Startseite Naturwissenschaften Spectroscopic characterization of biosynthesized lead oxide (PbO) nanoparticles and their applications in PVC/graphite-PbO nanocomposites
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Spectroscopic characterization of biosynthesized lead oxide (PbO) nanoparticles and their applications in PVC/graphite-PbO nanocomposites

  • Junaid Raza , Abdul Hamid , Muhammad Khan EMAIL logo , Fakhar Hussain , Li Tiehu , Perveen Fazil , Amir Zada EMAIL logo , Zainul Wahab und Amjad Ali
Veröffentlicht/Copyright: 8. März 2022
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 236 Heft 5

Abstract

Extract of Hibiscus rosa-sinensis plants was used for the green synthesis of PbO nanoparticles. The prepared nanoparticles were conformed with the help of SEM, X-ray diffraction, FTIR and UV-visible spectroscopy. The prepared PbO nanoparticles were dispersed in deionized water and mixed with graphite to get graphite-PbO (G-PbO) filler. Seven different nanocomposite membranes with variable compositions (5, 10, 15, 20, 25, 30 and 35%) of PVC/G-PbO were prepared in tetrahydrofuran (THF) solvent using solution casting method. Different physiochemical parameters of the nanocomposite membranes studied included morphology, porosity, density, water uptake, swelling degree, electrical conductivity and proton adsorption capacity. All these physiochemical parameters were compared with pure PVC membranes available in literature. It was found that the addition of G-PbO filler in PVC polymer improved all the physiochemical properties except density. PVC/G-PbO membranes showed 42.65 times more electrical conductivity and 5.90 times more ion adsorption capacities compare to pure PVC membranes.

Keywords: adsorption capacity; electrical conductivity; nanocomposite membranes; PbO nanoparticles; physiochemical properties
Corresponding authors: Muhammad Khan, School of Materials Science and Engineering, Northwestern Polytechnical University, Xian, 710072, P.R. China; and Department of Chemistry, University of Okara, Punjab, Pakistan, E-mail: ; and Amir Zada, Department of Chemistry, Abdul Wali Khan University, Mardan, Khyber Pakhtunkhwa, 23200, Pakistan, E-mail:

Acknowledgments

I pay my special thanks to Dr. Amjad Ali for his help in four probe characterizations. I would like to thank Dr. Fahim Arshad for his help in carrying out microscopic work.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Aze, S., Vallet, J. M., Detalle, V., Grauby, O., Baronnet, A. Phase Transitions 2008, 81, 145–154; https://doi.org/10.1080/01411590701514326.Suche in Google Scholar

2. Sonmez, M., Kumar, R. Hydrometallurgy 2009, 95, 53–60; https://doi.org/10.1016/j.hydromet.2008.04.012.Suche in Google Scholar

3. Tayebee, R., Maleki, B. J. Iran. Chem. Soc. 2017, 14, 1179–1188; https://doi.org/10.1007/s13738-017-1068-2.Suche in Google Scholar

4. Hayat, A., Sohail, M., Hamdy, M. S., Mane, S. K. B., Amin, M. A., Zada, A., Taha, T. A., Rahman, M. M., Palamanit, A., Medina, D. I., Khan, J., Nawawi, W. I. Mol. Catal. 2022, 518, 112064; https://doi.org/10.1016/j.mcat.2021.112064.Suche in Google Scholar

5. Hewavitharana, I. K., Brock, S. L. Z. Phys. Chem. 2018, 232, 1691; https://doi.org/10.1515/zpch-2018-1171.Suche in Google Scholar

6. Miri, A., Sarani, M., Hashemzadeh, A., Mardani, Z., Darroudi, M. Green Chem. Lett. Rev. 2018, 11, 567–572; https://doi.org/10.1080/17518253.2018.1547926.Suche in Google Scholar

7. Zhao, Y., Zada, A., Yang, Y., Pan, J., Wang, Y., Yan, Z., Xu, Z., Qi, K. Front. Chem. 2021, 9, 797738; https://doi.org/10.3389/fchem.2021.797738.Suche in Google Scholar PubMed PubMed Central

8. Saeed, K., Khan, I., Ahad, M., Shah, T., Sadiq, M., Zada, A., Zada, N. Appl. Water Sci. 2021, 11, 105; https://doi.org/10.1007/s13201-021-01442-0.Suche in Google Scholar

