Two luminescent d10 metal coordination polymers based on 3-nitro-5-(pyridin-3-yl)benzoic acid
-
Long Tang
,
HuanHuan Wang
Abstract
Two new coordination polymers (CPs), [Zn(npba)2] (1) and [Cd(npba)2] (2), have been hydrothermally synthesized from Zn(NO3)2·6H2O/Cd(NO3)2·6H2O and 3-nitro-5-(pyridin-3-yl) benzoic acid (Hnpba). The products have been characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. In CP 1, the four-coordinated Zn(II) centers are bridged by npba ligands to generate chains, which are connected through arene π–π stacking interactions to generate a layer structure. In CP 2, the six-coordinated Cd(II) centers are also bridged by npba ligands to form chains with similar connectivity. The photoluminescence properties of CPs 1 and 2 were studied.
Funding source: National Natural Science Foundation of China
Acknowledgments
This work was supported by the National Natural Science Foundation of China (Nos. 21573189, 21503183 and 21763028), the Research Foundation Project of of Yan′an University, and the National College Students’ innovation and entrepreneurship training program (D2019).
Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: This work was supported by the National Natural Science Foundation of China (Nos. 21573189, 21503183 and 21763028), The Research Foundation Project of Yan′an University, and the National College Students’ Innovation and Entrepreneurship Training Program (D2019).
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Wu, Y. P., Tian, J. W., Liu, S., Li, B., Zhao, J., Ma, L. F., Li, D. S., Lan, Y. Q., Bu, X. Angew. Chem. Int. Ed 2019, 58, 12185–12189; https://doi.org/10.1002/anie.201907136.Search in Google Scholar PubMed
2. Cheng, Y. J., Wang, R., Wang, S., Xi, X. J., Ma, L. F., Zang, S. Q. Chem. Commun. 2018, 54, 13563–13566; https://doi.org/10.1039/c8cc07784c.Search in Google Scholar PubMed
3. Wang, X. L., Xiong, Y., Sha, X. T., Liu, G. C., Lin, H. Y. Cryst. Growth Des. 2017, 17, 483–496; https://doi.org/10.1021/acs.cgd.6b01299.Search in Google Scholar
4. Zhao, Y., Wang, L., Fan, N. N., Han, M. L., Yang, G. P., Ma, L. F. Cryst. Growth Des. 2018, 18, 7114–7121; https://doi.org/10.1021/acs.cgd.8b01290.Search in Google Scholar
5. Tang, L., Fu, F., Wang, J. J., Gao, L. J., Chao, D. D., Wang, Z. Polyhedron 2015, 88, 116–124; https://doi.org/10.1016/j.poly.2014.12.023.Search in Google Scholar
6. Kitagawa, S., Uemura, K. Chem. Soc. Rev. 2005, 34, 109–119; https://doi.org/10.1039/b313997m.Search in Google Scholar PubMed
7. Du, M., Li, C. P., Zhao, X. J. CrystEngComm 2006, 8, 552–562;https://doi.org/10.1039/b606400k.Search in Google Scholar
8. Patra, R., Titi, H. M., Goldberg, I. CrystEngComm 2013, 15, 2853–2862; https://doi.org/10.1039/c3ce27006h.Search in Google Scholar
9. Zhou, Z., Han, M. L., Fu, H. R., Ma, L. F., Luo, F., Li, D. S. Dalton Trans. 2018, 47, 5359–5365; https://doi.org/10.1039/c8dt00594j.Search in Google Scholar PubMed
10. Chen, X. L., Zhou, Y., Cui, H. L., Yang, H., Ren, Y. X., Wang, J. J., Tang, L. J. Mol. Struct. 2019, 1175, 593–600; https://doi.org/10.1016/j.molstruc.2018.08.036.Search in Google Scholar
11. Su, Y., Zang, S. Q., Li, L. Z., Zhu, H. Z., Meng, Q. J. Cryst. Growth Des. 2007, 7, 1277–1283; https://doi.org/10.1021/cg060572g.Search in Google Scholar
12. Wang, Y., Tian, Y. Q., Luo, J. H. Inorg. Chim. Commun. 2011, 14, 1258–1261; https://doi.org/10.1016/j.inoche.2011.04.036.Search in Google Scholar
13. Wu, W. P., Liu, P., Liang, Y. T., Cui, L., Xi, Z. P., Wang, Y. Y. J. Solid State Chem. 2015, 228, 124–130; https://doi.org/10.1016/j.jssc.2015.04.009.Search in Google Scholar
14. Tang, L., Fu, F., Hou, X. Y., Wang, J. J., Wang, Z. Chin. J. Struct. Chem. 2014, 33, 1836–1842.Search in Google Scholar
15. Tang, L., Fu, F., Gao, L. J., Wei, Q. B., Zhang, Z. L., Liu, Q. R. Z. Anorg. Allg. Chem. 2013, 639, 918–921; https://doi.org/10.1002/zaac.201300140.Search in Google Scholar
16. Tang, L., Fu, F., Gao, L. J., Wu, Y. P., Liu, Q. R., Gao, X. M. Z. Anorg. Allg. Chem. 2011, 637, 608–612; https://doi.org/10.1002/zaac.201000374.Search in Google Scholar
17. Sheldrick, G. M. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Search in Google Scholar PubMed PubMed Central
18. Sheldrick, G. M. Acta Crystallogr. 2015, C71, 3–8.Search in Google Scholar
19. Zhang, Y., Dang, B., Wang, Y., Huang, W., Yin, H. Inorg. Chem. Commun. 2015, 61, 89–92; https://doi.org/10.1016/j.inoche.2015.08.014.Search in Google Scholar
20. Yang, X. P., Wang, S. Q., Zhang, L. J., Huang, S. M., Li, Z. P., Wang, C. R., Zhu, T., Bo, L. J. Mater. Chem. C 2016, 4, 1589–1593; https://doi.org/10.1039/c5tc04103a.Search in Google Scholar
21. Tang, L., Li, D. S., Fu, F., Wang, J. J., Hu, H. M., Wang, Y. Y. Chin. J. Chem. 2007, 25, 1641−1645; https://doi.org/10.1002/cjoc.200790303.Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- In this issue
- Research Articles
- Regioselective synthesis of salicylates and acetophenones by formal [3+3]-cyclocondensations of 3-oxoorthoesters with 1,3-bis(trimethylsilyloxy)-1,3-butadienes
- Crystal structure, Hirshfeld surface analysis and Pixel calculations of the monohydrate of (E)-3-(2-hydroxy-5-methoxyphenyl)-1-(2-hydroxy-4-methoxyphenyl)prop-2-en-1-one: occurrence of π interactions
- Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability
- Single-crystal X-ray structure determinations of vardenafil, vardenafil dihydrate, vardenafil monohydrochloride trihydrate and vardenafil dihydrochloride hexahydrate
- Assembly, photocatalytic and fluorescence properties of three new coordination complexes of zinc(II) and nickel(II) with two kinds of flexible bis(pyridyl)-bis(amide) ligands
- Two luminescent d10 metal coordination polymers based on 3-nitro-5-(pyridin-3-yl)benzoic acid
- High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)
- A novel three-dimensional cadmium sulfate-based inorganic-organic hybrid polymer with green photoluminescence
