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The solid solutions TbCuIn1–x M x (M = Al, Ga)

  • Myroslava Horiacha , Galyna Nychyporuk , Rainer Pöttgen EMAIL logo and Vasyl Zaremba EMAIL logo
Published/Copyright: April 21, 2022
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 77 Issue 7-8

Abstract

The complete solid solutions TbCuIn1–x M x (M = Al, Ga) were studied by powder X-ray diffraction and scanning electron microscopy for samples equilibrated at T = 873 K. The influence of In substitution by Al or Ga, the solubility ranges and the changes of unit cell parameters have been determined: TbCuIn1.0–0Al0–1.0 (ZrNiAl type, space group P 6 ‾ 2 m, a = 0.7457(1)–0.7035(1), c = 0.3958(1)–0.4044(1) nm, V = 0.1906–0.1733 nm3); TbCuIn1–0.8Ga0–0.2 (ZrNiAl type, a = 0.74569(5)–0.73882(13), с = 0.39582(3)–0.39663(14) nm, V = 0.1906–0.1875 nm3); TbCuIn0.3–0Ga0.7–1.0 (KHg2 type, Imma, а = 0.43943(9)–0.43750(5), b = 0.70833(12)–0.70537(6), с = 0.74866(12)–0.74525(7) nm, V = 0.2330–0.2300 nm3). The crystal structure of TbCuIn0.42(1)Al0.58(1) was refined from single-crystal X-ray diffractometer data: ZrNiAl type, P 6 ‾ 2 m, a = 0.71633(6), c = 0.40785(3) nm, wR2 = 0.0379, 291 F 2 values and 16 variables. The basic crystal chemical features are discussed.

Keywords: copper; crystal structure; indium; solid solutions; terbium; X-ray powder data
Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail: ; and Vasyl Zaremba, Inorganic Chemistry Department, Ivan Franko National University of Lviv, Kyryla i Mefodiya Street 6, 79005 Lviv, Ukraine, E-mail:

Acknowledgements

This work was supported by the DAAD foundation (research stipend to MH).

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-03-22
Accepted: 2022-03-31
Published Online: 2022-04-21
Published in Print: 2022-07-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Electron density of a benzoylated tetrafructopyranose
  5. Die Reihe der nicht-zentrosymmetrischen tetragonalen Lanthanoid(III)-Oxidoantimonat(III)-Chloride LnSb2O4Cl (Ln = Gd–Lu)
  6. Iminium-substituted 2,3-dihydroisoxazoles: synthesis from acetylenic iminium salts and nitrones, and some transformations
  7. Reactions of 1-trifluoromethyl-prop-2-yne1-iminium salts with 2- and 3-aminopyridines
  8. 2,5-Dihydroxy-1,4-quinones appended with two phosphinyl groups: syntheses, structures, and redox properties
  9. Ordered CaCu5-type phases REPd2Zn3 (RE = Y, La–Nd, Sm, Gd–Dy)
  10. The solid solutions TbCuIn1–x M x (M = Al, Ga)
  11. Synthesis and structural characterization of a luminescent cadmium(II) complex with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands
  12. Synthesis and structure of a zinc(II) coordination polymer assembled with 5-(3-carboxybenzyloxy)isophthalic acid and 1,2-bis(4-pyridyl)ethane
  13. Orthoamide und Iminiumsalze, CV. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit Carbonsäureamiden
  14. Notes
  15. Addendum to: bixbyite-type phases in the system Ta-Zr-O-N
  16. Addendum to: Crystal structure of mechanochemically synthesized Ag2CdSnS4
  17. Addendum to: FeBiS2Cl – a new iron-containing member of the MPnQ 2 X family
https://doi.org/10.1515/znb-2022-0042
Keywords for this article
copper; crystal structure; indium; solid solutions; terbium; X-ray powder data

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Electron density of a benzoylated tetrafructopyranose
  5. Die Reihe der nicht-zentrosymmetrischen tetragonalen Lanthanoid(III)-Oxidoantimonat(III)-Chloride LnSb2O4Cl (Ln = Gd–Lu)
  6. Iminium-substituted 2,3-dihydroisoxazoles: synthesis from acetylenic iminium salts and nitrones, and some transformations
  7. Reactions of 1-trifluoromethyl-prop-2-yne1-iminium salts with 2- and 3-aminopyridines
  8. 2,5-Dihydroxy-1,4-quinones appended with two phosphinyl groups: syntheses, structures, and redox properties
  9. Ordered CaCu5-type phases REPd2Zn3 (RE = Y, La–Nd, Sm, Gd–Dy)
  10. The solid solutions TbCuIn1–x M x (M = Al, Ga)
  11. Synthesis and structural characterization of a luminescent cadmium(II) complex with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands
  12. Synthesis and structure of a zinc(II) coordination polymer assembled with 5-(3-carboxybenzyloxy)isophthalic acid and 1,2-bis(4-pyridyl)ethane
  13. Orthoamide und Iminiumsalze, CV. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit Carbonsäureamiden
  14. Notes
  15. Addendum to: bixbyite-type phases in the system Ta-Zr-O-N
  16. Addendum to: Crystal structure of mechanochemically synthesized Ag2CdSnS4
  17. Addendum to: FeBiS2Cl – a new iron-containing member of the MPnQ 2 X family
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