9. Muhammad, W., Khan, M. A., Nazir, M., Siddiquah, A., Mushtaq, S., Hashmi, S. S., Abbasi, B. H. Mater. Sci. Eng. C 2019, 103, 109740; https://doi.org/10.1016/j.msec.2019.109740.Suche in Google Scholar PubMed

10. Song, R., Wang, Q., Mao, B., Wang, Z., Tang, D., Zhang, B., Zhang, J., Liu, C., He, D., Wu, Z. Carbon 2018, 130, 164–169; https://doi.org/10.1016/j.carbon.2018.01.019.Suche in Google Scholar

11. Hussain, Z., Zada, A., Hussain, K., Naz, M. Y., Salam, N. M. A., Ibrahim, K. A. Asia Pac. J. Chem. Eng. 2021, 16, e2610; https://doi.org/10.1002/apj.2610.Suche in Google Scholar

12. Ali, A., Hussain, Z., Zahid, M., Qamar, L., Zada, A., Arain, M. B., Salman, S. M., Khan, K. M. Int. J. Environ. Anal. Chem. 2020, 1–16; https://doi.org/10.1080/03067319.2020.1760860.Suche in Google Scholar

13. Ahmad, T., Guria, C. J. Water Proc. Eng. 2022, 45, 102466; https://doi.org/10.1016/j.jwpe.2021.102466.Suche in Google Scholar

14. Ali, A., Hussain, Z., Arain, M. B., Shah, N., Khan, K. M., Gulab, H., Zada, A. Spectrochim. Acta Mol. Biomol. Spectrosc. 2016, 153, 374–378; https://doi.org/10.1016/j.saa.2015.07.104.Suche in Google Scholar PubMed

15. El Sayed, A., Morsi, W. Polym. Compos. 2013, 34, 2031–2039; https://doi.org/10.1002/pc.22611.Suche in Google Scholar

16. El-Haddad, M. N. Z. Phys. Chem. 2019, 234, 1835–1851; https://doi.org/10.1515/zpch-2019-1390.Suche in Google Scholar

17. Hussain, Z., Zuhra, Rukh, G., Zada, A., Naz, M. Y., Khan, K. M., Shukrullah, S., Sulaiman, S. A. Clean. Eng. Technol. 2021, 5, 100342; https://doi.org/10.1016/j.clet.2021.100342.Suche in Google Scholar

18. Bellucci, S., Micciulla, F., Levin, V., Petronyuk, Y. S., Chernozatonskii, L., Kuzhir, P., Paddubskaya, A., Macutkevic, J., Pletnev, M., Fierro, V. AIP Adv. 2015, 5, 067137; https://doi.org/10.1063/1.4922872.Suche in Google Scholar

19. Zhang, Z., Zada, A., Cui, N., Liu, N., Liu, M., Yang, Y., Jiang, D., Jiang, J., Liu, S. Crystals 2021, 11, 981; https://doi.org/10.3390/cryst11080981.Suche in Google Scholar

20. Yasmeen, H., Zada, A., Ali, S., Khan, I., Ali, W., Khan, W., Khan, M., Anwar, N., Ali, A., Flores, A. M. H., Subhan, F. J. Chin. Chem. Soc. 2020, 67, 1611–1617; https://doi.org/10.1002/jccs.202000205.Suche in Google Scholar

21. Al-Hartomy, O. A., Al-Solamy, F., Al-Ghamdi, A. A., Ibrahim, M., Dishovsky, N., El-Tantawy, F. J. Elastomers Plastics 2011, 43, 137–153; https://doi.org/10.1177/0095244310393927.Suche in Google Scholar

22. Shukla, S. Indian J. Chem. Technol. 2018, 25, 196–200.Suche in Google Scholar

23. Dang, A., Sun, Y., Fang, C., Li, T., Liu, X., Xia, Y., Ye, F., Zada, A., Khan, M. Appl. Surf. Sci. 2022, 581, 152432; https://doi.org/10.1016/j.apsusc.2022.152432.Suche in Google Scholar

24. Raziq, F., Aligayev, A., Shen, H., Ali, S., Shah, R., et al.. Adv. Sci. 2022, 9, 2102530; https://doi.org/10.1002/advs.202102530.Suche in Google Scholar PubMed PubMed Central

