environmental Risks and Toxicity of Surfactants: Overview of Analysis, Assessment, and Remediation Techniques. Environ. Sci. Pollut. Res. 2021, 28 (44), 62085–62104; https://doi.org/10.1007/s11356-021-16483-w.Suche in Google Scholar PubMed PubMed Central

7. Fernández Cirelli, A.; Ojeda, C.; Castro, M. J. L.; Salgot, M. Surfactants in Sludge-Amended Agricultural Soils: A Review. Environ. Chem. Lett. 2008, 12 (1), 85–95; https://doi.org/10.1007/s10311-013-0432-4.Suche in Google Scholar

8. Bhatt, J.; Rai, A. K.; Gupta, M.; Vyas, S.; Ameta, R.; Ameta, S. C Surfactants: an Emerging Face of Pollution. In Micropollutants and Challenges: Emerging in the Aquatic Environments and Treatment Processes; Elsevier: Netherlands, 2020.10.1016/B978-0-12-818612-1.00004-0Suche in Google Scholar

9. Kowalska, I. Usuwanie Anionowych Substancji Powierzchniowo Czynnych W Procesie Wymiany Jonowej. Ochr środowiska 2009, 31 (1), 25–29.Suche in Google Scholar

10. Nollet, L. M. L. Chromatographic Analysis of the Environment; CRC Press: USA, 2005.10.1201/9781420027983Suche in Google Scholar

11. Kumar, S.; Kumar, A.; Gautam, S.; Verma, A. Emulsification of Indian Heavy Crude Oil and Analysis of Flow Characteristics Using Computational Fluid Dynamics (CFD) for Pipeline Transportation. J. Dispers Sci. Technol. 2024, 45 (11), 2166–2179; https://doi.org/10.1080/01932691.2023.2256384.Suche in Google Scholar

12. Stamatelatou, K.; Pakou, C.; Lyberatos, G. Occurrence, Toxicity, and Biodegradation of Selected Emerging Priority Pollutants in Municipal Sewage Sludge. In Comprehensive Biotechnology, 2nd ed; Pergamon Press: UK, 2011.10.1016/B978-0-08-088504-9.00496-7Suche in Google Scholar

13. Smith, G. A.; Huggett, A.; Jones, C.; Ortego, G. Surface Activity and Performance Properties of Gemini Salts of Linear Alkylbenzene Sulfonate in Aqueous Solution. J. Surfactants Deterg. 2021, 24 (4), 563–574; https://doi.org/10.1002/jsde.12496.Suche in Google Scholar

14. Shen, C. Y. Properties of Detergent Phosphates and Their Effects on Detergent Processing. J. Am. Oil Chem. Soc. 1968, 45 (7), 510–516; https://doi.org/10.1007/bf02541337.Suche in Google Scholar

15. Broecker, J.; Keller, S. Impact of Urea on Detergent Micelle Properties. Langmuir 2013, 29 (27), 8502–8510; https://doi.org/10.1021/la4013747.Suche in Google Scholar PubMed

16. Khachane, P.; Date, A. A.; Nagarsenker, M. S. Positively Charged Polymeric Nanoparticles: Application in Improving Therapeutic Efficacy of Meloxicam after Oral Administration. Pharmazie 2011, 66 (5), 334–338.Suche in Google Scholar

17. Bartelds, R.; Nematollahi, M. H.; Pols, T.; Stuart, M. C. A.; Pardakhty, A.; Asadikaram, G.; Poolman, B. Niosomes, an Alternative for Liposomal Delivery. PLoS One 2018, 13 (4), e0194179; https://doi.org/10.1371/journal.pone.0194179.Suche in Google Scholar PubMed PubMed Central

18. Hari, A.; Doddapaneni, T. R. K. C.; Kikas, T. Common Operational Issues and Possible Solutions for Sustainable Biosurfactant Production from Lignocellulosic Feedstock. Environ. Res. 2024, 251, 118665; https://doi.org/10.1016/j.envres.2024.118665.Suche in Google Scholar PubMed

19. Jimoh, A. A.; Lin, J. Biosurfactant: A New Frontier for Greener Technology and Environmental Sustainability. Ecotoxicol. Environ. Saf. 2019, 184, 109607; https://doi.org/10.1016/j.ecoenv.2019.109607.Suche in Google Scholar PubMed

20. Ruiz, C. C. Sugar-based Surfactants: Fundamentals and Applications. In Sugar-Based Surfactants: Fundamentals and Applications; CVC Press: Boca Raton, 2008.10.1201/9781420051674Suche in Google Scholar

