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Synthesis and structure of a zinc(II) coordination polymer assembled with 5-(3-carboxybenzyloxy)isophthalic acid and 1,2-bis(4-pyridyl)ethane

  • Xin-Hong Chang
Published/Copyright: June 6, 2022
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 77 Issue 7-8

Abstract

A zinc(II) coordination polymer [Zn(cyip)(bpe)] n (1), (cyipH2 = 5-(3-carboxybenzyloxy)-isophthalic acid, bpe = 1,2-bis(4-pyridyl)ethane), has been synthesized under hydrothermal conditions. Its structure was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectra. Complex 1 crystallizes in the monoclinic space group I2/a. In 1, the [cyip]2– ligand bridges the Zn(II) cations to form infinite chains, which are connected through O–H···O hydrogen bonds into layers in the form of 2-fold interpenetrated nets.

Keywords: coordination polymer; crystal structure; zinc complex
Corresponding author: Xin-Hong Chang, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, P. R. China, E-mail:

  1. Author contributions: The author has accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The author declare no conflicts of interest regarding this article.

References

1. Qin, J. H., Xu, P., Huang, Y. D., Xiao, L. Y., Lu, W. W., Yang, X. G., Ma, L. F., Zang, S. Q. Chem. Commun. 2021, 57, 8468–8471; https://doi.org/10.1039/d1cc02847b.Search in Google Scholar PubMed

2. Xue, L. P., Li, Z. H., Zhang, T., Cui, J. J., Gao, Y., Yao, J. X. New J. Chem. 2018, 42, 14203–14209; https://doi.org/10.1039/c8nj02055h.Search in Google Scholar

3. Deng, D., Guo, H., Ji, B., Wang, W., Ma, L., Luo, F. New J. Chem. 2017, 41, 12611–12616; https://doi.org/10.1039/c7nj02021j.Search in Google Scholar

4. Han, M. L., Duan, Y. P., Li, D. S., Xu, G. W., Wu, Y. P., Zhao, J. Dalton Trans. 2014, 43, 17519–17527; https://doi.org/10.1039/c4dt01946f.Search in Google Scholar PubMed

5. Li, J.-X., Xiong, L.-Y., Fu, L.-L., Bo, W.-B., Du, Z.-X., Feng, X. J. Solid State Chem. 2022, 305, 122636; https://doi.org/10.1016/j.jssc.2021.122636.Search in Google Scholar

6. Li, R.-F., Li, R.-H., Liu, X.-F., Chang, X.-H., Feng, X. RSC Adv. 2020, 10, 6192–6199; https://doi.org/10.1039/c9ra10975g.Search in Google Scholar PubMed PubMed Central

7. Chang, X.-H., Han, M.-L. Chin. J. Struct. Chem. 2015, 34, 1895–1900.Search in Google Scholar

8. Chang, X.-H., Qin, J.-H., Han, M.-L., Ma, L.-F., Wang, L.-Y. CrystEngComm 2014, 16, 870–882; https://doi.org/10.1039/c3ce41641k.Search in Google Scholar

9. Chang, X.-H., Qin, J.-H., Ma, L.-F., Wang, L.-Y. J. Solid State Chem. 2014, 212, 121–127; https://doi.org/10.1016/j.jssc.2013.12.030.Search in Google Scholar

10. Qin, J. H., Huang, Y. D., Shi, M. Y., Wang, H. R., Han, M. L., Yang, X. G., Li, F. F., Ma, L. F. RSC Adv. 2020, 10, 1439–1446; https://doi.org/10.1039/c9ra08733h.Search in Google Scholar PubMed PubMed Central

11. Fu, H. R., Wu, X. X., Ma, L. F., Wang, F., Zhang, J. ACS Appl. Mater. Interfaces 2018, 10, 18012–18020; https://doi.org/10.1021/acsami.8b05614.Search in Google Scholar PubMed

12. Li, R.-F., Zhang, Y.-W., Liu, X.-F., Chang, X.-H., Feng, X. Inorg. Chim. Acta 2020, 502, 119370; https://doi.org/10.1016/j.ica.2019.119370.Search in Google Scholar

