One-Pot Synthesis and Rheological Study of Cationic Poly (3-acrylamidopropyltrimethyl ammoniumchloride) P(APTMACl) Polymer Hydrogels
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Abstract
The main objective of this research work is to explore the complete and extensive rheological studies of cationic poly (3-acrylamidopropyl trimethyl ammonium chloride) P(APTMACl) hydrogel, prepared by free radical polymerization method at room temperature. Hydrogel was characterized by various techniques such as SEM, FTIR and TGA, whereas rheological properties of synthesized hydrogel were obtained using frequency sweep and frequency curve analysis in different temperature range. Storage modulus (G′) and loss modulus (G′′) were investigated as a function of angular frequencies and shear stress at various temperatures. Rheological models like Bingham plastic model, modified Bingham and Ostwald power law were applied to understand the rheological performance of the gels. Flow curves obtained at different temperatures indicate that P(APTMACl) hydrogel shows a non-Newtonian pseudo plastic behavior. All results concluded that rheology is a powerful tool to study the complete visco-elastic behavior of polymer hydrogel for multiple applications.
Acknowledgement
Dr. Luqman Ali Shah is highly thankful to Higher Education Commission (HEC) of Pakistan for financial support under the startup research grant program No. 21-718/SRGP/R&D/HEC/2016.
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Supplementary Material
The online version of this article offers supplementary material (DOI: https://doi.org/10.1515/zpch-2018-1310).
©2019 Walter de Gruyter GmbH, Berlin/Boston
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Articles in the same Issue
- Frontmatter
- Hydrogen Bond Interaction of Ascorbic Acid with Urea: Experimental and Theoretical Study
- The Thermodynamic and Binding Studies of Hg+2 Ions with Egg Protein by Polarographic and pH Metric Techniques
- Effect of Maltodextrin and Temperature on Micellar Behavior of Bile Salts in Aqueous Medium: Conductometric and Spectrofluorimetric Studies
- Probing Inclusion Complexes of Pentoxifylline and Pralidoxim inside Cyclic Oligosaccharides by Physicochemical Methodologies
- Solubility and Solution Thermodynamics of Baricitinib in Six Different Pharmaceutically Used Solvents at Different Temperatures
- One-Pot Synthesis and Rheological Study of Cationic Poly (3-acrylamidopropyltrimethyl ammoniumchloride) P(APTMACl) Polymer Hydrogels
- Synthesis and Characterization of BaAl2O4 Catalyst and its Photocatalytic Activity Towards Degradation of Methylene Blue Dye
- Chemically Synthesized Hierarchical Flower like ZnO Microstructures
- Statistical Modeling, Optimization and Kinetics of Mn2+ Adsorption in Aqueous Solution Using a Biosorbent
