Amine Capped Gold Colloids at Oxidic Supports: Their Electronic Interactions
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Michael Siemer
Abstract
Colloidal deposition of noble metal nanoparticles on oxidic supports is a recent approach for the fabrication of heterogeneous catalyst materials. We present studies on the interaction of different amine ligands with gold nanoparticles before and after deposition on several oxidic supports (titania, silica, alumina, magnesia or zinc oxide), using X-ray photoelectron and Auger spectroscopy, and high-resolution transmission electron microscopy. The adsorption of amines on thin gold films as well as on nanoparticles leads to a decrease in metal photoelectron binding energies. Usually, this is explained by donor-acceptor interactions via the amine group. By additional analysis of Auger signals, which are more sensitive to changes in the oxidation state than photoelectron spectra, we demonstrate that these shifts are due to a final state effect, namely, the increased photoelectron hole screening in presence of amine adsorbates. It will be shown, that this effect is not sensitive neither to the nanoparticle size nor the sterical properties of the capping amine. After deposition on oxide supports, the photoelectron binding energies are even further decreased. The presented findings exhibit that care has to be taken to interpret binding energy shifts simply with charging, which has impact on understanding the local electronic situation on the surface of metal-loaded oxides, crucial for heterogeneous catalysis.
Acknowledgment
Hereby, we want to thank Pascal Buhani for providing additional data on ODA capped gold nanoparticles and Erhard Rhiel, Ute Friedrich und Edith Kieselhorst for assistance in the electron microscopy facility and Carsten Dosche for technical support related to XPS.
The JEOL JEM2100F electron microscope and the Thermo Fisher ESCALAB 250Xi spectrometer were funded by the Deutsche Forschungsgesellschaft (INST 184/106-1 FUGG and INST 184/144-1 FUGG). This support is gratefully acknowledged.
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Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/zpch-2018-0004).
©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Editorial
- Nanosized Matter
- Extinction Coefficient of Plasmonic Nickel Sulfide Nanocrystals and Gold-Nickel Sulfide Core-Shell Nanoparticles
- Thermal cis-to-trans Isomerization of Azobenzene Side Groups in Metal-Organic Frameworks investigated by Localized Surface Plasmon Resonance Spectroscopy
- Brightly Luminescent Cu-Zn-In-S/ZnS Core/Shell Quantum Dots in Salt Matrices
- Role of Tryptophan in Protein–Nanocrystals Interaction: Energy or Charge Transfer
- Synthesis of InP/ZnS Nanocrystals and Phase Transfer by Hydrolysis of Ester
- Amine Capped Gold Colloids at Oxidic Supports: Their Electronic Interactions
- Yolk Type Asymmetric Ag–Cu2O Hybrid Nanoparticles on Graphene Substrate as Efficient Electrode Material for Hybrid Supercapacitors
- Electrospun CuO Nanofibre Assemblies for H2S Sensing
- Review
- Two-Dimensional Oxides: Recent Progress in Nanosheets
Artikel in diesem Heft
- Frontmatter
- Editorial
- Nanosized Matter
- Extinction Coefficient of Plasmonic Nickel Sulfide Nanocrystals and Gold-Nickel Sulfide Core-Shell Nanoparticles
- Thermal cis-to-trans Isomerization of Azobenzene Side Groups in Metal-Organic Frameworks investigated by Localized Surface Plasmon Resonance Spectroscopy
- Brightly Luminescent Cu-Zn-In-S/ZnS Core/Shell Quantum Dots in Salt Matrices
- Role of Tryptophan in Protein–Nanocrystals Interaction: Energy or Charge Transfer
- Synthesis of InP/ZnS Nanocrystals and Phase Transfer by Hydrolysis of Ester
- Amine Capped Gold Colloids at Oxidic Supports: Their Electronic Interactions
- Yolk Type Asymmetric Ag–Cu2O Hybrid Nanoparticles on Graphene Substrate as Efficient Electrode Material for Hybrid Supercapacitors
- Electrospun CuO Nanofibre Assemblies for H2S Sensing
- Review
- Two-Dimensional Oxides: Recent Progress in Nanosheets