13. Liu, X., Zhang, X., Li, R., Du, L., Feng, X., Ding, Y. Dyes Pigments 2020, 178, 108347; https://doi.org/10.1016/j.dyepig.2020.108347.Search in Google Scholar

14. Fu, H. R., Yan, L. B., Xie, T. Chin. J. Struct. Chem. 2018, 37, 796–802.Search in Google Scholar

15. Qin, J. H., Zhang, H., Sun, P. F., Huang, Y. D., Shen, Q. M., Yang, X. G., Ma, L. F. Dalton Trans. 2020, 49, 17772–17778; https://doi.org/10.1039/d0dt03031g.Search in Google Scholar PubMed

16. Fu, H. R., Wang, N., Qin, J. H., Han, M. L., Ma, L. F., Wang, F. Chem. Commun. 2018, 54, 11645–11648; https://doi.org/10.1039/c8cc05990j.Search in Google Scholar PubMed

17. Li, S. H., Han, M. L., Liu, G. Z., Ma, L. F., Wang, L. Y. RSC Adv. 2015, 5, 17588–17591; https://doi.org/10.1039/c5ra00621j.Search in Google Scholar

18. Li, J.-X., Zhang, Y.-H., Du, Z.-X., Feng, X. Inorg. Chim. Acta 2022, 530, 120697; https://doi.org/10.1016/j.ica.2021.120697.Search in Google Scholar

19. Yang, X.-G., Lu, X.-M., Zhai, Z.-M., Zhao, Y., Liu, X.-Y., Ma, L.-F., Zang, S.-Q. Chem. Commun. 2019, 55, 11099–11102; https://doi.org/10.1039/c9cc05708k.Search in Google Scholar PubMed

20. Yang, X.-G., Zhai, Z.-M., Lu, X.-M., Zhao, Y., Chang, X.-H., Ma, L.-F. Dalton Trans. 2019, 48, 10785–10789; https://doi.org/10.1039/c9dt02178g.Search in Google Scholar PubMed

21. Chang, X.-H., Yang, X.-G., Zhai, Z.-M., Chen, J.-Y., Li, F.-F. Chin. J. Struct. Chem. 2021, 40, 187–192.Search in Google Scholar

22. Chang, X.-H., Ling, X.-L., Lu, X.-M., Yang, X.-G., Li, F.-F., Guo, Y.-M. J. Solid State Chem. 2020, 292, 121694; https://doi.org/10.1016/j.jssc.2020.121694.Search in Google Scholar

23. Chang, X.-H., Qin, W.-J., Zhang, X.-Y., Jin, X., Yang, X.-G., Dou, C.-X., Ma, L.-F. Inorg. Chem. 2021, 60, 10109–10113; https://doi.org/10.1021/acs.inorgchem.1c01541.Search in Google Scholar PubMed

24. Medishetty, R., Zaręba, J. K., Mayer, D., Samoć, M., Fischer, R. A. Chem. Soc. Rev. 2017, 46, 4976–5004; https://doi.org/10.1039/c7cs00162b.Search in Google Scholar PubMed

25. Liu, J., Huang, J., Zhang, L., Lei, J. Chem. Soc. Rev. 2021, 50, 1188–1218; https://doi.org/10.1039/d0cs00178c.Search in Google Scholar PubMed

26. Jin, J., Xue, J., Liu, Y., Yang, G., Wang, Y.-Y. Dalton Trans. 2021, 50, 1950–1972; https://doi.org/10.1039/d0dt03930f.Search in Google Scholar PubMed

27. Fritz, R. A., Colon, Y. J., Herrera, F. Chem. Sci. 2021, 12, 3475–3482; https://doi.org/10.1039/d0sc05572g.Search in Google Scholar PubMed PubMed Central

28. Pan, M., Liao, W.-M., Yin, S.-Y., Sun, S.-S., Su, C.-Y. Chem. Rev. 2018, 118, 8889–8935; https://doi.org/10.1021/acs.chemrev.8b00222.Search in Google Scholar PubMed

29. Yang, X.-G., Zhai, Z.-M., Liu, X.-Y., Li, J.-Y., Li, F.-F., Ma, L.-F. Dalton Trans. 2020, 49, 598–602; https://doi.org/10.1039/c9dt04046c.Search in Google Scholar PubMed

