Home Darstellung und 51V-NMR-spektroskopische Untersuchungen von η5-Cyclopentadienyl-tert-butylimidovanadium(III)-Komplexen mit σ-Donator, π-Akzeptor-Liganden / Synthesis and 51V NMR Spectroscopic Studies of η5 -Cyclopentadienyl-tert-butylimidovanadium( III) Complexes with σ -Donor, π -Acceptor Ligands
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Darstellung und 51V-NMR-spektroskopische Untersuchungen von η5-Cyclopentadienyl-tert-butylimidovanadium(III)-Komplexen mit σ-Donator, π-Akzeptor-Liganden / Synthesis and 51V NMR Spectroscopic Studies of η5 -Cyclopentadienyl-tert-butylimidovanadium( III) Complexes with σ -Donor, π -Acceptor Ligands

  • Martin Billen , Gabriele Hornung and Fritz Preuss EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 58 Issue 10

The imidovanadium(III) complexes [tBuN=VCp(PR3)2], [tBuN=VCp{P(OR)3}2] and [tBuN= VCp(CO)2] have been prepared starting from tBuN=VCpCl2 by reductive dehalogenation with magnesium. The reaction of [tBuN=VCp(PMe3)2] (2a) with carbon monoxide, alkynes, alkenes, tert-butylphosphaalkyne, nitriles, ketones and carbon disulfide furnished the complexes [tBuN=VCp(PMe3) (L)], while the vanadium(V) compound tBuN=VCp(O2C2Ph2) is formed with benzil. All vanadium(III) complexes obtained are diamagnetic (d2, low-spin configuration) and have been characterized by spectroscopic methods (MS; 1H, 13C, 31P, 51V NMR).

Keywords : Diamagnetic Vanadium(III) Complexes; σ -Donor; π-Acceptor Ligand; 51V NMR Spectra
Received: 2003-6-17
Published Online: 2014-6-2
Published in Print: 2003-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Non-Stoichiometric Monoclinic Cr5Se8 Prepared at High-Pressure and High-Temperature and the Crystal Structure Refined from Rietveld Data
  2. SiF-NH-Funktionelle Cyclodisilazane – Synthese und Reaktivität / SiF-NH-Functional Cyclodisilazane – Synthesis and Reactivity
  3. Synthesis, Electronic Spectra and Solvent-Induced Reversible Dissociation of Diphosphine(hexafluoroacetylacetonato)copper(I) Complexes
  4. Synthesis, Crystal Structure and Spectroscopic Properties of a Dinuclear Nickel(II) Complex Bridged by an Alkoxide and a μ-Pyrazolate Ligand
  5. Formation and Structural Characterization of [RuCl2(CO)2(SPh2)2], [RuCl2(CO)3(OH2)], and [Ru(OH2)6][RuCl3(CO)3]2 · 2H2O
  6. Is 2-D Graphite an Ultimate Large Hydrocarbon? IV. Structure and Energy Spectra of Large Polycyclic Aromatic Hydrocarbons with Different Symmetry
  7. Crystal Structure of Eu2PdSi3
  8. Darstellung und 51V-NMR-spektroskopische Untersuchungen von η5-Cyclopentadienyl-tert-butylimidovanadium(III)-Komplexen mit σ-Donator, π-Akzeptor-Liganden / Synthesis and 51V NMR Spectroscopic Studies of η5 -Cyclopentadienyl-tert-butylimidovanadium( III) Complexes with σ -Donor, π -Acceptor Ligands
  9. Reduktion von Isochinolin und Indol mit Cäsium in flüssigem Ammoniak / Reduction of Isoquinoline and Indole with Cesium in Liquid Ammonia
  10. Synthesis of trans-Configurated Spacered Nucleoside Analogues Comprising a Difluorocyclopropane Moiety
  11. Generation and Structural Characterization of an [(Imidazol-2-ylidene)HfCl5]-Anion/Imidazolium Cation Salt
  12. Synthesis and Characterization of Copper(II) and Zinc(II) Complexes Containing 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone
  13. Synthesis and Liquid Crystalline Properties of Novel Imides and Thioimides with Chiral Aliphatic Tails
  14. Note: Synthesis of the Dinuclear Halogeno-Bridged Complexes [Re2(μ-X)2(CO)6(CH3CN)2], (X = Cl, Br)
  15. Dawenol, a New Polyene Metabolite from the Myxobacterium
  16. A Novel Methylene Dithioether as a Ligand: Synthesis and Molecular Structure of a Zinc(II) Complex with N4S2 Coordination Environment
  17. Synthesis and Tin(IV) Coordination Chemistry of the Novel Tripod N(CH2CH2CH2SH)3
https://doi.org/10.1515/znb-2003-1008
Keywords for this article
Diamagnetic Vanadium(III) Complexes; σ -Donor; π-Acceptor Ligand; 51V NMR Spectra

Articles in the same Issue

  1. Non-Stoichiometric Monoclinic Cr5Se8 Prepared at High-Pressure and High-Temperature and the Crystal Structure Refined from Rietveld Data
  2. SiF-NH-Funktionelle Cyclodisilazane – Synthese und Reaktivität / SiF-NH-Functional Cyclodisilazane – Synthesis and Reactivity
  3. Synthesis, Electronic Spectra and Solvent-Induced Reversible Dissociation of Diphosphine(hexafluoroacetylacetonato)copper(I) Complexes
  4. Synthesis, Crystal Structure and Spectroscopic Properties of a Dinuclear Nickel(II) Complex Bridged by an Alkoxide and a μ-Pyrazolate Ligand
  5. Formation and Structural Characterization of [RuCl2(CO)2(SPh2)2], [RuCl2(CO)3(OH2)], and [Ru(OH2)6][RuCl3(CO)3]2 · 2H2O
  6. Is 2-D Graphite an Ultimate Large Hydrocarbon? IV. Structure and Energy Spectra of Large Polycyclic Aromatic Hydrocarbons with Different Symmetry
  7. Crystal Structure of Eu2PdSi3
  8. Darstellung und 51V-NMR-spektroskopische Untersuchungen von η5-Cyclopentadienyl-tert-butylimidovanadium(III)-Komplexen mit σ-Donator, π-Akzeptor-Liganden / Synthesis and 51V NMR Spectroscopic Studies of η5 -Cyclopentadienyl-tert-butylimidovanadium( III) Complexes with σ -Donor, π -Acceptor Ligands
  9. Reduktion von Isochinolin und Indol mit Cäsium in flüssigem Ammoniak / Reduction of Isoquinoline and Indole with Cesium in Liquid Ammonia
  10. Synthesis of trans-Configurated Spacered Nucleoside Analogues Comprising a Difluorocyclopropane Moiety
  11. Generation and Structural Characterization of an [(Imidazol-2-ylidene)HfCl5]-Anion/Imidazolium Cation Salt
  12. Synthesis and Characterization of Copper(II) and Zinc(II) Complexes Containing 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone
  13. Synthesis and Liquid Crystalline Properties of Novel Imides and Thioimides with Chiral Aliphatic Tails
  14. Note: Synthesis of the Dinuclear Halogeno-Bridged Complexes [Re2(μ-X)2(CO)6(CH3CN)2], (X = Cl, Br)
  15. Dawenol, a New Polyene Metabolite from the Myxobacterium
  16. A Novel Methylene Dithioether as a Ligand: Synthesis and Molecular Structure of a Zinc(II) Complex with N4S2 Coordination Environment
  17. Synthesis and Tin(IV) Coordination Chemistry of the Novel Tripod N(CH2CH2CH2SH)3
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