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Thiakronenether-Metallkomplexe: Komplexe von Silber(I) und Quecksilber(II) mit Tetrathia-12-krone-4, Silber(I) und Cadmium(II) mit Hexathia-18-krone-6 und Silber(I) mit 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11-13-dien / Thia Crown Ether Metal Complexes: Complexes of Silver(I) and Mercury(II) with Tetrathia-12-crown-4, Silver(I), and Cadmium(II) with Hexathia-18-crown-6, and Silver(I) with 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11-13-diene
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Joachim Pickardt
,
Lars von Chrzanowski
Published/Copyright:
June 2, 2014
Abstract
Crystals of 1,4,7,10-tetrathiacyclododecane silver(I) trifluoromethanesulfonate, Ag(C8H16S4)- (CF3SO3), 1,4,7,10-tetrathiacyclododecane iodo mercury(II) hexaiododimercurate(II)methylene chloride [HgI(C8H16S4)][Hg2I6] · CH2Cl2, 1,4,7,10,13,16-hexathiacyclooctadecane silver(I) trifluoromethanesulfonate [Ag(C12H24S6)](CF3SO3), 1,4,7,10,13,16-hexathiacyclooctadecane diiodocadmium, [Cd(C12H24S6)I2], and bis-3,6,9,14-tetrathiabicyclo[9.2.1]tetradeca-11-13-diene silver(I) trifluoromethanesulfonate [Ag(C10H14S4)2](CF3SO3) were obtained by reaction of solutions of the ligands and the appropriate metal salts and their X-ray crystal structures determined.
Received: 2004-7-6
Published Online: 2014-6-2
Published in Print: 2004-10-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Articles in the same Issue
- Thiakronenether-Metallkomplexe: Komplexe von Silber(I) und Quecksilber(II) mit Tetrathia-12-krone-4, Silber(I) und Cadmium(II) mit Hexathia-18-krone-6 und Silber(I) mit 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11-13-dien / Thia Crown Ether Metal Complexes: Complexes of Silver(I) and Mercury(II) with Tetrathia-12-crown-4, Silver(I), and Cadmium(II) with Hexathia-18-crown-6, and Silver(I) with 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11-13-diene
- Synthesis, Crystal Structures and Properties of Three New Tetrathiomolybdates with Organic Ammonium Cations
- Diastereomeric Halfsandwich Rhenium Complexes Containing Thiolate and Thioaldehyde Ligands
- A New Ternary Arsenide LaNi5As3: Preparation and Crystal Structure
- Syntheses and Characterization of New Mixed-Ligand Mercury(II) Complexes, Hg(bpy)n(SCN)X (X = CH3COO–, NO3– and ClO4–), Crystal Structure of [Hg(bpy)2(SCN)]NO3
- Crystal Engineering of a New Layered Polyiodide Using 1,9-Diammoniononane as a Flexible Template Cation
- Cazolobine, a New Sesquiterpene from Isolona hexaloba (Annonaceae)
- Synthesis and Solid-State Structures of Alkyl-Substituted 3-Cyano-2-pyridones
- Enamines in Heterocyclic Synthesis: A Route to 4-Substituted Pyrazoles and Condensed Pyrazoles
- Synthesis, Spectroscopic Studies and Crystal Structure of 5,5’-Dimethoxy- 3,3’-methanediyl-bis-indole as the Inhibitor of Cell Proliferation of Human Tumors
- 1,2-Deoxygenation of vic-Dihydroxyindenoimidazoles: Optimization of a Novel Deoxygenation Reagent
- Experimental Gas Phase 1H NMR Spectra and Basis Set Dependence of ab initio GIAOMO Calculations of 1H and 13C NMR Absolute Shieldings and Chemical Shifts of Small Hydrocarbons
- Synthesis, Structure, and Absolute Configuration of a New Cyclopropanic Compound Derived from the Sesquiterpene β-Himachalene
Keywords for this article
Thia Crown Ether Complexes;
Mercuric Iodide;
Cadmium Iodide;
Silver(I) Complexes
Articles in the same Issue
- Thiakronenether-Metallkomplexe: Komplexe von Silber(I) und Quecksilber(II) mit Tetrathia-12-krone-4, Silber(I) und Cadmium(II) mit Hexathia-18-krone-6 und Silber(I) mit 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11-13-dien / Thia Crown Ether Metal Complexes: Complexes of Silver(I) and Mercury(II) with Tetrathia-12-crown-4, Silver(I), and Cadmium(II) with Hexathia-18-crown-6, and Silver(I) with 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11-13-diene
- Synthesis, Crystal Structures and Properties of Three New Tetrathiomolybdates with Organic Ammonium Cations
- Diastereomeric Halfsandwich Rhenium Complexes Containing Thiolate and Thioaldehyde Ligands
- A New Ternary Arsenide LaNi5As3: Preparation and Crystal Structure
- Syntheses and Characterization of New Mixed-Ligand Mercury(II) Complexes, Hg(bpy)n(SCN)X (X = CH3COO–, NO3– and ClO4–), Crystal Structure of [Hg(bpy)2(SCN)]NO3
- Crystal Engineering of a New Layered Polyiodide Using 1,9-Diammoniononane as a Flexible Template Cation
- Cazolobine, a New Sesquiterpene from Isolona hexaloba (Annonaceae)
- Synthesis and Solid-State Structures of Alkyl-Substituted 3-Cyano-2-pyridones
- Enamines in Heterocyclic Synthesis: A Route to 4-Substituted Pyrazoles and Condensed Pyrazoles
- Synthesis, Spectroscopic Studies and Crystal Structure of 5,5’-Dimethoxy- 3,3’-methanediyl-bis-indole as the Inhibitor of Cell Proliferation of Human Tumors
- 1,2-Deoxygenation of vic-Dihydroxyindenoimidazoles: Optimization of a Novel Deoxygenation Reagent
- Experimental Gas Phase 1H NMR Spectra and Basis Set Dependence of ab initio GIAOMO Calculations of 1H and 13C NMR Absolute Shieldings and Chemical Shifts of Small Hydrocarbons
- Synthesis, Structure, and Absolute Configuration of a New Cyclopropanic Compound Derived from the Sesquiterpene β-Himachalene
