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Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

  • Runmei Ding , Zixin He , Meilin Wang , Danian Tian and Peipei Cen EMAIL logo
Published/Copyright: December 4, 2020
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 76 Issue 1

Abstract

Based on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P1‾. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Keywords: crystal structure; lanthanide coordination polymers; pyridyl dicarboxylate; thermostability
Corresponding author: Peipei Cen, College of Basic Medical Sciences, College of Public Health and Management, Ningxia Medical University, Yinchuan750021, P. R. China, E-mail:

Funding source: Natural Science Foundation of Ningxia Province

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the Natural Science Foundation of Ningxia Province (2020AAC03118).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Liu, X.-Y., Li, Y., Tsung, C. K., Li, J. Chem. Commun. 2019, 55, 10669–10672; https://doi.org/10.1039/c9cc05533a.Search in Google Scholar PubMed

2. Pan, M., Wu, K., Zhang, J.-H., Su, C.-Y. Coord. Chem. Rev. 2019, 378, 333–349; https://doi.org/10.1016/j.ccr.2017.10.031.Search in Google Scholar

3. Mallick, A., El-Zohry, A. M., Shekhah, O., Yin, J., Jia, J., Aggarwal, H., Emwas, A. H., Mohammed, O. F., Eddaoudi, M. J. Am. Chem. Soc. 2019, 141, 7245–7249; https://doi.org/10.1021/jacs.9b01839.Search in Google Scholar PubMed

4. Shao, Z., Yu, C., Xie, Q., Wu, Q., Zhao, Y., Hou, H. Chem. Commun. 2019, 55, 13382–13385; https://doi.org/10.1039/c9cc06849j.Search in Google Scholar PubMed

5. Ding, M., Flaig, R. W., Jiang, H.-L., Yaghi, O. M. Chem. Soc. Rev. 2019, 48, 2783–2828; https://doi.org/10.1039/c8cs00829a.Search in Google Scholar PubMed

6. Feng, L., Wang, K.-Y., Day, G. S., Zhou, H.-C. Chem. Soc. Rev. 2019, 48, 4823–4853; https://doi.org/10.1039/c9cs00250b.Search in Google Scholar PubMed

7. Cui, Y., Yue, D., Huang, Y., Zhang, J., Wang, Z., Yang, D., Qian, G. Chem. Commun. 2019, 55, 11231–11234; https://doi.org/10.1039/c9cc05019a.Search in Google Scholar PubMed

8. Jiang, K., Zhang, L., Xia, T., Yang, Y., Li, B., Cui, Y., Qian, G. Sci. China Mater. 2019, 62, 1315–1322; https://doi.org/10.1007/s40843-019-9427.Search in Google Scholar

9. Du, W., Zhu, Z., Bai, Y.-L., Yang, Z., Zhu, S., Xu, J., Xie, Z., Fang, J. Chem. Commun. 2018, 54, 5972–5975; https://doi.org/10.1039/c8cc02193g.Search in Google Scholar PubMed

10. Liu, Y., Xie, X.-Y., Cheng, C., Shao, Z.-S., Wang, H.-S. J. Mater. Chem. C 2019, 7, 10743–10763; https://doi.org/10.1039/c9tc03208h.Search in Google Scholar

11. Xiao, J.-D., Han, L., Luo, J., Yu, S.-H., Jiang, H.-L. Angew. Chem. Int. Ed. 2018, 57, 1103–1107; https://doi.org/10.1002/anie.201711725.Search in Google Scholar PubMed

12. Yue, D., Chen, D., Zhang, X., Huang, Y., Wang, Z. Z. Anorg. Allg. Chem. 2019, 645, 1303–1306; https://doi.org/10.1002/zaac.201900225.Search in Google Scholar

13. Nguyen, T. N., Ebrahim, F. M., Stylianou, K. C. Coord. Chem. Rev. 2018, 377, 259–306; https://doi.org/10.1016/j.ccr.2018.08.024.Search in Google Scholar

14. Zhang, Q., Lei, M., Yan, H., Wang, J., Shi, Y. Inorg. Chem. 2017, 56, 7610–7614; https://doi.org/10.1021/acs.inorgchem.7b01156.Search in Google Scholar PubMed

15. Han, M.-L., Wen, G.-X., Dong, W.-W., Zhou, Z.-H., Wu, Y.-P., Zhao, J., Li, D.-S., Ma, L.-F., Bu, X. J. Mater. Chem. C 2017, 5, 8469–8474; https://doi.org/10.1039/c7tc02885g.Search in Google Scholar