30. Li, Z. H., Zhou, Y. X., Ni, Y. Y. Chin. J. Struct. Chem. 2020, 39, 1729–1734.Search in Google Scholar

31. Yang, X.-G., Zhai, Z.-M., Lu, X.-M., Ma, L.-F., Yan, D. ACS Cent. Sci. 2020, 6, 1169–1178; https://doi.org/10.1021/acscentsci.0c00447.Search in Google Scholar PubMed PubMed Central

32. Li, J.-X., Zhang, T., Chen, H.-J., Du, Z.-X. Z. Kristallogr. 2021, 236, 251–259; https://doi.org/10.1515/zkri-2021-2043.Search in Google Scholar

33. Baroncini, M., Bergamini, G., Ceroni, P. Chem. Commun. 2017, 53, 2081–2093; https://doi.org/10.1039/c6cc09288h.Search in Google Scholar PubMed

34. Kwon, M. S., Lee, D., Seo, S., Jung, J., Kim, J. Angew. Chem. Int. Ed. 2014, 53, 11177–11181; https://doi.org/10.1002/anie.201404490.Search in Google Scholar PubMed

35. Cheng, Z., Shi, H., Ma, H., Bian, L., Wu, Q., Gu, L., Cai, S., Wang, X., Xiong, W.-W., An, Z., Huang, W. Angew. Chem. Int. Ed. 2018, 57, 678–682; https://doi.org/10.1002/anie.201710017.Search in Google Scholar PubMed

36. Ma, J.-L., Liu, H., Li, S.-Y., Li, Z.-Y., Zhang, H.-Y., Wang, Y., Zhao, C.-H. Organometallics 2020, 39, 4153–4158; https://doi.org/10.1021/acs.organomet.0c00068.Search in Google Scholar

37. Sun, Y., Liu, J., Pang, X., Zhang, X., Zhuang, J., Zhang, H., Hu, C., Zheng, M., Lei, B., Liu, Y. J. Mater. Chem. C 2020, 8, 5744–5751; https://doi.org/10.1039/d0tc00507j.Search in Google Scholar

38. Zhang, C., Yan, Z.-P., Dong, X.-Y., Han, Z., Li, S., Fu, T., Zhu, Y.-Y., Zheng, Y.-X., Niu, Y.-Y., Zang, S.-Q. Adv. Mater. 2020, 32, 2002914; https://doi.org/10.1002/adma.202002914.Search in Google Scholar PubMed

39. Liu, J., Yang, L. Y., Luo, F. J. Solid State Chem. 2021, 301, 122369; https://doi.org/10.1016/j.jssc.2021.122369.Search in Google Scholar

40. Chen, W., Li, L., Li, X.-X., Lin, L.-D., Wang, G., Zhang, Z., Li, L., Yu, Y. Cryst. Growth Des. 2019, 19, 4754–4764; https://doi.org/10.1021/acs.cgd.9b00635.Search in Google Scholar

41. Yang, X., Jiao, B., Dang, J.-S., Sun, Y., Wu, Y., Zhou, G., Wong, W.-Y. ACS Appl. Mater. Interfaces 2018, 10, 10227–10235; https://doi.org/10.1021/acsami.7b18330.Search in Google Scholar PubMed

42. Chakraborty, P., Adhikary, J., Samanta, S., Majumder, I., Massera, C., Escudero, D., Ghosh, S., Bauza, A., Frontera, A., Das, D. Dalton Trans. 2015, 44, 20032–20044; https://doi.org/10.1039/c5dt02768c.Search in Google Scholar PubMed

43. Mu, Y., Ni, A.-Y., Han, S.-D., Pan, J., Li, J.-H., Wang, G.-M. Inorg. Chem. 2018, 57, 14497–14500; https://doi.org/10.1021/acs.inorgchem.8b02792.Search in Google Scholar PubMed

44. Yang, X.-G., Zhai, Z.-M., Lu, X.-M., Qin, J.-H., Li, F.-F., Ma, L.-F. Inorg. Chem. 2020, 59, 10395–10399; https://doi.org/10.1021/acs.inorgchem.0c01415.Search in Google Scholar PubMed

