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ZnO/UV/H2O2 Based Advanced Oxidation of Disperse Red Dye

  • Aneela Jamil , Tanveer Hussain Bokhari , Munawar Iqbal EMAIL logo , Muhammad Zuber and Iftikhar Hussain Bukhari
Published/Copyright: April 16, 2019
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 234 Issue 1

Abstract

In view of promising efficiency of advanced oxidation process, ZnO/UV/H2O2 based advanced oxidation process (AOP) was employed for the degradation of Disperse Red-60 (DR-60) in aqueous medium. The process variables such as concentration of catalysts, reaction time, pH, dye initial concentration and H2O2 dose were evaluated for maximum degradation of dye. The maximum degradation of 97% was achieved at optimum conditions of H2O2 (0.9 mL/L), ZnO (0.6 g/L) at pH 9.0 in 60 min irradiation time. The analysis of treated dye solution revealed the complete degradation under the effect of ZnO/UV/H2O2 treatment. The water quality parameters were also studied of treated and un-treated dye solution and up to 79% COD and 60% BOD reductions were achieved when dye was treated with at optimum conditions. The dissolved oxygen increased up to 85.6% after UV/H2O2/ZnO treatment. The toxicity was also monitored using hemolytic and Ames tests and results revealed that toxicity (cytotoxicity and mutagenicity) was also reduced significantly. In view of promising efficiency of UV/H2O2/ZnO system, it could possibly be used for the treatment of wastewater containing toxic dyes.

Keywords: advanced oxidation process; characterization; disperse Red 60; toxicity; ZnO/UV/H2O2 system

Funding source: Higher Education Commission (HEC) of Pakistan

Award Identifier / Grant number: 5626/Punjab/NRPU/R&D/HEC/2016

Funding statement: Authors are grateful to the Higher Education Commission (HEC) of Pakistan for financial support to conduct this research work (Funder Id: http://dx.doi.org/10.13039/501100004681, Project No. 5626/Punjab/NRPU/R&D/HEC/2016).

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Received: 2019-01-09
Accepted: 2019-03-23
Published Online: 2019-04-16
Published in Print: 2020-01-28

©2020 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. The Maximum of Minimal Conductivity in Aqueous Electrolytes
  3. The Effect of Low Weight Percent Multiwalled Carbon Nanotubes on the Dielectric Properties of Non-Conducting Polymer/Ceramic Nanocomposites for Energy Storage Materials
  4. Synthesis, Characterization and Electrical Conductivity of Silver Doped Polyvinyl Acetate/Graphene Nanocomposites: A Novel Humidity Sensor
  5. Preparation, Physical Characterization and Adsorption Properties of Synthesized Co–Ni–Cr Nanocomposites for Highly Effective Removal of Nitrate: Isotherms, Kinetics and Thermodynamic Studies
  6. New Heterocyclic Derivative to Stop Carbon Steel Corrosion
  7. Investigating of Erosion-Corrosion Behavior of Carbon Steel in Egyptian Crude Oil-Water Mixture Using Electrochemical Method
  8. Structural, Vibrational and UV/Vis Studies of Adamantane-Containing Triazole Thiones by Spectral, DFT and Multi-reference ab initio Methods
  9. The Effect of Grain Size and Shape on Sliding Friction of Wet Granular Media
  10. Decomposition Kinetics of Levofloxacin: Drug-Excipient Interaction
  11. ZnO/UV/H2O2 Based Advanced Oxidation of Disperse Red Dye
  12. An Efficient Ultrasonic-Assisted Synthesis and Nonlinear Optical Property of Donor (D) -π-Acceptor (A) Chalcone (DDFP)
  13. Synthesized and Photocatalytic Mechanism of the NiO Supported YMnO3 Nanoparticles for Photocatalytic Degradation of the Methyl Orange Dye
https://doi.org/10.1515/zpch-2019-0006
Keywords for this article
advanced oxidation process; characterization; disperse Red 60; toxicity; ZnO/UV/H2O2 system

Articles in the same Issue

  1. Frontmatter
  2. The Maximum of Minimal Conductivity in Aqueous Electrolytes
  3. The Effect of Low Weight Percent Multiwalled Carbon Nanotubes on the Dielectric Properties of Non-Conducting Polymer/Ceramic Nanocomposites for Energy Storage Materials
  4. Synthesis, Characterization and Electrical Conductivity of Silver Doped Polyvinyl Acetate/Graphene Nanocomposites: A Novel Humidity Sensor
  5. Preparation, Physical Characterization and Adsorption Properties of Synthesized Co–Ni–Cr Nanocomposites for Highly Effective Removal of Nitrate: Isotherms, Kinetics and Thermodynamic Studies
  6. New Heterocyclic Derivative to Stop Carbon Steel Corrosion
  7. Investigating of Erosion-Corrosion Behavior of Carbon Steel in Egyptian Crude Oil-Water Mixture Using Electrochemical Method
  8. Structural, Vibrational and UV/Vis Studies of Adamantane-Containing Triazole Thiones by Spectral, DFT and Multi-reference ab initio Methods
  9. The Effect of Grain Size and Shape on Sliding Friction of Wet Granular Media
  10. Decomposition Kinetics of Levofloxacin: Drug-Excipient Interaction
  11. ZnO/UV/H2O2 Based Advanced Oxidation of Disperse Red Dye
  12. An Efficient Ultrasonic-Assisted Synthesis and Nonlinear Optical Property of Donor (D) -π-Acceptor (A) Chalcone (DDFP)
  13. Synthesized and Photocatalytic Mechanism of the NiO Supported YMnO3 Nanoparticles for Photocatalytic Degradation of the Methyl Orange Dye
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