Home Optimal co-catalytic effect of NiFe2O4/ZnO nanocomposites toward enhanced photodegradation for dye MB
Article
Licensed
Unlicensed Requires Authentication

Optimal co-catalytic effect of NiFe2O4/ZnO nanocomposites toward enhanced photodegradation for dye MB

  • Zuming He , Yongmei Xia EMAIL logo , Bin Tang EMAIL logo , Jiangbin Su and Xingfang Jiang
Published/Copyright: June 22, 2018

Abstract

A series of magnetically recyclable NiFe2O4/ZnO nanocomposites have been successfully fabricated by a facile two-step route. The as-prepared NiFe2O4/ZnO nanocomposites were characterized by X-ray diffraction, field-emission scanning electron microscopy, vibrating sample magnetometer, ultraviolet-visible diffuse reflectance spectroscopy and photoluminescence spectroscopy. The results demonstrate that the NiFe2O4/ZnO nanocomposites are composed of ZnO particles (50–120 nm) integrated with NiFe2O4 particles (30–80 nm). Compared with bare ZnO, the NiFe2O4/ZnO nanocomposites exhibit evidently enhanced visible light absorption and decreased recombination of photo-generated electron-hole pairs. Moreover, the nanocomposites exhibit enhanced photocatalytic performance for the degradation of methylene blue under simulated solar light irradiation when compared with bare ZnO, and the 20%-NiFe2O4/ZnO nanocomposite is observed as the optimal composite. This is ascribed to the more efficient separation of photo-generated electron-hole pairs and generation of hydroxyl (˙OH) radicals in the 20%-NiFe2O4/ZnO nanocomposite. Furthermore, the NiFe2O4/ZnO nanocomposites have a high saturation magnetization, indicating that they can be magnetically separated and recycled from organic dye wastewater.

Award Identifier / Grant number: 61107055

Funding statement: This work was supported by the National Natural Science Foundation of China (61107055) and the Universities-Funded Natural Science Project of Jiangsu Province (15KJD430004).

References

1. A. Ahmad, S. H. Mohd-Setapar, C. S. Chuong, A. Khatoon, W. A. Wani, R. Kumar and M. Rafatullah, RSC Adv. 5 (2015) 30801.10.1039/C4RA16959JSearch in Google Scholar

2. Z. M. Cui, H. Yang, X. X. Zhao, Mater. Sci. Eng. B 229 (2018) 160.10.1016/j.mseb.2017.12.037Search in Google Scholar

3. F. Wang, H. Yang, Y. C. Zhang, Mater. Sci. Semicond. Proc. 73 (2018) 58.10.1016/j.mssp.2017.09.029Search in Google Scholar

4. L. J. Di, H. Yang, T. Xian, X. X. Chen, Materials 10 (2017) 1118.10.3390/ma10101118Search in Google Scholar PubMed PubMed Central

5. K. J. Liu, J. Y. Zhang, H. Gao, T. F. Xie, D. J. Wang, J. Alloy Compd. 552 (2013) 299.10.1016/j.jallcom.2012.10.111Search in Google Scholar

6. J. C. Colmenares, E. Kuna, S. Jakubiak, J. Michalski, K. Kurzydłowski, Appl. Catal. B Environ. 170–171 (2015) 273.10.1016/j.apcatb.2015.01.031Search in Google Scholar

7. C. Han, M. Q. Yang, B. Weng, Y. J. Xu, Chem. Phys. 16 (2014) 16891.10.1039/C4CP02189DSearch in Google Scholar

8. M. Saeed, M. Siddique, M. Usman, A. U. Haq, S. G. Khan, H. A. Raoof, Z. Phys. Chem. 231 (2016) 1559.10.1515/zpch-2016-0921Search in Google Scholar

9. H. K. Farag, A. M. El-Shamy, E. M. Sherif, Z. Phys. Chem. 230 (2016) 1733.10.1515/zpch-2016-0777Search in Google Scholar

10. Z. M. He, Y. M. Xia, B. Tang, X. F. Jiang, J. B. Su, Mater. Lett. 184 (2016) 148.10.1016/j.matlet.2016.08.020Search in Google Scholar

11. J. K. Vaishnav, S. S. Arbuj, S. B. Rane, D. P. Amalnerkar, RSC Adv. 4 (2014) 47637.10.1039/C4RA08561BSearch in Google Scholar

12. J. Baima, A. Erba, L. Maschio, C. M. Zicovich-Wilson, R. Dovesi, B. Kirtman, Z. Phys. Chem. 230 (2015) 719.10.1515/zpch-2015-0701Search in Google Scholar