21. Jiao, Y.; Xu, Z.; Qiao, W.; Li, Z. Research Interfacial Properties of the Novel Lignosulfonates. Energy Sources, Part A Recovery, Util. Environ. Eff. 2007, 29 (15), 1425–1432; https://doi.org/10.1080/00908310600710699.Suche in Google Scholar

22. Abdalla, K. M. I. The Application of a New Polymeric Surfactant for Chemical EOR. In Introduction to Enhanced Oil Recovery (EOR) Processes and Bioremediation of Oil-Contaminated Sites; Intech: Crotia, 2012.10.5772/47975Suche in Google Scholar

23. Fioroni, G.; Katahira, R.; Van Wychen, S.; Rowland, S. M.; Christensen, E. D.; Dong, T.; Pienkos, P. T.; Laurens, L. M. L. Synthesis of Hydrophilic Derivative Surfactants from Algae-Derived Unsaponifiable Lipids. Front. Chem. Eng. 2021, 3, 768382; https://doi.org/10.3389/fceng.2021.768382.Suche in Google Scholar

24. Kamal, M. S. A Review of Gemini Surfactants: Potential Application in Enhanced Oil Recovery. J. Surfactants Deterg. 2016, 19 (2), 223–236; https://doi.org/10.1007/s11743-015-1776-5.Suche in Google Scholar

25. Rosen, M. J. The Relationship of Structure to Properties in Surfactants. J. Am. Oil Chem. Soc. 1972, 49 (5), 293–297; https://doi.org/10.1007/bf02637577.Suche in Google Scholar

26. Ghosh, S.; Ray, A.; Pramanik, N. Self-assembly of Surfactants: An Overview on General Aspects of Amphiphiles. Biophys. Chem. 2020, 265, 106429; https://doi.org/10.1016/j.bpc.2020.106429.Suche in Google Scholar PubMed

27. van Oss, C. J.; Israelachvili, J. N. A Review of Intermolecular and Surface Forces, 2nd ed.; Academic Press: London, 1991. xxi + 450; hardbound, $49.95. J Dispers Sci Technol. 1992, 13 (1), 1–704. 10.1080/01932699208943350Suche in Google Scholar

28. Perinelli, D. R.; Cespi, M.; Lorusso, N.; Palmieri, G. F.; Bonacucina, G.; Blasi, P. Surfactant Self-Assembling and Critical Micelle Concentration: One Approach Fits All? Langmuir 2020, 36 (21), 5745–5753; https://doi.org/10.1021/acs.langmuir.0c00420.Suche in Google Scholar PubMed PubMed Central

29. Kolbeck, C.; Lehmann, J.; Lovelock, K. R. J.; Cremer, T.; Paape, N.; Wasserscheid, P.; Fröba, A. P.; Maier, F.; Steinrück, H. P. Density and Surface Tension of Ionic Liquids. J. Phys. Chem. B 2010, 114 (51), 17025–17036; https://doi.org/10.1021/jp1068413.Suche in Google Scholar PubMed

30. Saxena, K.; Chen, Y. Effect Of Surfactants On Surface Wettability Via Measurement Of Droplet Contact Angle And Interfacial Tension. In ASME International Mechanical Engineering Congress and Exposition, Proceedings (IMECE); ASME: USA, 2023.10.1115/IMECE2023-112217Suche in Google Scholar

31. Chaudhari, S. P.; Dugar, R. P. Application of Surfactants in Solid Dispersion Technology for Improving Solubility of Poorly Water Soluble Drugs. J. Drug Delivery Sci. Technol. 2017, 41, 68–77; https://doi.org/10.1016/j.jddst.2017.06.010.Suche in Google Scholar

32. Rosen, M. J. Surfactants and Interfacial Phenomena, 2nd ed.; Wiley: New York, 1989; pp. 39–55.Suche in Google Scholar

33. Poce-Fatou, J. A. A Superficial Overview of Detergency. J. Chem. Educ. 2006, 8, 1147; https://doi.org/10.1021/ed083p1147.Suche in Google Scholar

34. Wang, T.; Chang, D.; Huang, D.; Liu, Z.; Wu, Y.; Liu, H.; Yuan, H.; Jiang, Y. Application of Surfactants in Papermaking Industry and Future Development Trend of Green Surfactants. Appl. Microbiol. Biotechnol. 2021, 105 (20), 7619–7634; https://doi.org/10.1007/s00253-021-11602-6.Suche in Google Scholar PubMed

