Startseite Experimental investigation of structural, morphological, and optical characteristics of SrTiO3 nanoparticles using a shock tube for photocatalytic applications
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Experimental investigation of structural, morphological, and optical characteristics of SrTiO3 nanoparticles using a shock tube for photocatalytic applications

  • Surendhar Sakthivel , Sivaprakash Paramasivam , Periyasamy Velusamy , Joseph Anthony Doss Jerries Infanta , Venkatesan Ragavendran , Jeyanthinath Mayandi , Sonachalam Arumugam EMAIL logo und Ikhyun Kim EMAIL logo
Veröffentlicht/Copyright: 9. Februar 2024

Abstract

We investigated the role of dynamic shock waves in perovskite SrTiO3 (STO) material. XRD, FE-SEM, EDAX, FTIR, UV-DRS, XPS, and Raman spectroscopy were all used to examine the title material. When perovskite sample was loaded with shocks, its diffraction pattern did not show any crystal structure changes. The FE-SEM results suggest that the grain size increased linearly with the number of shocks. We used energy-dispersive X-ray spectroscopy to perform elemental analysis; results confirmed that SrTiO3 NPs were indeed present. Although the impulse of the shock wave changed the optical characteristics, it did not affect the molecular structure. To find the optical band gap energies of untreated and shocked NPs, Tauc plot relationships were used. The band-gap energies got smaller as the shock pulse became more substantial. The impact of shock waves caused oxygen vacancies and surface defects, lowering band gap energy. The test for photocatalytic testing showed that SrTiO3 NPs that are loaded with shock waves worked much better when they were exposed to visible light. The characteristics, including stress, strain, and bond length, were found to significantly influence photocatalytic applications. In addition, attempts were made to provide a viewpoint for future study. Overall, the objective of this research was to provide valuable insights for experts engaged in the field of SrTiO3.


Corresponding author: Sonachalam Arumugam, Centre for High Pressure Research, School of Physics, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu, India; and Tamil Nadu Open University, Chennai, 600015, India, E-mail: ; and Ikhyun Kim, Department of Mechanical Engineering, Keimyung University, Daegu 42601, South Korea, E-mail:

Funding source: National Research Foundation of Korea (NRF) grant funded by the Korea government (MIST)

Award Identifier / Grant number: (No. 2022R1C1C1006414)

Acknowledgments

S. A. wishes to thank UGC-DAE-CSR (Indore), DST (MES and SERB), MHRD-RUSA, TANSCHE (Chennai) and BRNS (Mumbai), Indo-Poland for financial support.

  1. Research ethics: Not applicable.

  2. Author contributions: The author(s) have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The author(s) state(s) no conflict of interest.

  4. Research funding: The research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MIST) (No. 2022R1C1C1006414).

  5. Data availability: Not applicable.

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Received: 2023-11-20
Accepted: 2024-01-10
Published Online: 2024-02-09
Published in Print: 2024-10-28

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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