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Synthesis and Solid-State Structures of Alkyl-Substituted 3-Cyano-2-pyridones
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Christian B. Fischer
Published/Copyright:
June 2, 2014
Abstract
A series of 3-cyano-pyridones carrying a variety of alkyl substituents at C-5 and C-6 has been synthesized and their solid-state structures have been studied. Hydrogen bonding interactions between individual pyridone molecules lead either to the formation of symmetric dimers of the R22 (8) type or to helical chains of the C(4) type. Based on known and calculated structures for the 2-pyridone parent system, the solid-state structures can be divided in two groups representing cases with little external influence on the hydrogen bonding array (group A) and those with a larger external influence (group B).
Received: 2004-6-18
Published Online: 2014-6-2
Published in Print: 2004-10-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Keywords for this article
Hydrogen Bonds;
Dimerization;
Solid State Structure;
Aggregation;
Alkylation
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