35. Bhardwaj, A.; Hartland, S. Applications of Surfactants in Petroleum Industry. J. Dispers Sci Technol. 1993, 14 (1), 87–116.10.1080/01932699308943389Suche in Google Scholar

36. Singh, A.; Van Hamme, J. D.; Ward, O. P. Surfactants in Microbiology and Biotechnology: Part 2. Application Aspects. Biotechnol. Adv. 2007, 26 (1), 99–121; https://doi.org/10.1016/j.biotechadv.2006.10.004.Suche in Google Scholar PubMed

37. Ziyatdinova, G. K.; Ziganshina, E. R.; Budnikov, H. C. Application of Surfactants in Voltammetric Analysis. J. Anal. Chem. 2012, 67 (11), 869–879; https://doi.org/10.1134/s106193481211010x.Suche in Google Scholar

38. Beneventi, D.; Allix, J.; Zeno, E.; Nortier, P.; Carré, B. Simulation of Surfactant Contribution to Ink Removal Selectivity in Flotation Deinking Lines. Sep Purif Technol. 2009, 64 (3), 357–367.10.1016/j.seppur.2008.10.033Suche in Google Scholar

39. Pranav, H.; Nakhate, P. A. Optimisation of Rhamnolipid: A New Age Biosurfactant from Pseudomonas aeruginosa MTCC 1688 and its Application in Oil Recovery, Heavy and Toxic Metals Recovery. J. Bioprocess. Biotech. 2015, 5 (5), 1; https://doi.org/10.4172/2155-9821.1000229.Suche in Google Scholar

40. Pouton, C. W. Formulation of Poorly Water-Soluble Drugs for Oral Administration: Physicochemical and Physiological Issues and the Lipid Formulation Classification System. Eur. J. Pharm. Sci. 2006, 29 (3–4), 278–287; https://doi.org/10.1016/j.ejps.2006.04.016.Suche in Google Scholar PubMed

41. Sjökvist, E.; Nyström, C.; Aldén, M.; Caram-Lelham, N. Physicochemical Aspects of Drug Release. XIV. The Effects of Some Ionic and Non-ionic Surfactants on Properties of a Sparingly Soluble Drug in Solid Dispersions. Int. J. Pharm. 1992, 79 (1–3), 123–133.10.1016/0378-5173(92)90103-9Suche in Google Scholar

42. Banat, I. M.; Makkar, R. S.; Cameotra, S. S. Potential Commercial Applications of Microbial Surfactants. Appl. Microbiol. Biotechnol. 2000, 53 (5), 495–508; https://doi.org/10.1007/s002530051648.Suche in Google Scholar PubMed

43. Moosavi-Movahedi, A. A.; Semsarha, F.; Heli, H.; Nazari, K.; Ghourchian, H.; Hong, J.; Hakimelahi, G.; Saboury, A.; Sefidbakht, Y. Micellar Histidinate Hematin Complex as an Artificial Peroxidase Enzyme Model: Voltammetric and Spectroscopic Investigations. Colloids Surf. A Physicochem. Eng. Asp. 2008, 320 (1–3), 213–221; https://doi.org/10.1016/j.colsurfa.2008.01.047.Suche in Google Scholar

44. Satpati, A. K.; Sahoo, S.; Ravindran, P. V.; Venkateswaran, G. Stripping Voltammetric Determination of Uranium Traces in Sea Water Samples: Effect of Surfactants on the Measurements. Anal. Lett. 2010, 43 (4), 644–657; https://doi.org/10.1080/00032710903406904.Suche in Google Scholar

45. Schreiber, E.; Ziener, U.; Manzke, A.; Plettl, A.; Ziemann, P.; Landfester, K. Preparation of Narrowly Size Distributed Metal-Containing Polymer Latexes by Miniemulsion and Other Emulsion Techniques: Applications for Nanolithography. Chem. Mater. 2009, 21 (8), 1750–1760; https://doi.org/10.1021/cm802796y.Suche in Google Scholar

46. Hudson, L. K.; Eastoe, J.; Dowding, P. J. Nanotechnology in Action: Overbased Nanodetergents as Lubricant Oil Additives. Adv. Colloid Interface Sci. 2006, 123, 425–431; https://doi.org/10.1016/j.cis.2006.05.003.Suche in Google Scholar PubMed

Received: 2025-07-04
Accepted: 2025-07-09
Published Online: 2025-07-25
Published in Print: 2025-10-27

© 2025 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/zpch-2025-0095/html?lang=de
Button zum nach oben scrollen