45. Yang, X.-G., Lu, X.-M., Zhai, Z.-M., Qin, J.-H., Chang, X.-H., Han, M.-L., Li, F.-F., Ma, L.-F. Inorg. Chem. Front. 2020, 7, 2224–2230; https://doi.org/10.1039/d0qi00191k.Search in Google Scholar

46. Zhao, Y., Yang, X.-G., Lu, X.-M., Yang, C.-D., Fan, N.-N., Yang, Z.-T., Wang, L.-Y., Ma, L.-F. Inorg. Chem. 2019, 58, 6215–6221; https://doi.org/10.1021/acs.inorgchem.9b00450.Search in Google Scholar PubMed

47. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467–473; https://doi.org/10.1107/s0108767390000277.Search in Google Scholar

48. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112–122; https://doi.org/10.1107/s0108767307043930.Search in Google Scholar PubMed

Received: 2022-01-25
Accepted: 2022-05-09
Published Online: 2022-06-06
Published in Print: 2022-07-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Electron density of a benzoylated tetrafructopyranose
  5. Die Reihe der nicht-zentrosymmetrischen tetragonalen Lanthanoid(III)-Oxidoantimonat(III)-Chloride LnSb2O4Cl (Ln = Gd–Lu)
  6. Iminium-substituted 2,3-dihydroisoxazoles: synthesis from acetylenic iminium salts and nitrones, and some transformations
  7. Reactions of 1-trifluoromethyl-prop-2-yne1-iminium salts with 2- and 3-aminopyridines
  8. 2,5-Dihydroxy-1,4-quinones appended with two phosphinyl groups: syntheses, structures, and redox properties
  9. Ordered CaCu5-type phases REPd2Zn3 (RE = Y, La–Nd, Sm, Gd–Dy)
  10. The solid solutions TbCuIn1–x M x (M = Al, Ga)
  11. Synthesis and structural characterization of a luminescent cadmium(II) complex with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands
  12. Synthesis and structure of a zinc(II) coordination polymer assembled with 5-(3-carboxybenzyloxy)isophthalic acid and 1,2-bis(4-pyridyl)ethane
  13. Orthoamide und Iminiumsalze, CV. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit Carbonsäureamiden
  14. Notes
  15. Addendum to: bixbyite-type phases in the system Ta-Zr-O-N
  16. Addendum to: Crystal structure of mechanochemically synthesized Ag2CdSnS4
  17. Addendum to: FeBiS2Cl – a new iron-containing member of the MPnQ 2 X family
https://doi.org/10.1515/znb-2022-0031
Keywords for this article
coordination polymer; crystal structure; zinc complex

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Electron density of a benzoylated tetrafructopyranose
  5. Die Reihe der nicht-zentrosymmetrischen tetragonalen Lanthanoid(III)-Oxidoantimonat(III)-Chloride LnSb2O4Cl (Ln = Gd–Lu)
  6. Iminium-substituted 2,3-dihydroisoxazoles: synthesis from acetylenic iminium salts and nitrones, and some transformations
  7. Reactions of 1-trifluoromethyl-prop-2-yne1-iminium salts with 2- and 3-aminopyridines
  8. 2,5-Dihydroxy-1,4-quinones appended with two phosphinyl groups: syntheses, structures, and redox properties
  9. Ordered CaCu5-type phases REPd2Zn3 (RE = Y, La–Nd, Sm, Gd–Dy)
  10. The solid solutions TbCuIn1–x M x (M = Al, Ga)
  11. Synthesis and structural characterization of a luminescent cadmium(II) complex with bis(4-(1H-imidazole-1-yl)phenyl)amine and 4,4′-sulfonyldibenzoate ligands
  12. Synthesis and structure of a zinc(II) coordination polymer assembled with 5-(3-carboxybenzyloxy)isophthalic acid and 1,2-bis(4-pyridyl)ethane
  13. Orthoamide und Iminiumsalze, CV. Umsetzungen von Orthoamiden der Alkincarbonsäuren mit Carbonsäureamiden
  14. Notes
  15. Addendum to: bixbyite-type phases in the system Ta-Zr-O-N
  16. Addendum to: Crystal structure of mechanochemically synthesized Ag2CdSnS4
  17. Addendum to: FeBiS2Cl – a new iron-containing member of the MPnQ 2 X family
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