25. Falade, O. S., Aderogba, M. A., Kehinde, O., Akinpelu, B. A., Oyedapo, B., Adewusi, S. Niger. J. Nat. Prod. Med. 2009, 13, 58–64.10.4314/njnpm.v13i1.61609Suche in Google Scholar

26. Lieder, R., Darai, M., Örlygsson, G., Sigurjonsson, O. E. Biol. Proced. Online 2013, 15, 11; https://doi.org/10.1186/1480-9222-15-11.Suche in Google Scholar PubMed PubMed Central

27. Ali, S., Ali, S., Ismail, P. M., Shen, H., Zada, A., et al.. Appl. Catal. B Environ. 2022, 307, 121149; https://doi.org/10.1016/j.apcatb.2022.121149.Suche in Google Scholar

28. Hamid, A., Khan, M., Hayat, A., Raza, J., Zada, A., Ullah, A., Raziq, F., Li, T., Hussain, F. Spectrochim. Acta Mol. Biomol. Spectrosc. 2020, 235, 118303; https://doi.org/10.1016/j.saa.2020.118303.Suche in Google Scholar PubMed

29. Beydaghi, H., Javanbakht, M. Ind. Eng. Chem. Res. 2015, 54, 7028–7037; https://doi.org/10.1021/acs.iecr.5b01450.Suche in Google Scholar

30. Uzma, S. A., Subhan, H., Shah, L. A., Khattak, N. S. Z. Phys. Chem. 2021, 236, 197–213; https://doi.org/10.1515/zpch-2020-1808.Suche in Google Scholar

31. Encinas, J., Castillo-Ortega, M., Rodriguez, F., Castano, V. J. Electron. Mater. 2015, 44, 3225–3228; https://doi.org/10.1007/s11664-015-3916-0.Suche in Google Scholar

32. Zada, A., Ali, N., Ateeq, M., Flores, A. M. H., Hussain, Z., Shaheen, S., Ullah, M., Ali, S., Khan, I., Ali, W., Shah, M. I. A., Khan, W. J. Chin. Chem. Soc. 2020, 67, 983–989; https://doi.org/10.1002/jccs.201900398.Suche in Google Scholar

33. Hanifehpour, Y., Mirtamizdoust, B., Ahmadi, H., Wang, R., Joo, S. W. J. Mol. Struct. 2020, 1224, 129031.10.1016/j.molstruc.2020.129031Suche in Google Scholar

34. Khan, M., Hamid, A., Tiehu, L., Zada, A., Attique, F., Ahmad, N., Ullah, A., Hayat, A., Mahmood, I., Hussain, A., Khan, Y., Ahmad, I., Ali, A., Zhao, T. K. Diam. Relat. Mater. 2020, 107, 107897; https://doi.org/10.1016/j.diamond.2020.107897.Suche in Google Scholar

35. Ali, N., Zada, A., Zahid, M., Ismail, A., Rafiq, M., Riaz, A., Khan, A. J. Chin. Chem. Soc. 2019, 66, 402–408; https://doi.org/10.1002/jccs.201800213.Suche in Google Scholar

36. Darki, S. Y., Kalantari, M. E., Zare, H., Shahedi, Z. Mater. Chem. Phys. 2021, 262, 124305; https://doi.org/10.1016/j.matchemphys.2021.124305.Suche in Google Scholar

37. Bangi, U. K. H., Park, H., Han, W., Prakshale, V. M., Deshmukh, L. P. Int. Nano Lett. 2017, 7, 149–155; https://doi.org/10.1007/s40089-017-0209-z.Suche in Google Scholar

38. Nazir, R., Khan, M., Rehman, R. U., Shujah, S., Khan, M., Ullah, M., Zada, A., Mahmood, N., Ahmad, I. Soil Water Res. 2020, 15, 166–172; https://doi.org/10.17221/59/2019-swr.Suche in Google Scholar

39. Ullah, M., Nazir, R., Khan, M., Khan, W., Shah, M., Afridi, S. G., Zada, A. Soil Water Res. 2020, 15, 30–37.10.17221/212/2018-SWRSuche in Google Scholar