16. Zhang, F., Yao, H., Chu, T., Zhang, G., Wang, Y., Yang, Y. Chem. Eur J. 2017, 23, 10293–10300; https://doi.org/10.1002/chem.201701852.Search in Google Scholar PubMed

17. Qin, L., Li, Y.-H., Ma, P.-J., Cui, G.-H. J. Mol. Struct. 2013, 1051, 215–220; https://doi.org/10.1016/j.molstruc.2013.08.013.Search in Google Scholar

18. Wang, X.-L., Chen, Y.-Q., Liu, G.-C., Lin, H.-Y., Zhang, J.-X. J. Solid State Chem. 2009, 182, 2392–2401; https://doi.org/10.1016/j.jssc.2009.06.031.Search in Google Scholar

19. Han, M.-L., Duan, Y.-P., Li, D.-S., Wang, H.-B., Zhao, J., Wang, Y.-Y. Dalton Trans. 2014, 43, 15450–15456; https://doi.org/10.1039/c4dt01086h.Search in Google Scholar PubMed

20. Duan, C.-W., Cao, Y.-Z., Hu, L.-X., Fu, D., Ma, J.-L. Mater. Lett. 2019, 238, 254–257; https://doi.org/10.1016/j.matlet.2018.12.028.Search in Google Scholar

21. Liu, J.-Y., Ren, N., Zhang, J.-J., S He, .-M., Wang, S.-P. Ind. Eng. Chem. Res. 2013, 52, 6156–6163; https://doi.org/10.1021/ie400228j.Search in Google Scholar

22. Sheldrick, G. M. Shelxs-2014, Shelxl-2014, Programs for Crystal Structure Determination, University of Göttingen: Göttingen (Germany), 2014.Search in Google Scholar

23. Zhang, Y., Wu, Y., He, X., Ma, J., Shen, X., Zhu, D. Acta Crystallogr. 2018, C74, 256–262; https://doi.org/10.1107/s2053229618001432.Search in Google Scholar

24. Li, J.-Z., Rouhani, F., Gao, X.-M., Wang, R., Wei, X.-W., Yan, X.-W., Hu, M.-L., Liu, K.-G., Morsali, A. Inorg. Chem. 2019, 58, 5397–5400; https://doi.org/10.1021/acs.inorgchem.9b00264.Search in Google Scholar PubMed

25. Wang, C. G., Xing, Y. H., Li, Z. P., Li, J., Zeng, X. Q., Ge, M. F., Niu, S. Y. Cryst. Growth Des. 2009, 9, 1525–1530; https://doi.org/10.1021/cg801157k.Search in Google Scholar

26. Prieto, G., Tüysüz, H., Duyckaerts, N., Knossalla, J., Wang, G.-H., Schüth, F. Chem. Rev. 2016, 116, 14056–14119; https://doi.org/10.1021/acs.chemrev.6b00374.Search in Google Scholar PubMed

27. Sheldrick, G. M., Sadabs, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen: Göttingen (Germany), 1996.Search in Google Scholar

28. Duan, L.-J., Zhang, C.-C., Cen, P.-P., Jin, X.-Y., Liang, C., Yang, J.-H., Liu, X.-Y. CrystEngComm. 2020, 22, 1695–1704; https://doi.org/10.1039/c9ce01995b.Search in Google Scholar

Received: 2020-07-29
Accepted: 2020-11-10
Published Online: 2020-12-04
Published in Print: 2021-01-27

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/znb-2020-0136
Keywords for this article
crystal structure; lanthanide coordination polymers; pyridyl dicarboxylate; thermostability

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Regioselective synthesis of salicylates and acetophenones by formal [3+3]-cyclocondensations of 3-oxoorthoesters with 1,3-bis(trimethylsilyloxy)-1,3-butadienes
  5. Crystal structure, Hirshfeld surface analysis and Pixel calculations of the monohydrate of (E)-3-(2-hydroxy-5-methoxyphenyl)-1-(2-hydroxy-4-methoxyphenyl)prop-2-en-1-one: occurrence of π interactions
  6. Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability
  7. Single-crystal X-ray structure determinations of vardenafil, vardenafil dihydrate, vardenafil monohydrochloride trihydrate and vardenafil dihydrochloride hexahydrate
  8. Assembly, photocatalytic and fluorescence properties of three new coordination complexes of zinc(II) and nickel(II) with two kinds of flexible bis(pyridyl)-bis(amide) ligands
  9. Two luminescent d10 metal coordination polymers based on 3-nitro-5-(pyridin-3-yl)benzoic acid
  10. High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)
  11. A novel three-dimensional cadmium sulfate-based inorganic-organic hybrid polymer with green photoluminescence
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