13. C. X. Zheng, H. Yang, Z. M. Cui, H. M. Zhang, X. X. Wang, Nanoscale Res. Lett. 12 (2017) 608.10.1186/s11671-017-2377-1Search in Google Scholar PubMed PubMed Central

14. Z. M. He, Y. M. Xia, B. Tang, J. B. Su, Mater Res. Express 4 (2017) 095501.10.1088/2053-1591/aa7cb8Search in Google Scholar

15. X. J. Chen, Y. Z. Dai, T. H. Liu, J. Guo, X. Y. Wang, F. F. Li, J. Mol. Catal. A Chem. 409 (2015) 198.10.1016/j.molcata.2015.08.021Search in Google Scholar

16. S. S. Patil, M. S. Tamboli, V. G. Deonikar, G. G. Umarji, J. D. Ambekar, M. V. Kulkarni, S. S. Kolekar, B. B. Kale, D. R. Patil, Dalton Trans. 44 (2015) 20426.10.1039/C5DT03173GSearch in Google Scholar PubMed

17. Y. L. Li, Z. Q. Zhang, L. Y. Pei, X. G. Li, T. Fan, J. Ji, J. F. Shen, M. X. Ye, Appl. Catal. B Environ. 190 (2016) 1.10.1016/j.apcatb.2016.02.054Search in Google Scholar

18. E. Casbeer, V. K. Sharma, X. Z. Li, Sep. Purif. Technol. 87 (2012) 1.10.1016/j.seppur.2011.11.034Search in Google Scholar

19. N. M. Mahmoodi, J. Taiwan Inst. Chem. Eng.44 (2013) 322.10.1016/j.jtice.2012.11.014Search in Google Scholar

20. L. Sun, R. Shao, L. Tang, Z. Chen, J. Alloy Compd. 564 (2013) 55.10.1016/j.jallcom.2013.02.147Search in Google Scholar

21. X. J. Chen, Y. Z. Dai, J. Guo, T. H. Liu, X. Y. Wang, Ind. Eng. Chem. Res. 55 (2016) 568.10.1021/acs.iecr.5b03690Search in Google Scholar

22. J. Jiang, L. H. Ai, L. C. Li, H. Liu, J. Alloys Compd. 484 (2009) 69.10.1016/j.jallcom.2009.04.060Search in Google Scholar

23. L. Zhang, W. L. Jiao, J. Alloy Compd. 581 (2013) 11.10.1016/j.jallcom.2013.06.157Search in Google Scholar

24. H. Y. Zhu, R. Jiang, Y. Q. Fu, R. R. Li, J. Yao, S. T. Jiang, Appl. Surf. Sci. 369 (2016) 1.10.1016/j.apsusc.2016.02.025Search in Google Scholar

25. X. Guo, H. J. Zhu, Q. Li, Appl. Catal. B Environ. 160–161 (2014) 408.10.1016/j.apcatb.2014.05.047Search in Google Scholar

26. M. Sun, T. Li, Z. Zhang, N. Wang, A. Xie, X. Lv, Y. Wang, F. Wu, M. Wang, RSC Adv. 5 (2015) 84406.10.1039/C5RA16389GSearch in Google Scholar

27. Y. M. Xia, Z. M. He, J. B. Su, B. Tang, K. J. Hu, Y. L. Lu, S. P. Sun, X. P. Li, RSC Adv. 8 (2018) 4284.10.1039/C7RA12546ASearch in Google Scholar

28. X. Zhao, H. Yang, Z. Cui, R. Li, W. Feng, Mater. Technol. 32 (2017) 870.10.1080/10667857.2017.1371914Search in Google Scholar

29. F. Wang, H. Yang, H. M. Zhang, J. L. Jiang, J. Mater. Sci. Mater. Electron. 29 (2018) 1304.10.1007/s10854-017-8036-6Search in Google Scholar

30. Y. C. Ye, H. Yang, R. S. Li, X. X. Wang, J. Sol-Gel Sci. Technol. 82 (2017) 509.10.1007/s10971-017-4332-0Search in Google Scholar

31. R. H. Kodama, A. E. Berkowitz Jr, E. J. McNiff, S. Foner, Phys. Rev. Lett. 77 (1996) 394.10.1103/PhysRevLett.77.394Search in Google Scholar PubMed

32. Y. M. Xia, Z. M. He, J. B. Su, B. Tang, K. J. Hu, Y. L. Lu, S. P. Sun, X. P. Li, RSC Adv. 8 (2018) 5441.10.1039/C7RA12393KSearch in Google Scholar

Received: 2017-08-01
Accepted: 2018-06-03
Published Online: 2018-06-22
Published in Print: 2019-03-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 26.10.2025 from https://www.degruyterbrill.com/document/doi/10.1515/zpch-2017-1017/html
Scroll to top button