40. Zada, A., Khan, M., Hussain, Z., Shah, M. I. A., Ateeq, M., Ullah, M., Ali, N., Shaheen, S., Yasmeen, H., Shah, S. N. A., Dang, A. Z. Phys. Chem. 2022, 236, 53–66; https://doi.org/10.1515/zpch-2020-1778.Suche in Google Scholar

41. Li, W., Ma-An, H., Fu, Y., Ma, C., Wang, G., Dong, X., Ma, H. J. Mater. Sci. 2021, 56, 4741–4752; https://doi.org/10.1007/s10853-020-05604-4.Suche in Google Scholar

42. Xu, M., Zada, A., Yan, R., Li, H., Sun, N., Qu, Y. Phys. Chem. Chem. Phys. 2020, 22, 4526–4532; https://doi.org/10.1039/c9cp05147c.Suche in Google Scholar PubMed

43. Zada, A., Khan, M., Khan, M. A., Khan, Q., Yangjeh, A. H., Dang, A. Environ. Res. 2021, 195, 110742; https://doi.org/10.1016/j.envres.2021.110742.Suche in Google Scholar PubMed

44. Zhu, J., Abeykoon, C., Karim, N. Int. J. Lightweight Mater. Manufac. 2021, 4, 370–382; https://doi.org/10.1016/j.ijlmm.2021.04.003.Suche in Google Scholar

45. Zada, A., Khan, M., Qureshi, M. N., Liu, S., Wang, R. Front. Chem. 2020, 7, 941; https://doi.org/10.3389/fchem.2019.00941.Suche in Google Scholar PubMed PubMed Central

46. Wang, S. J., Zhang, H., Shao, L. M., Liu, S. M., He, P. J. Chemosphere 2014, 117, 353–359; https://doi.org/10.1016/j.chemosphere.2014.07.076.Suche in Google Scholar PubMed

47. Deshmukh, S., Rao, A., Gaval, V., Joseph, S., Mahanwar, P. J. Miner. Mater. Char. Eng. 2010, 9, 831; https://doi.org/10.4236/jmmce.2010.99060.Suche in Google Scholar

48. Khan, M., Hayat, A., Mane, S. K. B., Li, T., Shaishta, N., Alei, D., Zhao, T. K., Ullah, A., Zada, A., Rehman, A. U., Khan, W. U. Int. J. Hydrogen Energy 2020, 45, 29070–29081; https://doi.org/10.1016/j.ijhydene.2020.07.274.Suche in Google Scholar

49. Yasmeen, H., Zada, A., Liu, S. J. Photochem. Photobiol. Chem. 2019, 380, 111867; https://doi.org/10.1016/j.jphotochem.2019.111867.Suche in Google Scholar

50. El Badawi, N., Ramadan, A. R., Esawi, A. M., El-Morsi, M. Desalination 2014, 344, 79–85; https://doi.org/10.1016/j.desal.2014.03.005.Suche in Google Scholar

51. Hamid, A., Mukhtar, A., Ghauri, M. S., Ali, A. J. Chem. Soc. Pakistan 2013, 35, 686–692.Suche in Google Scholar

52. Nahar, K., Rahman, M. S., Jahan, S., Zakirsultan, M., Sajjad, M. M. R., Sharif, M. T., Lubna, N. J., Chowdhury, A. A., Kabir, S., Amran, M. S. Eur. J. Prev. Med. 2015, 3, 17–21.10.11648/j.ejpm.20150302.11Suche in Google Scholar

53. Chen, Y., Lee, L., Ho, H., Sha, C., Sheu, M. J. Pharmaceut. Sci. 2012, 101, 3811–3822; https://doi.org/10.1002/jps.23279.Suche in Google Scholar PubMed

54. Hamid, A., Khan, M., Hussain, F., Zada, A., Li, T., Alei, D., Ali, A. Z. Phys. Chem. 2021, 235, 1791–1810; https://doi.org/10.1515/zpch-2020-1763.Suche in Google Scholar

55. Subhan, F., Aslam, S., Yan, Z., Yaseen, M., Zada, A., Ikram, M. Separ. Purif. Technol. 2021, 265, 118532; https://doi.org/10.1016/j.seppur.2021.118532.Suche in Google Scholar

56. Khan, M., Zada, A., Hayat, A., Ali, T., Uddin, I., Hayat, A., Khan, M., Ullah, A., Hussain, A., Li, T., Zhao, T. Int. J. Energy Res. 2021, 45, 14306–14337; https://doi.org/10.1002/er.6747.Suche in Google Scholar

57. Jiang, F., Zhang, Y., Wang, F., Zhou, X., Liao, W. Polymer 2021, 225, 123793; https://doi.org/10.1016/j.polymer.2021.123793.Suche in Google Scholar

58. Khan, W. A., Arain, M. B., Bibi, H., Tuzen, M., Shah, N., Zada, A. Z. Phys. Chem. 2021, 235, 1113–1128; https://doi.org/10.1515/zpch-2020-1761.Suche in Google Scholar

59. Cui, N., Zada, A., Song, J., Yang, Y., Liu, M., et al.. Desalination Water Treat. 2022, 245, 247–254; https://doi.org/10.5004/dwt.2022.27976.Suche in Google Scholar

60. Deyab, M. A., Al-Qhatani, M. M. Z. Phys. Chem. 2021, 236, 67–77; https://doi.org/10.1515/zpch-2021-3050.Suche in Google Scholar

61. Yang, G., Song, N., Deng, F., Liang, J., Huang, Q., Dou, J., Wen, Y., Liu, M., Zhang, X., Wei, Y. J. Mol. Liq. 2020, 306, 112877; https://doi.org/10.1016/j.molliq.2020.112877.Suche in Google Scholar

62. Wiemer, J. L., Rein, K., Weitzel, K. M. Z. Phys. Chem. 2021; https://doi.org/10.1515/zpch-2021-3091.Suche in Google Scholar

63. Elwan, H. A., Mamlouk, M., Scott, K. J. Power Sources 2021, 484, 229197; https://doi.org/10.1016/j.jpowsour.2020.229197.Suche in Google Scholar

64. Ahmed, S., Arshad, T., Zada, A., Afzal, A., Khan, M., Hussain, A., Hassan, M., Ali, M., Xu, S. Membranes 2021, 11, 450; https://doi.org/10.3390/membranes11060450.Suche in Google Scholar PubMed PubMed Central

65. Khan, M., Tiehu, L., Zaidi, S. B. A., Javed, E., Hussain, A., Hayat, A., Zada, A., Alei, D., Ullah, A. Polym. Int. 2021, 70, 1733–1740; https://doi.org/10.1002/pi.6274.Suche in Google Scholar
Received: 2021-10-08
Accepted: 2022-02-21
Published Online: 2022-03-08
Published in Print: 2022-05-25

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Original Papers
  3. Facile synthesis and adsorption characteristics of a hybrid composite based on ethyl acetoacetate modified chitosan/calcium alginate/TiO2 for efficient recovery of Ni(II) from aqueous solution
  4. Spectroscopic characterization of biosynthesized lead oxide (PbO) nanoparticles and their applications in PVC/graphite-PbO nanocomposites
  5. Green and eco-friendly synthesis of TiO2 nanoparticles and their application for removal of cadmium from wastewater: reaction kinetics study
  6. Catalytic degradation of MO and MB dyes under solar and UV light irradiation using ZnO fabricated using Syzygium Cumini leaf extract
  7. Graphene-substrate fabricated oxides and zinc oxide catalysts for the degradation of the methylene blue in the industrial wastewater
https://doi.org/10.1515/zpch-2021-3152
Schlagwörter für diesen Artikel
adsorption capacity; electrical conductivity; nanocomposite membranes; PbO nanoparticles; physiochemical properties

Artikel in diesem Heft

  1. Frontmatter
  2. Original Papers
  3. Facile synthesis and adsorption characteristics of a hybrid composite based on ethyl acetoacetate modified chitosan/calcium alginate/TiO2 for efficient recovery of Ni(II) from aqueous solution
  4. Spectroscopic characterization of biosynthesized lead oxide (PbO) nanoparticles and their applications in PVC/graphite-PbO nanocomposites
  5. Green and eco-friendly synthesis of TiO2 nanoparticles and their application for removal of cadmium from wastewater: reaction kinetics study
  6. Catalytic degradation of MO and MB dyes under solar and UV light irradiation using ZnO fabricated using Syzygium Cumini leaf extract
  7. Graphene-substrate fabricated oxides and zinc oxide catalysts for the degradation of the methylene blue in the industrial wastewater
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 8.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/zpch-2021-3152/pdf
Button zum nach oben scrollen